Optimisation of palm stearin, palm kernel oil and soybean oil blends for margarine formulations / Siti Hazirah Mohamad Fauzi

Palm stearin has limited application in natural form because of its high melting point, low plasticity and hence cannot be used directly in margarine production. Palm kernel oil contains short and medium triacylglycerols that can give desired melting characteristics and ensures the stable beta prime...

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Main Author: Mohamad Fauzi, Siti Hazirah
Format: Thesis
Language:English
Published: 2014
Subjects:
Online Access:http://ir.uitm.edu.my/id/eprint/15146/
http://ir.uitm.edu.my/id/eprint/15146/1/TM_SITI%20HAZIRAH%20MOHAMAD%20FAUZI%20AS%2014_5.pdf
id uitm-15146
recordtype eprints
spelling uitm-151462016-10-24T07:43:24Z http://ir.uitm.edu.my/id/eprint/15146/ Optimisation of palm stearin, palm kernel oil and soybean oil blends for margarine formulations / Siti Hazirah Mohamad Fauzi Mohamad Fauzi, Siti Hazirah Food processing and manufacture Special foods Palm oil Palm stearin has limited application in natural form because of its high melting point, low plasticity and hence cannot be used directly in margarine production. Palm kernel oil contains short and medium triacylglycerols that can give desired melting characteristics and ensures the stable beta prime (P') polymorph in products. To enhance the PS compatibility, it needs to be blended and/or interesterified with soybean oil to impart desirable properties to the final products. Blends of PS, PKO and SBO at certain proportions were formulated using a mixture design (Design Expert 8.0.4, 2010). All the 10 oil blends were subjected to chemical and enzymatic interesterification. The physicochemical, thermal, polymorphism, microstructural, textural properties and kinetics of isothermal crystallisation were studied. The interesterified (IE) blends had lower slip melting points and solid fat contents due to the randomisation in the TAGs. Interesterification also promotes significant alterations in the microstructural and polymorphism of blends, resulted in smaller crystals with P' form. The hardness of interesterified blends were reduced following the reaction. Interesterification also altered the mechanism of crystallisation kinetics of the blends, depending on the composition and the crystallisation temperatures. The optimisation of interesterified ternary blends for trans-free table (TM) and soft margarine (SM) formulations were conducted through graphical multiple responses in Design-Expert. The CIE and EIE for the TM formulation showed slightly different proportions of PS/PKO/SBO with 50/18/32 and 50/22/28 (w/w), while for SM formulation, both the interesterified blends give the same proportions of 51/0/49 (w/w) of PS/PKO/SBO. 2014 Thesis NonPeerReviewed text en http://ir.uitm.edu.my/id/eprint/15146/1/TM_SITI%20HAZIRAH%20MOHAMAD%20FAUZI%20AS%2014_5.pdf Mohamad Fauzi, Siti Hazirah (2014) Optimisation of palm stearin, palm kernel oil and soybean oil blends for margarine formulations / Siti Hazirah Mohamad Fauzi. Masters thesis, Universiti Teknologi MARA.
repository_type Digital Repository
institution_category Local University
institution Universiti Teknologi MARA
building UiTM Institutional Repository
collection Online Access
language English
topic Food processing and manufacture
Special foods
Palm oil
spellingShingle Food processing and manufacture
Special foods
Palm oil
Mohamad Fauzi, Siti Hazirah
Optimisation of palm stearin, palm kernel oil and soybean oil blends for margarine formulations / Siti Hazirah Mohamad Fauzi
description Palm stearin has limited application in natural form because of its high melting point, low plasticity and hence cannot be used directly in margarine production. Palm kernel oil contains short and medium triacylglycerols that can give desired melting characteristics and ensures the stable beta prime (P') polymorph in products. To enhance the PS compatibility, it needs to be blended and/or interesterified with soybean oil to impart desirable properties to the final products. Blends of PS, PKO and SBO at certain proportions were formulated using a mixture design (Design Expert 8.0.4, 2010). All the 10 oil blends were subjected to chemical and enzymatic interesterification. The physicochemical, thermal, polymorphism, microstructural, textural properties and kinetics of isothermal crystallisation were studied. The interesterified (IE) blends had lower slip melting points and solid fat contents due to the randomisation in the TAGs. Interesterification also promotes significant alterations in the microstructural and polymorphism of blends, resulted in smaller crystals with P' form. The hardness of interesterified blends were reduced following the reaction. Interesterification also altered the mechanism of crystallisation kinetics of the blends, depending on the composition and the crystallisation temperatures. The optimisation of interesterified ternary blends for trans-free table (TM) and soft margarine (SM) formulations were conducted through graphical multiple responses in Design-Expert. The CIE and EIE for the TM formulation showed slightly different proportions of PS/PKO/SBO with 50/18/32 and 50/22/28 (w/w), while for SM formulation, both the interesterified blends give the same proportions of 51/0/49 (w/w) of PS/PKO/SBO.
format Thesis
author Mohamad Fauzi, Siti Hazirah
author_facet Mohamad Fauzi, Siti Hazirah
author_sort Mohamad Fauzi, Siti Hazirah
title Optimisation of palm stearin, palm kernel oil and soybean oil blends for margarine formulations / Siti Hazirah Mohamad Fauzi
title_short Optimisation of palm stearin, palm kernel oil and soybean oil blends for margarine formulations / Siti Hazirah Mohamad Fauzi
title_full Optimisation of palm stearin, palm kernel oil and soybean oil blends for margarine formulations / Siti Hazirah Mohamad Fauzi
title_fullStr Optimisation of palm stearin, palm kernel oil and soybean oil blends for margarine formulations / Siti Hazirah Mohamad Fauzi
title_full_unstemmed Optimisation of palm stearin, palm kernel oil and soybean oil blends for margarine formulations / Siti Hazirah Mohamad Fauzi
title_sort optimisation of palm stearin, palm kernel oil and soybean oil blends for margarine formulations / siti hazirah mohamad fauzi
publishDate 2014
url http://ir.uitm.edu.my/id/eprint/15146/
http://ir.uitm.edu.my/id/eprint/15146/1/TM_SITI%20HAZIRAH%20MOHAMAD%20FAUZI%20AS%2014_5.pdf
first_indexed 2023-09-18T22:53:12Z
last_indexed 2023-09-18T22:53:12Z
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