Synthesis and characterization of plasticized carboxymethyl cellulose based solid biopolymer electrolyte / Fitriyah Munirah Abdullah
In this study, solid biopolymer electrolyte (SBE) has been prepared using carboxymethyl cellulose (CMC) and ammonium chloride (AC) by solution casting method. The effect of plasticizers ; ethylene carbonate (BC) and propylene carbonate (PC) was investigated. The ionic conductivity of CMC-AC-EC an...
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Format: | Student Project |
Language: | English |
Published: |
Faculty of Applied Sciences
2017
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Online Access: | http://ir.uitm.edu.my/id/eprint/23943/ http://ir.uitm.edu.my/id/eprint/23943/1/PPb_FITRIYAH%20MUNIRAH%20ABDULLAH%20AS%20C%2017_5.PDF |
Summary: | In this study, solid biopolymer electrolyte (SBE) has been prepared using
carboxymethyl cellulose (CMC) and ammonium chloride (AC) by solution casting
method. The effect of plasticizers ; ethylene carbonate (BC) and propylene carbonate
(PC) was investigated. The ionic conductivity of CMC-AC-EC and CMC-AC-PC
achieved at 2.715 x 10-5 Scm-1 and 3.672 x 10-5 Scm-1, respectively. The Fourier
Transform Infrared (FTIR) spectra showed the occurrence of complexation between
the SBE and AC salt. X-Ray diffraction (XRD) indicated that amorphous nature is
higher in CMC-AC-PC. Differential Scanning Calorimetry (DSC) showed higher
Tg for CMC-AC-PC. It can be concluded that PC is the promising plasticizer to
enhance the ionic conductivity and performance of SBE system. |
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