Determination of polar aromatic amines using newly synthesized sol-gel titanium (IV) butoxide cyanopropyltriethoxysilane as solid phase extraction sorbent

A solid phase extraction (SPE) method has been developed using a newly synthesized titanium (IV) butoxide-cyanopropyltriethoxysilane (Ti-CNPrTEOS) sorbent for polar selective extraction of aromatic amines in river water sample. The effect of different parameters on the extraction recovery was studie...

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Main Authors:	Miskam, Mazidatulakmam Akmam, Abu Bakar, Nor Kartini, Mohamad, Sharifah
Format:	Article
Language:	English English English
Published:	Elsevier BV 2014
Subjects:	QD Chemistry RA Public aspects of medicine TP Chemical technology
Online Access:	http://irep.iium.edu.my/58377/ http://irep.iium.edu.my/58377/ http://irep.iium.edu.my/58377/ http://irep.iium.edu.my/58377/1/58377_Determination%20of%20polar%20aromati.pdf http://irep.iium.edu.my/58377/2/58377_Determination%20of%20polar%20aromati_SCOPUS.pdf http://irep.iium.edu.my/58377/3/58377_Determination%20of%20polar%20aromati_WOS.pdf

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spelling	iium-583772017-09-18T01:18:06Z http://irep.iium.edu.my/58377/ Determination of polar aromatic amines using newly synthesized sol-gel titanium (IV) butoxide cyanopropyltriethoxysilane as solid phase extraction sorbent Miskam, Mazidatulakmam Akmam Abu Bakar, Nor Kartini Mohamad, Sharifah QD Chemistry RA Public aspects of medicine TP Chemical technology A solid phase extraction (SPE) method has been developed using a newly synthesized titanium (IV) butoxide-cyanopropyltriethoxysilane (Ti-CNPrTEOS) sorbent for polar selective extraction of aromatic amines in river water sample. The effect of different parameters on the extraction recovery was studied using the SPE method. The applicability of the sorbents for the extraction of polar aromatic amines by the SPE was extensively studied and evaluated as a function of pH, conditioning solvent, sample loading volume, elution solvent and elution solvent volume. The optimum experimental conditions were sample at pH 7, dichloromethane as conditioning solvent, 10 mL sample loading volume and 5 mL of acetonitrile as the eluting solvent. Under the optimum conditions, the limit of detection (LOD) and limit of quantification (LOQ) for solid phase extraction using Ti-CNPrTEOS SPE sorbent (0.01-0.2; 0.03-0.61 μgL-1) were lower compared with those achieved using Si-CN SPE sorbent (0.25-1.50; 1.96-3.59 μgL-1) and C18 SPE sorbent (0.37-0.98; 1.87-2.87 μgL -1) with higher selectivity towards the extraction of polar aromatic amines. The optimized procedure was successfully applied for the solid phase extraction method of selected aromatic amines in river water, waste water and tap water samples prior to the gas chromatography-flame ionization detector separation. Elsevier BV 2014-03 Article PeerReviewed application/pdf en http://irep.iium.edu.my/58377/1/58377_Determination%20of%20polar%20aromati.pdf application/pdf en http://irep.iium.edu.my/58377/2/58377_Determination%20of%20polar%20aromati_SCOPUS.pdf application/pdf en http://irep.iium.edu.my/58377/3/58377_Determination%20of%20polar%20aromati_WOS.pdf Miskam, Mazidatulakmam Akmam and Abu Bakar, Nor Kartini and Mohamad, Sharifah (2014) Determination of polar aromatic amines using newly synthesized sol-gel titanium (IV) butoxide cyanopropyltriethoxysilane as solid phase extraction sorbent. Talanta, 120. pp. 450-455. ISSN 0039-9140 E-ISSN 1873-3573 http://www.sciencedirect.com/science/article/pii/S0039914013010199?via%3Dihub#! 10.1016/j.talanta.2013.12.037
repository_type	Digital Repository
institution_category	Local University
institution	International Islamic University Malaysia
building	IIUM Repository
collection	Online Access
language	English English English
topic	QD Chemistry RA Public aspects of medicine TP Chemical technology
spellingShingle	QD Chemistry RA Public aspects of medicine TP Chemical technology Miskam, Mazidatulakmam Akmam Abu Bakar, Nor Kartini Mohamad, Sharifah Determination of polar aromatic amines using newly synthesized sol-gel titanium (IV) butoxide cyanopropyltriethoxysilane as solid phase extraction sorbent
description	A solid phase extraction (SPE) method has been developed using a newly synthesized titanium (IV) butoxide-cyanopropyltriethoxysilane (Ti-CNPrTEOS) sorbent for polar selective extraction of aromatic amines in river water sample. The effect of different parameters on the extraction recovery was studied using the SPE method. The applicability of the sorbents for the extraction of polar aromatic amines by the SPE was extensively studied and evaluated as a function of pH, conditioning solvent, sample loading volume, elution solvent and elution solvent volume. The optimum experimental conditions were sample at pH 7, dichloromethane as conditioning solvent, 10 mL sample loading volume and 5 mL of acetonitrile as the eluting solvent. Under the optimum conditions, the limit of detection (LOD) and limit of quantification (LOQ) for solid phase extraction using Ti-CNPrTEOS SPE sorbent (0.01-0.2; 0.03-0.61 μgL-1) were lower compared with those achieved using Si-CN SPE sorbent (0.25-1.50; 1.96-3.59 μgL-1) and C18 SPE sorbent (0.37-0.98; 1.87-2.87 μgL -1) with higher selectivity towards the extraction of polar aromatic amines. The optimized procedure was successfully applied for the solid phase extraction method of selected aromatic amines in river water, waste water and tap water samples prior to the gas chromatography-flame ionization detector separation.
format	Article
author	Miskam, Mazidatulakmam Akmam Abu Bakar, Nor Kartini Mohamad, Sharifah
author_facet	Miskam, Mazidatulakmam Akmam Abu Bakar, Nor Kartini Mohamad, Sharifah
author_sort	Miskam, Mazidatulakmam Akmam
title	Determination of polar aromatic amines using newly synthesized sol-gel titanium (IV) butoxide cyanopropyltriethoxysilane as solid phase extraction sorbent
title_short	Determination of polar aromatic amines using newly synthesized sol-gel titanium (IV) butoxide cyanopropyltriethoxysilane as solid phase extraction sorbent
title_full	Determination of polar aromatic amines using newly synthesized sol-gel titanium (IV) butoxide cyanopropyltriethoxysilane as solid phase extraction sorbent
title_fullStr	Determination of polar aromatic amines using newly synthesized sol-gel titanium (IV) butoxide cyanopropyltriethoxysilane as solid phase extraction sorbent
title_full_unstemmed	Determination of polar aromatic amines using newly synthesized sol-gel titanium (IV) butoxide cyanopropyltriethoxysilane as solid phase extraction sorbent
title_sort	determination of polar aromatic amines using newly synthesized sol-gel titanium (iv) butoxide cyanopropyltriethoxysilane as solid phase extraction sorbent
publisher	Elsevier BV
publishDate	2014
url	http://irep.iium.edu.my/58377/ http://irep.iium.edu.my/58377/ http://irep.iium.edu.my/58377/ http://irep.iium.edu.my/58377/1/58377_Determination%20of%20polar%20aromati.pdf http://irep.iium.edu.my/58377/2/58377_Determination%20of%20polar%20aromati_SCOPUS.pdf http://irep.iium.edu.my/58377/3/58377_Determination%20of%20polar%20aromati_WOS.pdf
first_indexed	2023-09-18T21:22:32Z
last_indexed	2023-09-18T21:22:32Z
_version_	1777411977786687488

Determination of polar aromatic amines using newly synthesized sol-gel titanium (IV) butoxide cyanopropyltriethoxysilane as solid phase extraction sorbent

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