Synthesis and characterization of mixed ligand complexes of caffeine, adenine and thiocyanate with some transition metal ions

An ethanolic solution of caffeine was added to an aqueous solution of metal salts and followed by adding ethanolic solution of adenine and an aqueous solution of potassium thiocyanate to give complexes with general formula [M(CA)2(Ad)X2] where CA is caffeine, Ad is adenine, X is thiocyanate ion and...

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Main Authors: Shayma A. Shaker, Yang Farina, Sadia Mahmmod, Mohean Eskender
Format: Article
Language:English
Published: Universiti Kebangsaan Malaysia 2010
Online Access:http://journalarticle.ukm.my/7439/
http://journalarticle.ukm.my/7439/
http://journalarticle.ukm.my/7439/1/26_Ayiesah.pdf
id ukm-7439
recordtype eprints
spelling ukm-74392016-12-14T06:44:05Z http://journalarticle.ukm.my/7439/ Synthesis and characterization of mixed ligand complexes of caffeine, adenine and thiocyanate with some transition metal ions Shayma A. Shaker, Yang Farina, Sadia Mahmmod, Mohean Eskender, An ethanolic solution of caffeine was added to an aqueous solution of metal salts and followed by adding ethanolic solution of adenine and an aqueous solution of potassium thiocyanate to give complexes with general formula [M(CA)2(Ad)X2] where CA is caffeine, Ad is adenine, X is thiocyanate ion and M is Co(II), Ni(II), Cu(II), Zn(II) and Cd(II). The resulting products were characterized using UV-visible and infrared spectroscopies. Elemental analyses were performed using C, H, N analysis and atomic absorption techniques. The magnetic susceptibility and the conductivity were also measured. The results suggested that the complexes have octahedral geometry. Universiti Kebangsaan Malaysia 2010-12 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/7439/1/26_Ayiesah.pdf Shayma A. Shaker, and Yang Farina, and Sadia Mahmmod, and Mohean Eskender, (2010) Synthesis and characterization of mixed ligand complexes of caffeine, adenine and thiocyanate with some transition metal ions. Sains Malaysiana, 39 (6). pp. 957-962. ISSN 0126-6039 http://www.ukm.my/jsm/english_journals/vol39num6_2010/contentsVol39num6_2010.html
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building UKM Institutional Repository
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language English
description An ethanolic solution of caffeine was added to an aqueous solution of metal salts and followed by adding ethanolic solution of adenine and an aqueous solution of potassium thiocyanate to give complexes with general formula [M(CA)2(Ad)X2] where CA is caffeine, Ad is adenine, X is thiocyanate ion and M is Co(II), Ni(II), Cu(II), Zn(II) and Cd(II). The resulting products were characterized using UV-visible and infrared spectroscopies. Elemental analyses were performed using C, H, N analysis and atomic absorption techniques. The magnetic susceptibility and the conductivity were also measured. The results suggested that the complexes have octahedral geometry.
format Article
author Shayma A. Shaker,
Yang Farina,
Sadia Mahmmod,
Mohean Eskender,
spellingShingle Shayma A. Shaker,
Yang Farina,
Sadia Mahmmod,
Mohean Eskender,
Synthesis and characterization of mixed ligand complexes of caffeine, adenine and thiocyanate with some transition metal ions
author_facet Shayma A. Shaker,
Yang Farina,
Sadia Mahmmod,
Mohean Eskender,
author_sort Shayma A. Shaker,
title Synthesis and characterization of mixed ligand complexes of caffeine, adenine and thiocyanate with some transition metal ions
title_short Synthesis and characterization of mixed ligand complexes of caffeine, adenine and thiocyanate with some transition metal ions
title_full Synthesis and characterization of mixed ligand complexes of caffeine, adenine and thiocyanate with some transition metal ions
title_fullStr Synthesis and characterization of mixed ligand complexes of caffeine, adenine and thiocyanate with some transition metal ions
title_full_unstemmed Synthesis and characterization of mixed ligand complexes of caffeine, adenine and thiocyanate with some transition metal ions
title_sort synthesis and characterization of mixed ligand complexes of caffeine, adenine and thiocyanate with some transition metal ions
publisher Universiti Kebangsaan Malaysia
publishDate 2010
url http://journalarticle.ukm.my/7439/
http://journalarticle.ukm.my/7439/
http://journalarticle.ukm.my/7439/1/26_Ayiesah.pdf
first_indexed 2023-09-18T19:49:44Z
last_indexed 2023-09-18T19:49:44Z
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