An investigation on the abnormal trend of the conductivity properties of CMC/PVA-doped NH4Cl-based solid biopolymer electrolyte system

The present work was carried out to investigate the abnormal trend of electrochemical properties of solid biopolymer electrolytes (SBEs) system-based carboxymethyl cellulose (CMC) blended with polyvinyl alcohol (PVA)-doped NH4Cl. The SBEs system was prepared via solution casting technique and analyz...

Full description

Bibliographic Details
Main Authors:	Mazuki, N.F., Fuzlin, A.F., Mohd. Ali, Noor Saadiah, Samsudin, Ahmad Salihin
Format:	Article
Language:	English English English
Published:	Institute for Ionics 2019
Subjects:	TP248.13 Biotechnology
Online Access:	http://irep.iium.edu.my/78685/ http://irep.iium.edu.my/78685/ http://irep.iium.edu.my/78685/ http://irep.iium.edu.my/78685/13/78685_An%20investigation%20on%20the%20abnormal%20trend_complete.pdf http://irep.iium.edu.my/78685/2/78685_An%20investigation%20on%20the%20abnormal%20trend_SCOPUS.pdf http://irep.iium.edu.my/78685/14/78685_An%20investigation%20on%20the%20abnormal%20trend_wos.pdf

id	iium-78685
recordtype	eprints
spelling	iium-786852020-02-20T04:33:17Z http://irep.iium.edu.my/78685/ An investigation on the abnormal trend of the conductivity properties of CMC/PVA-doped NH4Cl-based solid biopolymer electrolyte system Mazuki, N.F. Fuzlin, A.F. Mohd. Ali, Noor Saadiah Samsudin, Ahmad Salihin TP248.13 Biotechnology The present work was carried out to investigate the abnormal trend of electrochemical properties of solid biopolymer electrolytes (SBEs) system-based carboxymethyl cellulose (CMC) blended with polyvinyl alcohol (PVA)-doped NH4Cl. The SBEs system was prepared via solution casting technique and analyzed through Fourier transform infrared (FTIR) spectroscopy, thermogravimetric analysis (TGA), X-ray diffraction (XRD) analysis, and electrical impedance spectroscopy (EIS). Complexation was observed with the changes of peaks at 1065 cm−1, 1598 cm−1, 2912 cm−1, and 3396 cm−1 that corresponds to C–O–C, C=O of COO− stretching, C–H stretching, and O–H stretching, respectively, of CMC/PVA blend system upon the addition of NH4Cl. The decrease of the amorphousness and the increase of weight loss demonstrated the abnormal observation of the ionic conductivity when (1–5 wt%) NH4Cl was added in the SBEs system which was lower than the un-doped SBEs system. It was also observed that the highest ionic conductivity at 8.86 × 10−5 Scm−1 was achieved by the sample containing 6 wt% of NH4Cl. The temperature dependence of the SBEs system is found to be governed by the Arrhenius rule. Through the IR deconvolution technique, the conductivity of CMC/PVA-NH4Cl SBEs system was shown to be primarily influenced by the ionic mobility and diffusion coefficient of the ions. Institute for Ionics 2019-06-01 Article PeerReviewed application/pdf en http://irep.iium.edu.my/78685/13/78685_An%20investigation%20on%20the%20abnormal%20trend_complete.pdf application/pdf en http://irep.iium.edu.my/78685/2/78685_An%20investigation%20on%20the%20abnormal%20trend_SCOPUS.pdf application/pdf en http://irep.iium.edu.my/78685/14/78685_An%20investigation%20on%20the%20abnormal%20trend_wos.pdf Mazuki, N.F. and Fuzlin, A.F. and Mohd. Ali, Noor Saadiah and Samsudin, Ahmad Salihin (2019) An investigation on the abnormal trend of the conductivity properties of CMC/PVA-doped NH4Cl-based solid biopolymer electrolyte system. Ionics, 25 (6). pp. 2657-2667. ISSN 0947-7047 (In Press) https://link.springer.com/article/10.1007/s11581-018-2734-9 10.1007/s11581-018-2734-9
repository_type	Digital Repository
institution_category	Local University
institution	International Islamic University Malaysia
building	IIUM Repository
collection	Online Access
language	English English English
topic	TP248.13 Biotechnology
spellingShingle	TP248.13 Biotechnology Mazuki, N.F. Fuzlin, A.F. Mohd. Ali, Noor Saadiah Samsudin, Ahmad Salihin An investigation on the abnormal trend of the conductivity properties of CMC/PVA-doped NH4Cl-based solid biopolymer electrolyte system
description	The present work was carried out to investigate the abnormal trend of electrochemical properties of solid biopolymer electrolytes (SBEs) system-based carboxymethyl cellulose (CMC) blended with polyvinyl alcohol (PVA)-doped NH4Cl. The SBEs system was prepared via solution casting technique and analyzed through Fourier transform infrared (FTIR) spectroscopy, thermogravimetric analysis (TGA), X-ray diffraction (XRD) analysis, and electrical impedance spectroscopy (EIS). Complexation was observed with the changes of peaks at 1065 cm−1, 1598 cm−1, 2912 cm−1, and 3396 cm−1 that corresponds to C–O–C, C=O of COO− stretching, C–H stretching, and O–H stretching, respectively, of CMC/PVA blend system upon the addition of NH4Cl. The decrease of the amorphousness and the increase of weight loss demonstrated the abnormal observation of the ionic conductivity when (1–5 wt%) NH4Cl was added in the SBEs system which was lower than the un-doped SBEs system. It was also observed that the highest ionic conductivity at 8.86 × 10−5 Scm−1 was achieved by the sample containing 6 wt% of NH4Cl. The temperature dependence of the SBEs system is found to be governed by the Arrhenius rule. Through the IR deconvolution technique, the conductivity of CMC/PVA-NH4Cl SBEs system was shown to be primarily influenced by the ionic mobility and diffusion coefficient of the ions.
format	Article
author	Mazuki, N.F. Fuzlin, A.F. Mohd. Ali, Noor Saadiah Samsudin, Ahmad Salihin
author_facet	Mazuki, N.F. Fuzlin, A.F. Mohd. Ali, Noor Saadiah Samsudin, Ahmad Salihin
author_sort	Mazuki, N.F.
title	An investigation on the abnormal trend of the conductivity properties of CMC/PVA-doped NH4Cl-based solid biopolymer electrolyte system
title_short	An investigation on the abnormal trend of the conductivity properties of CMC/PVA-doped NH4Cl-based solid biopolymer electrolyte system
title_full	An investigation on the abnormal trend of the conductivity properties of CMC/PVA-doped NH4Cl-based solid biopolymer electrolyte system
title_fullStr	An investigation on the abnormal trend of the conductivity properties of CMC/PVA-doped NH4Cl-based solid biopolymer electrolyte system
title_full_unstemmed	An investigation on the abnormal trend of the conductivity properties of CMC/PVA-doped NH4Cl-based solid biopolymer electrolyte system
title_sort	investigation on the abnormal trend of the conductivity properties of cmc/pva-doped nh4cl-based solid biopolymer electrolyte system
publisher	Institute for Ionics
publishDate	2019
url	http://irep.iium.edu.my/78685/ http://irep.iium.edu.my/78685/ http://irep.iium.edu.my/78685/ http://irep.iium.edu.my/78685/13/78685_An%20investigation%20on%20the%20abnormal%20trend_complete.pdf http://irep.iium.edu.my/78685/2/78685_An%20investigation%20on%20the%20abnormal%20trend_SCOPUS.pdf http://irep.iium.edu.my/78685/14/78685_An%20investigation%20on%20the%20abnormal%20trend_wos.pdf
first_indexed	2023-09-18T21:50:50Z
last_indexed	2023-09-18T21:50:50Z
_version_	1777413757689921536

An investigation on the abnormal trend of the conductivity properties of CMC/PVA-doped NH4Cl-based solid biopolymer electrolyte system

Similar Items