Inhibitive effect of schiff bases on corrosion of mild steel in hydrocloric acid solution / Mohd Shahril Anoar

The syntheses of Schiff base compounds using 4-hydroxybenzaldehyde and 4-chlorobenzaldehyde with N-phenyl-1,4-phenylenediamine have yielded two green semi-crystalline compounds. The characterization of the compounds is performed by infrared spectroscopy, NMR spectroscopy and elemental analysis. All...

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Main Author: Anoar, Mohd Shahril
Format: Student Project
Language:English
Published: Faculty of Applied Sciences 2009
Subjects:
Online Access:http://ir.uitm.edu.my/id/eprint/23130/
http://ir.uitm.edu.my/id/eprint/23130/1/PPb_MOHD%20SHAHRIL%20ANOAR%20AS%2009_5.pdf
id uitm-23130
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spelling uitm-231302019-02-25T07:07:17Z http://ir.uitm.edu.my/id/eprint/23130/ Inhibitive effect of schiff bases on corrosion of mild steel in hydrocloric acid solution / Mohd Shahril Anoar Anoar, Mohd Shahril Schiff bases The syntheses of Schiff base compounds using 4-hydroxybenzaldehyde and 4-chlorobenzaldehyde with N-phenyl-1,4-phenylenediamine have yielded two green semi-crystalline compounds. The characterization of the compounds is performed by infrared spectroscopy, NMR spectroscopy and elemental analysis. All the analyses have positively indicated the successful formation of the desired compounds. Weight loss measurement method have been used to study the inhibition effect of the Schiff bases 4-{(Z)-[(4-anilinophenyl)]imino]methyl}phenol (4-hbnp) and N-[(1Z)-(4- chlorophenyl)methylene]-N’-phenylbenzene-1,4-diamine (4-cbnp) on the corrosion of mild steel in 1 M HCl. Results show that both compounds possess excellent corrosion inhibition efficiency at the maximum values of 91.20 % and 95.37 %, respectively, increases with increasing concentration of the Schiff bases. The 4-hbnp reaches maximum inhibition efficiency (91.20 %) at 1 x 10⁻² M whereas 4-cbnp reaches the highest inhibition efficiency (95.37 %) at 1 x 10⁻² M. It is suggested that the corrosion inhibition on mild steel through adsorption is affected largely by the anchoring factor which seems to have played a more prominent role in the inhibiting property of the Schiff bases than the π-ring factor. Faculty of Applied Sciences 2009 Student Project NonPeerReviewed text en http://ir.uitm.edu.my/id/eprint/23130/1/PPb_MOHD%20SHAHRIL%20ANOAR%20AS%2009_5.pdf Anoar, Mohd Shahril (2009) Inhibitive effect of schiff bases on corrosion of mild steel in hydrocloric acid solution / Mohd Shahril Anoar. [Student Project] (Unpublished)
repository_type Digital Repository
institution_category Local University
institution Universiti Teknologi MARA
building UiTM Institutional Repository
collection Online Access
language English
topic Schiff bases
spellingShingle Schiff bases
Anoar, Mohd Shahril
Inhibitive effect of schiff bases on corrosion of mild steel in hydrocloric acid solution / Mohd Shahril Anoar
description The syntheses of Schiff base compounds using 4-hydroxybenzaldehyde and 4-chlorobenzaldehyde with N-phenyl-1,4-phenylenediamine have yielded two green semi-crystalline compounds. The characterization of the compounds is performed by infrared spectroscopy, NMR spectroscopy and elemental analysis. All the analyses have positively indicated the successful formation of the desired compounds. Weight loss measurement method have been used to study the inhibition effect of the Schiff bases 4-{(Z)-[(4-anilinophenyl)]imino]methyl}phenol (4-hbnp) and N-[(1Z)-(4- chlorophenyl)methylene]-N’-phenylbenzene-1,4-diamine (4-cbnp) on the corrosion of mild steel in 1 M HCl. Results show that both compounds possess excellent corrosion inhibition efficiency at the maximum values of 91.20 % and 95.37 %, respectively, increases with increasing concentration of the Schiff bases. The 4-hbnp reaches maximum inhibition efficiency (91.20 %) at 1 x 10⁻² M whereas 4-cbnp reaches the highest inhibition efficiency (95.37 %) at 1 x 10⁻² M. It is suggested that the corrosion inhibition on mild steel through adsorption is affected largely by the anchoring factor which seems to have played a more prominent role in the inhibiting property of the Schiff bases than the π-ring factor.
format Student Project
author Anoar, Mohd Shahril
author_facet Anoar, Mohd Shahril
author_sort Anoar, Mohd Shahril
title Inhibitive effect of schiff bases on corrosion of mild steel in hydrocloric acid solution / Mohd Shahril Anoar
title_short Inhibitive effect of schiff bases on corrosion of mild steel in hydrocloric acid solution / Mohd Shahril Anoar
title_full Inhibitive effect of schiff bases on corrosion of mild steel in hydrocloric acid solution / Mohd Shahril Anoar
title_fullStr Inhibitive effect of schiff bases on corrosion of mild steel in hydrocloric acid solution / Mohd Shahril Anoar
title_full_unstemmed Inhibitive effect of schiff bases on corrosion of mild steel in hydrocloric acid solution / Mohd Shahril Anoar
title_sort inhibitive effect of schiff bases on corrosion of mild steel in hydrocloric acid solution / mohd shahril anoar
publisher Faculty of Applied Sciences
publishDate 2009
url http://ir.uitm.edu.my/id/eprint/23130/
http://ir.uitm.edu.my/id/eprint/23130/1/PPb_MOHD%20SHAHRIL%20ANOAR%20AS%2009_5.pdf
first_indexed 2023-09-18T23:10:07Z
last_indexed 2023-09-18T23:10:07Z
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