Preparation and characterization of titania-cyanopropyltriethoxysilane sorbent for the extraction of polar aromatic amines

A new titanium(IV) butoxide-cyanopropyltriethoxysilane (Ti-CNPrTEOS) hybrid material was successfully synthesized for the use as sorbent for the extraction of polar aromatic amines. The sorbent was synthesized by hydrolysis and condensation of titanium(IV) butoxide and cyanopropyltriethoxysilan...

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Main Authors:	Miskam, Mazidatulakmam, Abu Bakar, Nor Kartini, Mohamad, Sharifah
Format:	Article
Language:	English
Published:	Springer Science+Business Media New York 2015
Subjects:	QD Chemistry
Online Access:	http://irep.iium.edu.my/43214/ http://irep.iium.edu.my/43214/ http://irep.iium.edu.my/43214/1/JSST_journal.pdf

id	iium-43214
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spelling	iium-432142015-06-09T00:55:48Z http://irep.iium.edu.my/43214/ Preparation and characterization of titania-cyanopropyltriethoxysilane sorbent for the extraction of polar aromatic amines Miskam, Mazidatulakmam Abu Bakar, Nor Kartini Mohamad, Sharifah QD Chemistry A new titanium(IV) butoxide-cyanopropyltriethoxysilane (Ti-CNPrTEOS) hybrid material was successfully synthesized for the use as sorbent for the extraction of polar aromatic amines. The sorbent was synthesized by hydrolysis and condensation of titanium(IV) butoxide and cyanopropyltriethoxysilane with the presence of hydrochloric acid as catalyst via sol–gel method. Several factors influencing the synthesized sorbent such as solvent selection, mol of water content, ratio of titanium(IV) butoxide and cyanopropyltriethoxysilane and aging temperature were investigated and optimized. The sorbents were characterized by fourier transform-infrared, field-emission scanning electron microscopy-energy, CHN elemental analysis and thermogravimetric analysis. The applicability of the sorbents for the extraction of polar aromatic amines by the batch sorption method was extensively studied and evaluated. Under the optimum synthesis conditions (tetrahydrofuran as solvent, 1.2 M of hydrochloric acid catalyst, 4 mol of water content with ratio of titanium(IV) butoxide and cyanopropylteriethoxysilane of 1:1 and aging temperature of 60 C), the extraction showed high recovery towards the extraction of polar aromatic amines. The synthesized sorbent was successfully applied for the extraction of selected aromatic amines via batch sorption method in waste water samples prior to the gas chromatography-flame ionization detector separation. The synthesized sol–gel Ti-CNPrTEOS sorbent demonstrated the potential as an alternative extraction sorbent with higher selectivity towards polar aromatic amines. Springer Science+Business Media New York 2015 Article PeerReviewed application/pdf en http://irep.iium.edu.my/43214/1/JSST_journal.pdf Miskam, Mazidatulakmam and Abu Bakar, Nor Kartini and Mohamad, Sharifah (2015) Preparation and characterization of titania-cyanopropyltriethoxysilane sorbent for the extraction of polar aromatic amines. Journal of Sol-Gel Science and Technology . pp. 1-9. ISSN 0928-0707 http://10.1007/s10971-013-3057-y
repository_type	Digital Repository
institution_category	Local University
institution	International Islamic University Malaysia
building	IIUM Repository
collection	Online Access
language	English
topic	QD Chemistry
spellingShingle	QD Chemistry Miskam, Mazidatulakmam Abu Bakar, Nor Kartini Mohamad, Sharifah Preparation and characterization of titania-cyanopropyltriethoxysilane sorbent for the extraction of polar aromatic amines
description	A new titanium(IV) butoxide-cyanopropyltriethoxysilane (Ti-CNPrTEOS) hybrid material was successfully synthesized for the use as sorbent for the extraction of polar aromatic amines. The sorbent was synthesized by hydrolysis and condensation of titanium(IV) butoxide and cyanopropyltriethoxysilane with the presence of hydrochloric acid as catalyst via sol–gel method. Several factors influencing the synthesized sorbent such as solvent selection, mol of water content, ratio of titanium(IV) butoxide and cyanopropyltriethoxysilane and aging temperature were investigated and optimized. The sorbents were characterized by fourier transform-infrared, field-emission scanning electron microscopy-energy, CHN elemental analysis and thermogravimetric analysis. The applicability of the sorbents for the extraction of polar aromatic amines by the batch sorption method was extensively studied and evaluated. Under the optimum synthesis conditions (tetrahydrofuran as solvent, 1.2 M of hydrochloric acid catalyst, 4 mol of water content with ratio of titanium(IV) butoxide and cyanopropylteriethoxysilane of 1:1 and aging temperature of 60 C), the extraction showed high recovery towards the extraction of polar aromatic amines. The synthesized sorbent was successfully applied for the extraction of selected aromatic amines via batch sorption method in waste water samples prior to the gas chromatography-flame ionization detector separation. The synthesized sol–gel Ti-CNPrTEOS sorbent demonstrated the potential as an alternative extraction sorbent with higher selectivity towards polar aromatic amines.
format	Article
author	Miskam, Mazidatulakmam Abu Bakar, Nor Kartini Mohamad, Sharifah
author_facet	Miskam, Mazidatulakmam Abu Bakar, Nor Kartini Mohamad, Sharifah
author_sort	Miskam, Mazidatulakmam
title	Preparation and characterization of titania-cyanopropyltriethoxysilane sorbent for the extraction of polar aromatic amines
title_short	Preparation and characterization of titania-cyanopropyltriethoxysilane sorbent for the extraction of polar aromatic amines
title_full	Preparation and characterization of titania-cyanopropyltriethoxysilane sorbent for the extraction of polar aromatic amines
title_fullStr	Preparation and characterization of titania-cyanopropyltriethoxysilane sorbent for the extraction of polar aromatic amines
title_full_unstemmed	Preparation and characterization of titania-cyanopropyltriethoxysilane sorbent for the extraction of polar aromatic amines
title_sort	preparation and characterization of titania-cyanopropyltriethoxysilane sorbent for the extraction of polar aromatic amines
publisher	Springer Science+Business Media New York
publishDate	2015
url	http://irep.iium.edu.my/43214/ http://irep.iium.edu.my/43214/ http://irep.iium.edu.my/43214/1/JSST_journal.pdf
first_indexed	2023-09-18T21:01:35Z
last_indexed	2023-09-18T21:01:35Z
_version_	1777410659408936960

Preparation and characterization of titania-cyanopropyltriethoxysilane sorbent for the extraction of polar aromatic amines

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