Synthesis, characterization and adsorption study of C-4-phenacyloxy-phenylcalix[4]resorcinarene for Pb(II), Cd(II) and Cr(III) ions

C-4-phenacyloxy phenyl calix[4]resorcinarene (CPPCR) was synthesized by acidic condensation of 4-hydroxybenzaldehyde and resorcinol. The adsorption of CPPCR for Pb(II), Cd(II) and Cr(III) has been studied by measuring the metal concentration in aqueous solution using Atomic Absorption Spectrophotome...

Full description

Bibliographic Details
Main Authors:	Rastuti, Undri, Siswanta, Dwi, Pambudi, Wisnu, Nurohmah, Beta Achromi, Bohari M. Yamin, Jumina
Format:	Article
Language:	English
Published:	Penerbit Universiti Kebangsaan Malaysia 2018
Online Access:	http://journalarticle.ukm.my/12121/ http://journalarticle.ukm.my/12121/ http://journalarticle.ukm.my/12121/1/12%20Undri%20Rastuti.pdf

id	ukm-12121
recordtype	eprints
spelling	ukm-121212018-09-28T22:17:28Z http://journalarticle.ukm.my/12121/ Synthesis, characterization and adsorption study of C-4-phenacyloxy-phenylcalix[4]resorcinarene for Pb(II), Cd(II) and Cr(III) ions Rastuti, Undri Siswanta, Dwi Pambudi, Wisnu Nurohmah, Beta Achromi Bohari M. Yamin, Jumina, C-4-phenacyloxy phenyl calix[4]resorcinarene (CPPCR) was synthesized by acidic condensation of 4-hydroxybenzaldehyde and resorcinol. The adsorption of CPPCR for Pb(II), Cd(II) and Cr(III) has been studied by measuring the metal concentration in aqueous solution using Atomic Absorption Spectrophotometry (AAS). The effects of solution pH, contact time and initial concentration of metal ions on the adsorption capacity of CPPCR were investigated. The adsorption kinetic of all the ions obeyed the Ho and McKay pseudo 2nd order rate law and the adsorption isotherm profile matched very well with Langmuir model. The separation factor (RL) of CPPCR for Pb(II), Cd(II) and Cr(III) were 0.190, 0.017, and 0.065, respectively, indicating the formation of monolayer behaviour. The Gibb free energy (ΔG) of the adsorption for all the metal ions have negative values indicating the adsorption process of Pb(II), Cd(II) and Cr(III) by CPPCR are spontaneous. Penerbit Universiti Kebangsaan Malaysia 2018-06 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/12121/1/12%20Undri%20Rastuti.pdf Rastuti, Undri and Siswanta, Dwi and Pambudi, Wisnu and Nurohmah, Beta Achromi and Bohari M. Yamin, and Jumina, (2018) Synthesis, characterization and adsorption study of C-4-phenacyloxy-phenylcalix[4]resorcinarene for Pb(II), Cd(II) and Cr(III) ions. Sains Malaysiana, 47 (6). pp. 1167-1179. ISSN 0126-6039 http://www.ukm.my/jsm/malay_journals/jilid47bil6_2018/KandunganJilid47Bil6_2018.html
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Kebangasaan Malaysia
building	UKM Institutional Repository
collection	Online Access
language	English
description	C-4-phenacyloxy phenyl calix[4]resorcinarene (CPPCR) was synthesized by acidic condensation of 4-hydroxybenzaldehyde and resorcinol. The adsorption of CPPCR for Pb(II), Cd(II) and Cr(III) has been studied by measuring the metal concentration in aqueous solution using Atomic Absorption Spectrophotometry (AAS). The effects of solution pH, contact time and initial concentration of metal ions on the adsorption capacity of CPPCR were investigated. The adsorption kinetic of all the ions obeyed the Ho and McKay pseudo 2nd order rate law and the adsorption isotherm profile matched very well with Langmuir model. The separation factor (RL) of CPPCR for Pb(II), Cd(II) and Cr(III) were 0.190, 0.017, and 0.065, respectively, indicating the formation of monolayer behaviour. The Gibb free energy (ΔG) of the adsorption for all the metal ions have negative values indicating the adsorption process of Pb(II), Cd(II) and Cr(III) by CPPCR are spontaneous.
format	Article
author	Rastuti, Undri Siswanta, Dwi Pambudi, Wisnu Nurohmah, Beta Achromi Bohari M. Yamin, Jumina,
spellingShingle	Rastuti, Undri Siswanta, Dwi Pambudi, Wisnu Nurohmah, Beta Achromi Bohari M. Yamin, Jumina, Synthesis, characterization and adsorption study of C-4-phenacyloxy-phenylcalix[4]resorcinarene for Pb(II), Cd(II) and Cr(III) ions
author_facet	Rastuti, Undri Siswanta, Dwi Pambudi, Wisnu Nurohmah, Beta Achromi Bohari M. Yamin, Jumina,
author_sort	Rastuti, Undri
title	Synthesis, characterization and adsorption study of C-4-phenacyloxy-phenylcalix[4]resorcinarene for Pb(II), Cd(II) and Cr(III) ions
title_short	Synthesis, characterization and adsorption study of C-4-phenacyloxy-phenylcalix[4]resorcinarene for Pb(II), Cd(II) and Cr(III) ions
title_full	Synthesis, characterization and adsorption study of C-4-phenacyloxy-phenylcalix[4]resorcinarene for Pb(II), Cd(II) and Cr(III) ions
title_fullStr	Synthesis, characterization and adsorption study of C-4-phenacyloxy-phenylcalix[4]resorcinarene for Pb(II), Cd(II) and Cr(III) ions
title_full_unstemmed	Synthesis, characterization and adsorption study of C-4-phenacyloxy-phenylcalix[4]resorcinarene for Pb(II), Cd(II) and Cr(III) ions
title_sort	synthesis, characterization and adsorption study of c-4-phenacyloxy-phenylcalix[4]resorcinarene for pb(ii), cd(ii) and cr(iii) ions
publisher	Penerbit Universiti Kebangsaan Malaysia
publishDate	2018
url	http://journalarticle.ukm.my/12121/ http://journalarticle.ukm.my/12121/ http://journalarticle.ukm.my/12121/1/12%20Undri%20Rastuti.pdf
first_indexed	2023-09-18T20:01:54Z
last_indexed	2023-09-18T20:01:54Z
_version_	1777406904451989504

Synthesis, characterization and adsorption study of C-4-phenacyloxy-phenylcalix[4]resorcinarene for Pb(II), Cd(II) and Cr(III) ions

Similar Items