Utilization of waste crab shell (Scylla serrata) as a catalyst in palm olein transesterification

Aquaculture activity has increased the population of crab, hence increasing the generation of related wastes, particularly the shell. In addition, the number of molting process in crabs compounds further the amount of waste shell generated. As such, in the present work, the application of the waste...

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Main Authors: Boey, Peng-Lim, Maniam, Gaanty Pragas, Abd Hamid, Shafida
Format: Article
Language:English
Published: Japan Oil Chemists' Society 2009
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spelling iium-103642013-07-27T04:57:27Z http://irep.iium.edu.my/10364/ Utilization of waste crab shell (Scylla serrata) as a catalyst in palm olein transesterification Boey, Peng-Lim Maniam, Gaanty Pragas Abd Hamid, Shafida QD Chemistry Aquaculture activity has increased the population of crab, hence increasing the generation of related wastes, particularly the shell. In addition, the number of molting process in crabs compounds further the amount of waste shell generated. As such, in the present work, the application of the waste crab shell as a source of CaO in transesterification of palm olein to biodiesel (methyl ester) was investigated. Preliminary XRD results revealed that thermally activated crab shell contains mainly CaO. Parametric study has been investigated and optimal conditions were found to be methanol/oil mass ratio, 0.5:1; catalyst amount, 4 wt. %; and reaction temperature, 338 K. As compared to laboratory CaO, the catalyst from waste crab shell performs well, thus creating another low-cost catalyst source for producing biodiesel as well as adding value to the waste crab shell. Reusability of crab shell CaO has also been studied and the outcome confirmed that the catalyst is capable to be reutilized up to 11 times, without any major deterioration. Japan Oil Chemists' Society 2009 Article PeerReviewed application/pdf en http://irep.iium.edu.my/10364/1/_pdf.pdf Boey, Peng-Lim and Maniam, Gaanty Pragas and Abd Hamid, Shafida (2009) Utilization of waste crab shell (Scylla serrata) as a catalyst in palm olein transesterification. Journal of Oleo Science, 58 (10). pp. 499-502. ISSN 1347-3352 (O), 1345-8957 (P) http://www.jstage.jst.go.jp/article/jos/58/10/58_499/_article 10.5650/jos.58.499
repository_type Digital Repository
institution_category Local University
institution International Islamic University Malaysia
building IIUM Repository
collection Online Access
language English
topic QD Chemistry
spellingShingle QD Chemistry
Boey, Peng-Lim
Maniam, Gaanty Pragas
Abd Hamid, Shafida
Utilization of waste crab shell (Scylla serrata) as a catalyst in palm olein transesterification
description Aquaculture activity has increased the population of crab, hence increasing the generation of related wastes, particularly the shell. In addition, the number of molting process in crabs compounds further the amount of waste shell generated. As such, in the present work, the application of the waste crab shell as a source of CaO in transesterification of palm olein to biodiesel (methyl ester) was investigated. Preliminary XRD results revealed that thermally activated crab shell contains mainly CaO. Parametric study has been investigated and optimal conditions were found to be methanol/oil mass ratio, 0.5:1; catalyst amount, 4 wt. %; and reaction temperature, 338 K. As compared to laboratory CaO, the catalyst from waste crab shell performs well, thus creating another low-cost catalyst source for producing biodiesel as well as adding value to the waste crab shell. Reusability of crab shell CaO has also been studied and the outcome confirmed that the catalyst is capable to be reutilized up to 11 times, without any major deterioration.
format Article
author Boey, Peng-Lim
Maniam, Gaanty Pragas
Abd Hamid, Shafida
author_facet Boey, Peng-Lim
Maniam, Gaanty Pragas
Abd Hamid, Shafida
author_sort Boey, Peng-Lim
title Utilization of waste crab shell (Scylla serrata) as a catalyst in palm olein transesterification
title_short Utilization of waste crab shell (Scylla serrata) as a catalyst in palm olein transesterification
title_full Utilization of waste crab shell (Scylla serrata) as a catalyst in palm olein transesterification
title_fullStr Utilization of waste crab shell (Scylla serrata) as a catalyst in palm olein transesterification
title_full_unstemmed Utilization of waste crab shell (Scylla serrata) as a catalyst in palm olein transesterification
title_sort utilization of waste crab shell (scylla serrata) as a catalyst in palm olein transesterification
publisher Japan Oil Chemists' Society
publishDate 2009
url http://irep.iium.edu.my/10364/
http://irep.iium.edu.my/10364/
http://irep.iium.edu.my/10364/
http://irep.iium.edu.my/10364/1/_pdf.pdf
first_indexed 2023-09-18T20:19:48Z
last_indexed 2023-09-18T20:19:48Z
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