Synthesis and characterization of esters derived from ricinoleic acid and evaluation of their low temperature properties

A series of ester compounds derived from ricinoleic acid to be used as biolubricants base stock have been synthesized. The resulting products were confirmed by FTIR and NMR analyses. The synthesis was carried out in three stages: epoxidation of ricinoleic acid; synthesis of 10,12-dihydroxy-9-acyloxy...

Full description

Bibliographic Details
Main Authors: Jumat Salimon, Nadia Salih, Emad Yousif
Format: Article
Language:English
Published: Universiti Kebangsaan Malaysia 2012
Online Access:http://journalarticle.ukm.my/5530/
http://journalarticle.ukm.my/5530/
http://journalarticle.ukm.my/5530/1/10%2520Jumat%2520Salimon.pdf
id ukm-5530
recordtype eprints
spelling ukm-55302016-12-14T06:38:44Z http://journalarticle.ukm.my/5530/ Synthesis and characterization of esters derived from ricinoleic acid and evaluation of their low temperature properties Jumat Salimon, Nadia Salih, Emad Yousif, A series of ester compounds derived from ricinoleic acid to be used as biolubricants base stock have been synthesized. The resulting products were confirmed by FTIR and NMR analyses. The synthesis was carried out in three stages: epoxidation of ricinoleic acid; synthesis of 10,12-dihydroxy-9-acyloxystearic acid from epoxidized ricinoleic acid with various fatty acids and esterification of the acyloxystearic acid products with octanol to yield octyl-10,12-dihydroxy-9-acyloxystearate. The viscosities, flash points and pour points (PP) behavior of the products were measured. The resulting esters had an increased in molar weight and viscosity and decreased in pour points as compared to ricinoleic acid Universiti Kebangsaan Malaysia 2012-10 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/5530/1/10%2520Jumat%2520Salimon.pdf Jumat Salimon, and Nadia Salih, and Emad Yousif, (2012) Synthesis and characterization of esters derived from ricinoleic acid and evaluation of their low temperature properties. Sains Malaysiana, 41 (10). pp. 1239-1244. ISSN 0126-6039 http://www.ukm.my/jsm/contents.html
repository_type Digital Repository
institution_category Local University
institution Universiti Kebangasaan Malaysia
building UKM Institutional Repository
collection Online Access
language English
description A series of ester compounds derived from ricinoleic acid to be used as biolubricants base stock have been synthesized. The resulting products were confirmed by FTIR and NMR analyses. The synthesis was carried out in three stages: epoxidation of ricinoleic acid; synthesis of 10,12-dihydroxy-9-acyloxystearic acid from epoxidized ricinoleic acid with various fatty acids and esterification of the acyloxystearic acid products with octanol to yield octyl-10,12-dihydroxy-9-acyloxystearate. The viscosities, flash points and pour points (PP) behavior of the products were measured. The resulting esters had an increased in molar weight and viscosity and decreased in pour points as compared to ricinoleic acid
format Article
author Jumat Salimon,
Nadia Salih,
Emad Yousif,
spellingShingle Jumat Salimon,
Nadia Salih,
Emad Yousif,
Synthesis and characterization of esters derived from ricinoleic acid and evaluation of their low temperature properties
author_facet Jumat Salimon,
Nadia Salih,
Emad Yousif,
author_sort Jumat Salimon,
title Synthesis and characterization of esters derived from ricinoleic acid and evaluation of their low temperature properties
title_short Synthesis and characterization of esters derived from ricinoleic acid and evaluation of their low temperature properties
title_full Synthesis and characterization of esters derived from ricinoleic acid and evaluation of their low temperature properties
title_fullStr Synthesis and characterization of esters derived from ricinoleic acid and evaluation of their low temperature properties
title_full_unstemmed Synthesis and characterization of esters derived from ricinoleic acid and evaluation of their low temperature properties
title_sort synthesis and characterization of esters derived from ricinoleic acid and evaluation of their low temperature properties
publisher Universiti Kebangsaan Malaysia
publishDate 2012
url http://journalarticle.ukm.my/5530/
http://journalarticle.ukm.my/5530/
http://journalarticle.ukm.my/5530/1/10%2520Jumat%2520Salimon.pdf
first_indexed 2023-09-18T19:44:23Z
last_indexed 2023-09-18T19:44:23Z
_version_ 1777405802750935040