Electrochemical behaviour of Ni and Ni-PVC electrodes for the electroxidation of ethanol (Tingkah Laku Elektrokimia Pengoksidaan Etanol Menggunakan Elektrod Ni dan Ni-PVC)

In this study, two nickel based electrodes were prepared; nickel foil and nickel-polyvinylchloride (Ni-PVC), in order to study their electrochemical behavior using cyclic voltammetry, CV and chronocoulometry, CC. Ni electrode was prepared from Ni metal foil while Ni-PVC electrode was prepared by mix...

Full description

Bibliographic Details
Main Authors:	Mohd Syafiq Hamdan, Norazzizi Nordin, Siti Fathrita Mohd Amir, Riyanto, Mohamed Rozali Othman
Format:	Article
Language:	English
Published:	Universiti Kebangsaan Malaysia 2011
Online Access:	http://journalarticle.ukm.my/3143/ http://journalarticle.ukm.my/3143/ http://journalarticle.ukm.my/3143/1/12_Mohd_Syafiq.pdf

id	ukm-3143
recordtype	eprints
spelling	ukm-31432016-12-14T06:33:44Z http://journalarticle.ukm.my/3143/ Electrochemical behaviour of Ni and Ni-PVC electrodes for the electroxidation of ethanol (Tingkah Laku Elektrokimia Pengoksidaan Etanol Menggunakan Elektrod Ni dan Ni-PVC) Mohd Syafiq Hamdan, Norazzizi Nordin, Siti Fathrita Mohd Amir, Riyanto, Mohamed Rozali Othman, In this study, two nickel based electrodes were prepared; nickel foil and nickel-polyvinylchloride (Ni-PVC), in order to study their electrochemical behavior using cyclic voltammetry, CV and chronocoulometry, CC. Ni electrode was prepared from Ni metal foil while Ni-PVC electrode was prepared by mixing a weighed portion of Ni powder and PVC in THF solvent, swirled until the suspension was homogeneous and drying the suspension in an oven at 50oC for 3 h. The dry sample was then placed in a 1 cm diameter stainless steel mould and pressed at 10 ton/cm2. From CV data, Ni-PVC electrode showed a better electrochemical behavior compared to Ni metal foil electrode. The use of Ni-PVC electrode at higher concentration of supporting electrolyte (1.0 M KOH) was better than at lower concentration of the same supporting electrolyte in electroxidation of ethanol. In addition to acetic acid, the oxidation of ethanol also produced ethyl acetate and acetaldehyde. Universiti Kebangsaan Malaysia 2011-12 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/3143/1/12_Mohd_Syafiq.pdf Mohd Syafiq Hamdan, and Norazzizi Nordin, and Siti Fathrita Mohd Amir, and Riyanto, and Mohamed Rozali Othman, (2011) Electrochemical behaviour of Ni and Ni-PVC electrodes for the electroxidation of ethanol (Tingkah Laku Elektrokimia Pengoksidaan Etanol Menggunakan Elektrod Ni dan Ni-PVC). Sains Malaysiana, 40 (12). pp. 1421-1427. ISSN 0126-6039 http//:www.ukm.my/jsm/
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Kebangasaan Malaysia
building	UKM Institutional Repository
collection	Online Access
language	English
description	In this study, two nickel based electrodes were prepared; nickel foil and nickel-polyvinylchloride (Ni-PVC), in order to study their electrochemical behavior using cyclic voltammetry, CV and chronocoulometry, CC. Ni electrode was prepared from Ni metal foil while Ni-PVC electrode was prepared by mixing a weighed portion of Ni powder and PVC in THF solvent, swirled until the suspension was homogeneous and drying the suspension in an oven at 50oC for 3 h. The dry sample was then placed in a 1 cm diameter stainless steel mould and pressed at 10 ton/cm2. From CV data, Ni-PVC electrode showed a better electrochemical behavior compared to Ni metal foil electrode. The use of Ni-PVC electrode at higher concentration of supporting electrolyte (1.0 M KOH) was better than at lower concentration of the same supporting electrolyte in electroxidation of ethanol. In addition to acetic acid, the oxidation of ethanol also produced ethyl acetate and acetaldehyde.
format	Article
author	Mohd Syafiq Hamdan, Norazzizi Nordin, Siti Fathrita Mohd Amir, Riyanto, Mohamed Rozali Othman,
spellingShingle	Mohd Syafiq Hamdan, Norazzizi Nordin, Siti Fathrita Mohd Amir, Riyanto, Mohamed Rozali Othman, Electrochemical behaviour of Ni and Ni-PVC electrodes for the electroxidation of ethanol (Tingkah Laku Elektrokimia Pengoksidaan Etanol Menggunakan Elektrod Ni dan Ni-PVC)
author_facet	Mohd Syafiq Hamdan, Norazzizi Nordin, Siti Fathrita Mohd Amir, Riyanto, Mohamed Rozali Othman,
author_sort	Mohd Syafiq Hamdan,
title	Electrochemical behaviour of Ni and Ni-PVC electrodes for the electroxidation of ethanol (Tingkah Laku Elektrokimia Pengoksidaan Etanol Menggunakan Elektrod Ni dan Ni-PVC)
title_short	Electrochemical behaviour of Ni and Ni-PVC electrodes for the electroxidation of ethanol (Tingkah Laku Elektrokimia Pengoksidaan Etanol Menggunakan Elektrod Ni dan Ni-PVC)
title_full	Electrochemical behaviour of Ni and Ni-PVC electrodes for the electroxidation of ethanol (Tingkah Laku Elektrokimia Pengoksidaan Etanol Menggunakan Elektrod Ni dan Ni-PVC)
title_fullStr	Electrochemical behaviour of Ni and Ni-PVC electrodes for the electroxidation of ethanol (Tingkah Laku Elektrokimia Pengoksidaan Etanol Menggunakan Elektrod Ni dan Ni-PVC)
title_full_unstemmed	Electrochemical behaviour of Ni and Ni-PVC electrodes for the electroxidation of ethanol (Tingkah Laku Elektrokimia Pengoksidaan Etanol Menggunakan Elektrod Ni dan Ni-PVC)
title_sort	electrochemical behaviour of ni and ni-pvc electrodes for the electroxidation of ethanol (tingkah laku elektrokimia pengoksidaan etanol menggunakan elektrod ni dan ni-pvc)
publisher	Universiti Kebangsaan Malaysia
publishDate	2011
url	http://journalarticle.ukm.my/3143/ http://journalarticle.ukm.my/3143/ http://journalarticle.ukm.my/3143/1/12_Mohd_Syafiq.pdf
first_indexed	2023-09-18T19:37:59Z
last_indexed	2023-09-18T19:37:59Z
_version_	1777405400049516544

Electrochemical behaviour of Ni and Ni-PVC electrodes for the electroxidation of ethanol (Tingkah Laku Elektrokimia Pengoksidaan Etanol Menggunakan Elektrod Ni dan Ni-PVC)

Similar Items