Synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(III) ethylbutyldithiocarbamate

A new series of ethylbutyldithiocarbamate compounds have been synthesized. The compounds made of Zn(II), Cu(II), Ni(II), Pb(II), Sb(III) and Bi(III) were prepared by reacting the respective metal salts with ethylbutylamine and carbon disulphide using "in situ" method. Results of elemental...

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Main Authors:	Karimah Kassim, Ibrahim Baba, Yang Farina, Abdul Hamid Othman, H.K. Fun
Format:	Article
Published:	Universiti Kebangsaan Malaysia 2002
Online Access:	http://journalarticle.ukm.my/3827/ http://journalarticle.ukm.my/3827/

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spelling	ukm-38272012-05-04T04:14:55Z http://journalarticle.ukm.my/3827/ Synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(III) ethylbutyldithiocarbamate Karimah Kassim, Ibrahim Baba, Yang Farina , Abdul Hamid Othman, H.K. Fun, A new series of ethylbutyldithiocarbamate compounds have been synthesized. The compounds made of Zn(II), Cu(II), Ni(II), Pb(II), Sb(III) and Bi(III) were prepared by reacting the respective metal salts with ethylbutylamine and carbon disulphide using "in situ" method. Results of elemental analysis showed that the isolated compounds have the general formula, M[S2CNR1RZ2]n (n = 2; M = Zn(II), Cu(II), Ni(II), Pb(II), and n = 3; M = Sb(III) and Bi(III)). Infrared spectra of the compounds showed the thioureido v(C-N) bands in the regions 1468 – 1497 cm-1. The (C-S) bands appeared in the region 956 – 997 cm-1 while the v(M-S) bands appeared in the region 300 – 400 cm-1. The 1H NMR signals indicated ethyl- and butyl- in the region 0.40 – 3.85 ppm. The 13C NMR spectra of zinc(II) and lead(II) showed a resonance in the region 202.0 ppm, which attributed to the carbon atom of NCS2 group. Tris(N-ethyl-N-butyldithiocarbamato-S) bismuth(III) is pentagonal pyramid distorted with triclinic system with P1, a = 10.5120(1)Å, b = 10.5128(1)Å, b = 10.5128(1)Å, c = 14.5755(1)Å, α = 99.927(1)o, γ = 103.3383(1) and Z = 2. Universiti Kebangsaan Malaysia 2002 Article PeerReviewed Karimah Kassim, and Ibrahim Baba, and Yang Farina , and Abdul Hamid Othman, and H.K. Fun, (2002) Synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(III) ethylbutyldithiocarbamate. Sains Malaysiana, 31 . pp. 101-108. ISSN 0126-6039 http://www.ukm.my/jsm/english_journals/vol31_2002/vol31_02page101-108.html
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Kebangasaan Malaysia
building	UKM Institutional Repository
collection	Online Access
description	A new series of ethylbutyldithiocarbamate compounds have been synthesized. The compounds made of Zn(II), Cu(II), Ni(II), Pb(II), Sb(III) and Bi(III) were prepared by reacting the respective metal salts with ethylbutylamine and carbon disulphide using "in situ" method. Results of elemental analysis showed that the isolated compounds have the general formula, M[S2CNR1RZ2]n (n = 2; M = Zn(II), Cu(II), Ni(II), Pb(II), and n = 3; M = Sb(III) and Bi(III)). Infrared spectra of the compounds showed the thioureido v(C-N) bands in the regions 1468 – 1497 cm-1. The (C-S) bands appeared in the region 956 – 997 cm-1 while the v(M-S) bands appeared in the region 300 – 400 cm-1. The 1H NMR signals indicated ethyl- and butyl- in the region 0.40 – 3.85 ppm. The 13C NMR spectra of zinc(II) and lead(II) showed a resonance in the region 202.0 ppm, which attributed to the carbon atom of NCS2 group. Tris(N-ethyl-N-butyldithiocarbamato-S) bismuth(III) is pentagonal pyramid distorted with triclinic system with P1, a = 10.5120(1)Å, b = 10.5128(1)Å, b = 10.5128(1)Å, c = 14.5755(1)Å, α = 99.927(1)o, γ = 103.3383(1) and Z = 2.
format	Article
author	Karimah Kassim, Ibrahim Baba, Yang Farina , Abdul Hamid Othman, H.K. Fun,
spellingShingle	Karimah Kassim, Ibrahim Baba, Yang Farina , Abdul Hamid Othman, H.K. Fun, Synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(III) ethylbutyldithiocarbamate
author_facet	Karimah Kassim, Ibrahim Baba, Yang Farina , Abdul Hamid Othman, H.K. Fun,
author_sort	Karimah Kassim,
title	Synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(III) ethylbutyldithiocarbamate
title_short	Synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(III) ethylbutyldithiocarbamate
title_full	Synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(III) ethylbutyldithiocarbamate
title_fullStr	Synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(III) ethylbutyldithiocarbamate
title_full_unstemmed	Synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(III) ethylbutyldithiocarbamate
title_sort	synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(iii) ethylbutyldithiocarbamate
publisher	Universiti Kebangsaan Malaysia
publishDate	2002
url	http://journalarticle.ukm.my/3827/ http://journalarticle.ukm.my/3827/
first_indexed	2023-09-18T19:39:52Z
last_indexed	2023-09-18T19:39:52Z
_version_	1777405518505050112

Synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(III) ethylbutyldithiocarbamate

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