Palm olein corrosion inhibitor for aluminium in Hcl solution / Junaidah Jai and Wan Shabuddin Wan Ali

Aluminium (Al) is a low cost, lightweight and corrosion resistant material, which corrodes when exposed to pitting agents. Palm olein exhibits characteristics, which indicate its suitability as a corrosion inhibitor. Tween 20, hexane and diethyl triamine were used as additives to Palm olein to form...

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Main Authors: Jai, Junaidah, Wan Ali, Wan Shabuddin
Format: Article
Language:English
Published: Research Management Institute (RMI) 2011
Subjects:
Online Access:http://ir.uitm.edu.my/id/eprint/12946/
http://ir.uitm.edu.my/id/eprint/12946/1/AJ_JUNAIDAH%20JAI%20SRJ%2011%201.pdf
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recordtype eprints
spelling uitm-129462016-05-30T02:37:51Z http://ir.uitm.edu.my/id/eprint/12946/ Palm olein corrosion inhibitor for aluminium in Hcl solution / Junaidah Jai and Wan Shabuddin Wan Ali Jai, Junaidah Wan Ali, Wan Shabuddin Polarization Corrosion and anti-corrosives Aluminum Adsorption Aluminium (Al) is a low cost, lightweight and corrosion resistant material, which corrodes when exposed to pitting agents. Palm olein exhibits characteristics, which indicate its suitability as a corrosion inhibitor. Tween 20, hexane and diethyl triamine were used as additives to Palm olein to form the inhibitor formulation POT20HA. The inhibition efficiency (IE) and behaviour of the POT20HA were determined using potentiodynamic polarization in which Al 6061 samples were immersed in a 1 M HCl solution at 26, 50 and 70 oC in the presence of different POT20HA concentrations: 0, 0.03, 0.07, 0.10, 0.13 and 0.17 M. The IE increased with increasing POT20HA concentration, but decreased with increasing temperature. The work presented indicates that POT20HA is a mixed-type inhibitor capable of inhibiting both corrosive anodic and cathodic reactions. According to the Langmuir isotherm results POT20HA adsorbs on the Al 6061 surface through semiphysiosorption and/or semi-chemisorption. The POT20HA adsorption mechanism on Al 6061 takes through the protonation of micelles by the HCl solution, whereby protonated micelles in the presence of chloride ions adsorb on both cathodic and anodic surface corrosion sites. Research Management Institute (RMI) 2011 Article PeerReviewed text en http://ir.uitm.edu.my/id/eprint/12946/1/AJ_JUNAIDAH%20JAI%20SRJ%2011%201.pdf Jai, Junaidah and Wan Ali, Wan Shabuddin (2011) Palm olein corrosion inhibitor for aluminium in Hcl solution / Junaidah Jai and Wan Shabuddin Wan Ali. Scientific Research Journal, 8 (2). pp. 49-70. ISSN 1675-7009
repository_type Digital Repository
institution_category Local University
institution Universiti Teknologi MARA
building UiTM Institutional Repository
collection Online Access
language English
topic Polarization
Corrosion and anti-corrosives
Aluminum
Adsorption
spellingShingle Polarization
Corrosion and anti-corrosives
Aluminum
Adsorption
Jai, Junaidah
Wan Ali, Wan Shabuddin
Palm olein corrosion inhibitor for aluminium in Hcl solution / Junaidah Jai and Wan Shabuddin Wan Ali
description Aluminium (Al) is a low cost, lightweight and corrosion resistant material, which corrodes when exposed to pitting agents. Palm olein exhibits characteristics, which indicate its suitability as a corrosion inhibitor. Tween 20, hexane and diethyl triamine were used as additives to Palm olein to form the inhibitor formulation POT20HA. The inhibition efficiency (IE) and behaviour of the POT20HA were determined using potentiodynamic polarization in which Al 6061 samples were immersed in a 1 M HCl solution at 26, 50 and 70 oC in the presence of different POT20HA concentrations: 0, 0.03, 0.07, 0.10, 0.13 and 0.17 M. The IE increased with increasing POT20HA concentration, but decreased with increasing temperature. The work presented indicates that POT20HA is a mixed-type inhibitor capable of inhibiting both corrosive anodic and cathodic reactions. According to the Langmuir isotherm results POT20HA adsorbs on the Al 6061 surface through semiphysiosorption and/or semi-chemisorption. The POT20HA adsorption mechanism on Al 6061 takes through the protonation of micelles by the HCl solution, whereby protonated micelles in the presence of chloride ions adsorb on both cathodic and anodic surface corrosion sites.
format Article
author Jai, Junaidah
Wan Ali, Wan Shabuddin
author_facet Jai, Junaidah
Wan Ali, Wan Shabuddin
author_sort Jai, Junaidah
title Palm olein corrosion inhibitor for aluminium in Hcl solution / Junaidah Jai and Wan Shabuddin Wan Ali
title_short Palm olein corrosion inhibitor for aluminium in Hcl solution / Junaidah Jai and Wan Shabuddin Wan Ali
title_full Palm olein corrosion inhibitor for aluminium in Hcl solution / Junaidah Jai and Wan Shabuddin Wan Ali
title_fullStr Palm olein corrosion inhibitor for aluminium in Hcl solution / Junaidah Jai and Wan Shabuddin Wan Ali
title_full_unstemmed Palm olein corrosion inhibitor for aluminium in Hcl solution / Junaidah Jai and Wan Shabuddin Wan Ali
title_sort palm olein corrosion inhibitor for aluminium in hcl solution / junaidah jai and wan shabuddin wan ali
publisher Research Management Institute (RMI)
publishDate 2011
url http://ir.uitm.edu.my/id/eprint/12946/
http://ir.uitm.edu.my/id/eprint/12946/1/AJ_JUNAIDAH%20JAI%20SRJ%2011%201.pdf
first_indexed 2023-09-18T22:49:36Z
last_indexed 2023-09-18T22:49:36Z
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