6,6′-Dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate

6,6′-Dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate

The title compound, C22H20N2O4·2CHCl3, a new Schiff base compound, lies across a crystallographic inversion centre. An intramolecular O-HN hydrogen bond generates a six-membered ring, producing an S(6) ring motif. Intermolecular bifurcated C-HO hydrogen bonds involving the two O atoms of the Schiff...

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Main Authors: Al-Douh, Mohammed Hadi, Osman, Hasnah, Abd Hamid, Shafida, Kia, Reza, Fun, Hoong-Kun
Format: Article
Language:English
Published: International Union of Crystallography 2009
Subjects:
QD Chemistry
Online Access:http://irep.iium.edu.my/12809/
http://irep.iium.edu.my/12809/
http://irep.iium.edu.my/12809/
http://irep.iium.edu.my/12809/1/6_6_dimethoxy_2_p_phenylenebis.pdf
id iium-12809
recordtype eprints
spelling iium-128092012-05-08T12:37:01Z http://irep.iium.edu.my/12809/ 6,6′-Dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate Al-Douh, Mohammed Hadi Osman, Hasnah Abd Hamid, Shafida Kia, Reza Fun, Hoong-Kun QD Chemistry The title compound, C22H20N2O4·2CHCl3, a new Schiff base compound, lies across a crystallographic inversion centre. An intramolecular O-HN hydrogen bond generates a six-membered ring, producing an S(6) ring motif. Intermolecular bifurcated C-HO hydrogen bonds involving the two O atoms of the Schiff base ligand and the H atom of the chloroform solvent of crystallization, generate an R21(5) ring motif. The crystal structure is stabilized by intermolecular C-H and - interactions [centroid to centroid distance = 3.6158 (10) Å]. In the crystal structure, molecules are stacked down the c axis. International Union of Crystallography 2009 Article PeerReviewed application/pdf en http://irep.iium.edu.my/12809/1/6_6_dimethoxy_2_p_phenylenebis.pdf Al-Douh, Mohammed Hadi and Osman, Hasnah and Abd Hamid, Shafida and Kia, Reza and Fun, Hoong-Kun (2009) 6,6′-Dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate. Acta Crystallographica Section E Structure Reports Online, 65 (4). O680-O681. ISSN 1600-5368 http://dx.doi.org/10.1107/S1600536809007302 10.1107/S1600536809007302
repository_type Digital Repository
institution_category Local University
institution International Islamic University Malaysia
building IIUM Repository
collection Online Access
language English
topic QD Chemistry
spellingShingle QD Chemistry
Al-Douh, Mohammed Hadi
Osman, Hasnah
Abd Hamid, Shafida
Kia, Reza
Fun, Hoong-Kun
6,6′-Dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate
description The title compound, C22H20N2O4·2CHCl3, a new Schiff base compound, lies across a crystallographic inversion centre. An intramolecular O-HN hydrogen bond generates a six-membered ring, producing an S(6) ring motif. Intermolecular bifurcated C-HO hydrogen bonds involving the two O atoms of the Schiff base ligand and the H atom of the chloroform solvent of crystallization, generate an R21(5) ring motif. The crystal structure is stabilized by intermolecular C-H and - interactions [centroid to centroid distance = 3.6158 (10) Å]. In the crystal structure, molecules are stacked down the c axis.
format Article
author Al-Douh, Mohammed Hadi
Osman, Hasnah
Abd Hamid, Shafida
Kia, Reza
Fun, Hoong-Kun
author_facet Al-Douh, Mohammed Hadi
Osman, Hasnah
Abd Hamid, Shafida
Kia, Reza
Fun, Hoong-Kun
author_sort Al-Douh, Mohammed Hadi
title 6,6′-Dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate
title_short 6,6′-Dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate
title_full 6,6′-Dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate
title_fullStr 6,6′-Dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate
title_full_unstemmed 6,6′-Dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate
title_sort 6,6′-dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate
publisher International Union of Crystallography
publishDate 2009
url http://irep.iium.edu.my/12809/
http://irep.iium.edu.my/12809/
http://irep.iium.edu.my/12809/
http://irep.iium.edu.my/12809/1/6_6_dimethoxy_2_p_phenylenebis.pdf
first_indexed 2023-09-18T20:21:57Z
last_indexed 2023-09-18T20:21:57Z
_version_ 1777408165511430144

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