Effect of electron beam irradiation (EB) on gas barrier property of HDPE/EPDM nanocomposites

In this study, electron beam irradiated (EB) was applied as a crosslinker agent for both pristine high density polyethylene (HDPE) and HDPE/ ethylene propylene diene monomer (EPDM)nanocomposite systems. The doses rate for EB irradiated technique were varied between 50, 100,150 and 200 kGy. The nanoc...

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Main Authors: Jamal, Nur Ayuni, Anuar, Hazleen, Abd Razak, Shamsul Bahri
Format: Article
Language:English
Published: Trans Tech Publications, Switzerland 2011
Subjects:
Online Access:http://irep.iium.edu.my/2354/
http://irep.iium.edu.my/2354/
http://irep.iium.edu.my/2354/
http://irep.iium.edu.my/2354/1/KEM.471-472.775.pdf
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spelling iium-23542012-02-28T02:52:16Z http://irep.iium.edu.my/2354/ Effect of electron beam irradiation (EB) on gas barrier property of HDPE/EPDM nanocomposites Jamal, Nur Ayuni Anuar, Hazleen Abd Razak, Shamsul Bahri TS1870 Rubber industry In this study, electron beam irradiated (EB) was applied as a crosslinker agent for both pristine high density polyethylene (HDPE) and HDPE/ ethylene propylene diene monomer (EPDM)nanocomposite systems. The doses rate for EB irradiated technique were varied between 50, 100,150 and 200 kGy. The nanocomposites systems were first prepared via melt intercalation method with different organophilic montmorillonite (OMMT) loadings. It was found that, with 4 vol% organophilic montmorillonite (OMMT) loading, the barrier resistance of nanocomposite against oxygen transmission was significantly enhanced by EB irradiation dose rate of 100 kGy. The oxygen transmission for nanocomposite was reduced by 23.48%. The interplanar spacing,spacings of OMMT in nanocomposites were monitored using x-ray diffraction (XRD) and the extent of delamination was examined by transmission electron microscope (TEM). The wide angle of XRD patterns showed the increased interplanar spacing, of clay layers, indicating enhanced compatibility between polymer matrix and OMMT with EB irradiation. TEM photomicrographs illustrated the mixed intercalated and partial exfoliated structures of the nanocomposites with the irradiation process. � Trans Tech Publications, Switzerland 2011 Article PeerReviewed application/pdf en http://irep.iium.edu.my/2354/1/KEM.471-472.775.pdf Jamal, Nur Ayuni and Anuar, Hazleen and Abd Razak, Shamsul Bahri (2011) Effect of electron beam irradiation (EB) on gas barrier property of HDPE/EPDM nanocomposites. Key Engineering Materials, 471. pp. 775-780. ISSN ISSN: 1013-9826 http://www.scientific.net/KEM.471-472.775 doi:10.4028/www.scientific.net/KEM.471-472.775
repository_type Digital Repository
institution_category Local University
institution International Islamic University Malaysia
building IIUM Repository
collection Online Access
language English
topic TS1870 Rubber industry
spellingShingle TS1870 Rubber industry
Jamal, Nur Ayuni
Anuar, Hazleen
Abd Razak, Shamsul Bahri
Effect of electron beam irradiation (EB) on gas barrier property of HDPE/EPDM nanocomposites
description In this study, electron beam irradiated (EB) was applied as a crosslinker agent for both pristine high density polyethylene (HDPE) and HDPE/ ethylene propylene diene monomer (EPDM)nanocomposite systems. The doses rate for EB irradiated technique were varied between 50, 100,150 and 200 kGy. The nanocomposites systems were first prepared via melt intercalation method with different organophilic montmorillonite (OMMT) loadings. It was found that, with 4 vol% organophilic montmorillonite (OMMT) loading, the barrier resistance of nanocomposite against oxygen transmission was significantly enhanced by EB irradiation dose rate of 100 kGy. The oxygen transmission for nanocomposite was reduced by 23.48%. The interplanar spacing,spacings of OMMT in nanocomposites were monitored using x-ray diffraction (XRD) and the extent of delamination was examined by transmission electron microscope (TEM). The wide angle of XRD patterns showed the increased interplanar spacing, of clay layers, indicating enhanced compatibility between polymer matrix and OMMT with EB irradiation. TEM photomicrographs illustrated the mixed intercalated and partial exfoliated structures of the nanocomposites with the irradiation process. �
format Article
author Jamal, Nur Ayuni
Anuar, Hazleen
Abd Razak, Shamsul Bahri
author_facet Jamal, Nur Ayuni
Anuar, Hazleen
Abd Razak, Shamsul Bahri
author_sort Jamal, Nur Ayuni
title Effect of electron beam irradiation (EB) on gas barrier property of HDPE/EPDM nanocomposites
title_short Effect of electron beam irradiation (EB) on gas barrier property of HDPE/EPDM nanocomposites
title_full Effect of electron beam irradiation (EB) on gas barrier property of HDPE/EPDM nanocomposites
title_fullStr Effect of electron beam irradiation (EB) on gas barrier property of HDPE/EPDM nanocomposites
title_full_unstemmed Effect of electron beam irradiation (EB) on gas barrier property of HDPE/EPDM nanocomposites
title_sort effect of electron beam irradiation (eb) on gas barrier property of hdpe/epdm nanocomposites
publisher Trans Tech Publications, Switzerland
publishDate 2011
url http://irep.iium.edu.my/2354/
http://irep.iium.edu.my/2354/
http://irep.iium.edu.my/2354/
http://irep.iium.edu.my/2354/1/KEM.471-472.775.pdf
first_indexed 2023-09-18T20:09:57Z
last_indexed 2023-09-18T20:09:57Z
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