Electron beam irradiated nanocomposite for gas barrier application

Polyolefin and layered silicate nanocomposites are expected to replace metals and high performance engineering thermoplastics with lower cost in future. Development of multifunctional nanocomposite system with enhanced mechanical properties, oxygen permeability resistance and flame retardant require...

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Main Authors:	Anuar, Hazleen, Jamal, Nur Ayuni, Abdul Razak, Shamsul Bahri
Format:	Conference or Workshop Item
Language:	English
Published:	2011
Subjects:	TS195 Packaging
Online Access:	http://irep.iium.edu.my/6765/ http://irep.iium.edu.my/6765/ http://irep.iium.edu.my/6765/1/IRIIE-ID_76.pdf

id	iium-6765
recordtype	eprints
spelling	iium-67652011-11-29T06:18:43Z http://irep.iium.edu.my/6765/ Electron beam irradiated nanocomposite for gas barrier application Anuar, Hazleen Jamal, Nur Ayuni Abdul Razak, Shamsul Bahri TS195 Packaging Polyolefin and layered silicate nanocomposites are expected to replace metals and high performance engineering thermoplastics with lower cost in future. Development of multifunctional nanocomposite system with enhanced mechanical properties, oxygen permeability resistance and flame retardant required excellent structural characteristic. To obtain such characteristics, the right selection of crosslinking methods and fabrication techniques play an important role. Electron beam irradiation is a popular method of crosslinking instead of chemical crosslinking due to fast process, pollution free, simple, and suitable for synthesis and modification of polymeric materials without the need of toxic additives. In this project, high density polyethylene (HDPE) and ethylene-propylene-diene-monomer (EPDM) blend is filled with organophilic montmorillonite (OMMT). The nanocomposites systems were prepared via intercalation technique with different OMMT loading. Two types of crosslinking techniques were applied; maleic anhydride polyethylene (MAPE) and electron beam (EB) irradiated system. The effectiveness of these systems were then compared with control specimen and analyzed for its mechanical, thermal, gas barrier properties and morphological examinations. The mechanical tests revealed that control, MAPE and EB irradiated systems had attained the optimum mechanical properties at 4 vol% OMMT content. The introduction of 4 vol% organophilic montmorillonite (OMMT) was found to further enhance the barrier property of nanocomposites. EB irradiated system at dose rate of 100 kGy showed excellent mechanical, thermal and gas barrier properties with highest crosslinking degree which were proved by gel content analysis. X-ray diffraction (XRD) analysis confirmed the existence of delamination structure with MAPE and EB irradiation techniques based on the disappearance of characteristic peak. The degree of delamination was further investigated by transmission electron microscope (TEM). On the other hand, field emission scanning electron microscope (FESEM) revealed the stacking condition of OMMT particles was greatly reduced with crosslinking agents particularly with EB irradiated system as evidenced by finer surface. 2011 Conference or Workshop Item PeerReviewed application/pdf en http://irep.iium.edu.my/6765/1/IRIIE-ID_76.pdf Anuar, Hazleen and Jamal, Nur Ayuni and Abdul Razak, Shamsul Bahri (2011) Electron beam irradiated nanocomposite for gas barrier application. In: IIUM Research, Invention and Innovation Exhibition IRIIE 2011, 9-10 February 2011, Kuala Lumpur, Malaysia. (Unpublished) http://www.iium.edu.my/irie/11/
repository_type	Digital Repository
institution_category	Local University
institution	International Islamic University Malaysia
building	IIUM Repository
collection	Online Access
language	English
topic	TS195 Packaging
spellingShingle	TS195 Packaging Anuar, Hazleen Jamal, Nur Ayuni Abdul Razak, Shamsul Bahri Electron beam irradiated nanocomposite for gas barrier application
description	Polyolefin and layered silicate nanocomposites are expected to replace metals and high performance engineering thermoplastics with lower cost in future. Development of multifunctional nanocomposite system with enhanced mechanical properties, oxygen permeability resistance and flame retardant required excellent structural characteristic. To obtain such characteristics, the right selection of crosslinking methods and fabrication techniques play an important role. Electron beam irradiation is a popular method of crosslinking instead of chemical crosslinking due to fast process, pollution free, simple, and suitable for synthesis and modification of polymeric materials without the need of toxic additives. In this project, high density polyethylene (HDPE) and ethylene-propylene-diene-monomer (EPDM) blend is filled with organophilic montmorillonite (OMMT). The nanocomposites systems were prepared via intercalation technique with different OMMT loading. Two types of crosslinking techniques were applied; maleic anhydride polyethylene (MAPE) and electron beam (EB) irradiated system. The effectiveness of these systems were then compared with control specimen and analyzed for its mechanical, thermal, gas barrier properties and morphological examinations. The mechanical tests revealed that control, MAPE and EB irradiated systems had attained the optimum mechanical properties at 4 vol% OMMT content. The introduction of 4 vol% organophilic montmorillonite (OMMT) was found to further enhance the barrier property of nanocomposites. EB irradiated system at dose rate of 100 kGy showed excellent mechanical, thermal and gas barrier properties with highest crosslinking degree which were proved by gel content analysis. X-ray diffraction (XRD) analysis confirmed the existence of delamination structure with MAPE and EB irradiation techniques based on the disappearance of characteristic peak. The degree of delamination was further investigated by transmission electron microscope (TEM). On the other hand, field emission scanning electron microscope (FESEM) revealed the stacking condition of OMMT particles was greatly reduced with crosslinking agents particularly with EB irradiated system as evidenced by finer surface.
format	Conference or Workshop Item
author	Anuar, Hazleen Jamal, Nur Ayuni Abdul Razak, Shamsul Bahri
author_facet	Anuar, Hazleen Jamal, Nur Ayuni Abdul Razak, Shamsul Bahri
author_sort	Anuar, Hazleen
title	Electron beam irradiated nanocomposite for gas barrier application
title_short	Electron beam irradiated nanocomposite for gas barrier application
title_full	Electron beam irradiated nanocomposite for gas barrier application
title_fullStr	Electron beam irradiated nanocomposite for gas barrier application
title_full_unstemmed	Electron beam irradiated nanocomposite for gas barrier application
title_sort	electron beam irradiated nanocomposite for gas barrier application
publishDate	2011
url	http://irep.iium.edu.my/6765/ http://irep.iium.edu.my/6765/ http://irep.iium.edu.my/6765/1/IRIIE-ID_76.pdf
first_indexed	2023-09-18T20:15:53Z
last_indexed	2023-09-18T20:15:53Z
_version_	1777407784591032320

Electron beam irradiated nanocomposite for gas barrier application

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