Synthesis and characterisation of some diorganotin bis(N- methyl 0-nitrobenzohydroxamate)

Diorganotin(IV) complexes of N-methyl o-nitrobenzohydroxamic acid were synthesised by refluxing diorganotin(IV) oxide and the free ligand using a Dean and Stark water separator. The N-methyl o-nitrobenzohydroxamic acid was derived from the corresponding o-nitrobenzoyl chloride and Nmethylhydroxylam...

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Main Authors:	Elhadi Elba Saad, Y. Farina, Ibrahim Baba, Abdul Hamid Othman
Format:	Article
Published:	Universiti Kebangsaan Malaysia 2003
Online Access:	http://journalarticle.ukm.my/3858/ http://journalarticle.ukm.my/3858/

id	ukm-3858
recordtype	eprints
spelling	ukm-38582012-03-22T01:40:49Z http://journalarticle.ukm.my/3858/ Synthesis and characterisation of some diorganotin bis(N- methyl 0-nitrobenzohydroxamate) Elhadi Elba Saad, Y. Farina, Ibrahim Baba, Abdul Hamid Othman, Diorganotin(IV) complexes of N-methyl o-nitrobenzohydroxamic acid were synthesised by refluxing diorganotin(IV) oxide and the free ligand using a Dean and Stark water separator. The N-methyl o-nitrobenzohydroxamic acid was derived from the corresponding o-nitrobenzoyl chloride and Nmethylhydroxylamine in the presence of sodium hydrogen carbonate. The isolated complexes were characterized by elemental analysis and spectroscopic methods such as infrared, lH and 13C nuclear magnetic resonance. Results of analysis carried out on the diorganotin(IV) complexes of N-methyl onitrobenzohydroxamic acid showed a 1:2 stoichiometry with general formula R2Sn[O-NO2C6P4CONCH3O]2 (R= methyl, n-butyl and phenyl). The coordination mode occurs by deprotonation of the hydroxy group and subsequent (0,0) coordination of the carbonyl oxygen. Attempted recrystallization of ndibutyltin(IV) bis(N-methyl o-nitrobenzohydroxamate) from a mixture oftoluene and methanol yielded amorphous solids. Universiti Kebangsaan Malaysia 2003 Article PeerReviewed Elhadi Elba Saad, and Y. Farina, and Ibrahim Baba, and Abdul Hamid Othman, (2003) Synthesis and characterisation of some diorganotin bis(N- methyl 0-nitrobenzohydroxamate). Sains Malaysiana, 32 . pp. 79-86. ISSN 0126-6039 http://www.ukm.my/jsm/english_journals/vol32_2003/vol32_03page79-86.html
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Kebangasaan Malaysia
building	UKM Institutional Repository
collection	Online Access
description	Diorganotin(IV) complexes of N-methyl o-nitrobenzohydroxamic acid were synthesised by refluxing diorganotin(IV) oxide and the free ligand using a Dean and Stark water separator. The N-methyl o-nitrobenzohydroxamic acid was derived from the corresponding o-nitrobenzoyl chloride and Nmethylhydroxylamine in the presence of sodium hydrogen carbonate. The isolated complexes were characterized by elemental analysis and spectroscopic methods such as infrared, lH and 13C nuclear magnetic resonance. Results of analysis carried out on the diorganotin(IV) complexes of N-methyl onitrobenzohydroxamic acid showed a 1:2 stoichiometry with general formula R2Sn[O-NO2C6P4CONCH3O]2 (R= methyl, n-butyl and phenyl). The coordination mode occurs by deprotonation of the hydroxy group and subsequent (0,0) coordination of the carbonyl oxygen. Attempted recrystallization of ndibutyltin(IV) bis(N-methyl o-nitrobenzohydroxamate) from a mixture oftoluene and methanol yielded amorphous solids.
format	Article
author	Elhadi Elba Saad, Y. Farina, Ibrahim Baba, Abdul Hamid Othman,
spellingShingle	Elhadi Elba Saad, Y. Farina, Ibrahim Baba, Abdul Hamid Othman, Synthesis and characterisation of some diorganotin bis(N- methyl 0-nitrobenzohydroxamate)
author_facet	Elhadi Elba Saad, Y. Farina, Ibrahim Baba, Abdul Hamid Othman,
author_sort	Elhadi Elba Saad,
title	Synthesis and characterisation of some diorganotin bis(N- methyl 0-nitrobenzohydroxamate)
title_short	Synthesis and characterisation of some diorganotin bis(N- methyl 0-nitrobenzohydroxamate)
title_full	Synthesis and characterisation of some diorganotin bis(N- methyl 0-nitrobenzohydroxamate)
title_fullStr	Synthesis and characterisation of some diorganotin bis(N- methyl 0-nitrobenzohydroxamate)
title_full_unstemmed	Synthesis and characterisation of some diorganotin bis(N- methyl 0-nitrobenzohydroxamate)
title_sort	synthesis and characterisation of some diorganotin bis(n- methyl 0-nitrobenzohydroxamate)
publisher	Universiti Kebangsaan Malaysia
publishDate	2003
url	http://journalarticle.ukm.my/3858/ http://journalarticle.ukm.my/3858/
first_indexed	2023-09-18T19:39:56Z
last_indexed	2023-09-18T19:39:56Z
_version_	1777405522381635584

Synthesis and characterisation of some diorganotin bis(N- methyl 0-nitrobenzohydroxamate)

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