Reactivity ratio determination of newly synthesized copolymers from glycidyl methacrylate and tetrahydrofurfuryl acrylate

Reactivity ratio determination of newly synthesized copolymers from glycidyl methacrylate and tetrahydrofurfuryl acrylate

Copolymers from different feed compositions of glycidyl methacrylate (GMA) and tetrahydrofurfuryl acrylate (THFA) were synthesized using free radical polymerization in toluene solution at 70±1°C using benzoyl peroxide (BPO) as initiator. The polymers were characterized by 1H NMR,13C NMR and DEPT spe...

Full description

Bibliographic Details
Main Authors: Ahmad Danial Azzahari, Rosiyah Yahya, Aziz Hassan
Format: Article
Language:English
Published: Universiti Kebangsaan Malaysia 2013
Online Access:http://journalarticle.ukm.my/6086/
http://journalarticle.ukm.my/6086/
http://journalarticle.ukm.my/6086/1/12_Ahmad_Danial.pdf
id ukm-6086
recordtype eprints
spelling ukm-60862016-12-14T06:40:20Z http://journalarticle.ukm.my/6086/ Reactivity ratio determination of newly synthesized copolymers from glycidyl methacrylate and tetrahydrofurfuryl acrylate Ahmad Danial Azzahari, Rosiyah Yahya, Aziz Hassan, Copolymers from different feed compositions of glycidyl methacrylate (GMA) and tetrahydrofurfuryl acrylate (THFA) were synthesized using free radical polymerization in toluene solution at 70±1°C using benzoyl peroxide (BPO) as initiator. The polymers were characterized by 1H NMR,13C NMR and DEPT spectroscopic techniques. The copolymer compositions were determined using 1H NMR analysis. Reactivity ratios for GMA and THFA were determined by the Kelen-Tudos, Tidwell-Mortimer and error-in-variables model methods. The results showed that all these copolymerizations were strictly linear systems describable by the Mayo-Lewis equation based on the terminal model and that accurate reactivity ratio data can be obtained. Universiti Kebangsaan Malaysia 2013-04 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/6086/1/12_Ahmad_Danial.pdf Ahmad Danial Azzahari, and Rosiyah Yahya, and Aziz Hassan, (2013) Reactivity ratio determination of newly synthesized copolymers from glycidyl methacrylate and tetrahydrofurfuryl acrylate. Sains Malaysiana, 42 (4). pp. 509-514. ISSN 0126-6039 http://www.ukm.my/jsm/
repository_type Digital Repository
institution_category Local University
institution Universiti Kebangasaan Malaysia
building UKM Institutional Repository
collection Online Access
language English
description Copolymers from different feed compositions of glycidyl methacrylate (GMA) and tetrahydrofurfuryl acrylate (THFA) were synthesized using free radical polymerization in toluene solution at 70±1°C using benzoyl peroxide (BPO) as initiator. The polymers were characterized by 1H NMR,13C NMR and DEPT spectroscopic techniques. The copolymer compositions were determined using 1H NMR analysis. Reactivity ratios for GMA and THFA were determined by the Kelen-Tudos, Tidwell-Mortimer and error-in-variables model methods. The results showed that all these copolymerizations were strictly linear systems describable by the Mayo-Lewis equation based on the terminal model and that accurate reactivity ratio data can be obtained.
format Article
author Ahmad Danial Azzahari,
Rosiyah Yahya,
Aziz Hassan,
spellingShingle Ahmad Danial Azzahari,
Rosiyah Yahya,
Aziz Hassan,
Reactivity ratio determination of newly synthesized copolymers from glycidyl methacrylate and tetrahydrofurfuryl acrylate
author_facet Ahmad Danial Azzahari,
Rosiyah Yahya,
Aziz Hassan,
author_sort Ahmad Danial Azzahari,
title Reactivity ratio determination of newly synthesized copolymers from glycidyl methacrylate and tetrahydrofurfuryl acrylate
title_short Reactivity ratio determination of newly synthesized copolymers from glycidyl methacrylate and tetrahydrofurfuryl acrylate
title_full Reactivity ratio determination of newly synthesized copolymers from glycidyl methacrylate and tetrahydrofurfuryl acrylate
title_fullStr Reactivity ratio determination of newly synthesized copolymers from glycidyl methacrylate and tetrahydrofurfuryl acrylate
title_full_unstemmed Reactivity ratio determination of newly synthesized copolymers from glycidyl methacrylate and tetrahydrofurfuryl acrylate
title_sort reactivity ratio determination of newly synthesized copolymers from glycidyl methacrylate and tetrahydrofurfuryl acrylate
publisher Universiti Kebangsaan Malaysia
publishDate 2013
url http://journalarticle.ukm.my/6086/
http://journalarticle.ukm.my/6086/
http://journalarticle.ukm.my/6086/1/12_Ahmad_Danial.pdf
first_indexed 2023-09-18T19:45:56Z
last_indexed 2023-09-18T19:45:56Z
_version_ 1777405900225511424

Similar Items