Conductivity Study on Plasticized Solid bio-electrolytes CMC-NH4Br and Application in Solid-state Proton Batteries

This paper present the development of plasticized solid bio-electrolytes (PSBs) which has been accomplished by incorporating various composition of plasticizer namely ethylene carbonate (EC) with carboxy methylcellulose doped NH4Br via solution casting method. The plasticized polymer–salt ionic cond...

Full description

Bibliographic Details
Main Authors:	A. S., Samsudin, M. I. N., Isa
Format:	Conference or Workshop Item
Language:	English English
Published:	2015
Subjects:	Q Science (General)
Online Access:	http://umpir.ump.edu.my/id/eprint/10533/ http://umpir.ump.edu.my/id/eprint/10533/1/Conductivity%20study%20on%20plasticized%20solid%20bio-electrolytes%20CMC-NH4Br%20and.pdf http://umpir.ump.edu.my/id/eprint/10533/7/fist-2015-samsudin-Conductivity%20Study%20on%20Plasticized.pdf

id	ump-10533
recordtype	eprints
spelling	ump-105332015-09-30T03:17:31Z http://umpir.ump.edu.my/id/eprint/10533/ Conductivity Study on Plasticized Solid bio-electrolytes CMC-NH4Br and Application in Solid-state Proton Batteries A. S., Samsudin M. I. N., Isa Q Science (General) This paper present the development of plasticized solid bio-electrolytes (PSBs) which has been accomplished by incorporating various composition of plasticizer namely ethylene carbonate (EC) with carboxy methylcellulose doped NH4Br via solution casting method. The plasticized polymer–salt ionic conduction of PSBs has been analyzed by electrical impedance spectroscopy. Plasticization using EC in PSBs system assists the enhancement of NH4Br dissociation and therefore increases the protonation process in the system. The highest ionic conductivity obtained for CMC−NH4Br containing with 25 wt. % NH4Br was achieved at 1.12 x 10-4 Scm-1 and improved to 3.31 x 10-3 Scm-1 when EC was added in PSBs system. The ionic conductivity-temperature for PSBs system was found to obey the Arrhenius relationships where the ionic conductivity increases with temperature. The solid-state proton batteries were assembled with the formation of Zn + ZnSO4.7H2O \|\| highest conducting PSBs system \|\| MnO2 and achieve with a maximum open circuit voltage (OCV) of 1.48 V at room temperature and showed good in rechargeablity performance with more than 10 cycles. 2015 Conference or Workshop Item NonPeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/10533/1/Conductivity%20study%20on%20plasticized%20solid%20bio-electrolytes%20CMC-NH4Br%20and.pdf application/pdf en http://umpir.ump.edu.my/id/eprint/10533/7/fist-2015-samsudin-Conductivity%20Study%20on%20Plasticized.pdf A. S., Samsudin and M. I. N., Isa (2015) Conductivity Study on Plasticized Solid bio-electrolytes CMC-NH4Br and Application in Solid-state Proton Batteries. In: International Symposium On Sciences And Mathematics (ISYSM 2015), 24-26 November 2015 , Bandung, Indonesia. pp. 1-6.. (Unpublished)
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English English
topic	Q Science (General)
spellingShingle	Q Science (General) A. S., Samsudin M. I. N., Isa Conductivity Study on Plasticized Solid bio-electrolytes CMC-NH4Br and Application in Solid-state Proton Batteries
description	This paper present the development of plasticized solid bio-electrolytes (PSBs) which has been accomplished by incorporating various composition of plasticizer namely ethylene carbonate (EC) with carboxy methylcellulose doped NH4Br via solution casting method. The plasticized polymer–salt ionic conduction of PSBs has been analyzed by electrical impedance spectroscopy. Plasticization using EC in PSBs system assists the enhancement of NH4Br dissociation and therefore increases the protonation process in the system. The highest ionic conductivity obtained for CMC−NH4Br containing with 25 wt. % NH4Br was achieved at 1.12 x 10-4 Scm-1 and improved to 3.31 x 10-3 Scm-1 when EC was added in PSBs system. The ionic conductivity-temperature for PSBs system was found to obey the Arrhenius relationships where the ionic conductivity increases with temperature. The solid-state proton batteries were assembled with the formation of Zn + ZnSO4.7H2O \|\| highest conducting PSBs system \|\| MnO2 and achieve with a maximum open circuit voltage (OCV) of 1.48 V at room temperature and showed good in rechargeablity performance with more than 10 cycles.
format	Conference or Workshop Item
author	A. S., Samsudin M. I. N., Isa
author_facet	A. S., Samsudin M. I. N., Isa
author_sort	A. S., Samsudin
title	Conductivity Study on Plasticized Solid bio-electrolytes CMC-NH4Br and Application in Solid-state Proton Batteries
title_short	Conductivity Study on Plasticized Solid bio-electrolytes CMC-NH4Br and Application in Solid-state Proton Batteries
title_full	Conductivity Study on Plasticized Solid bio-electrolytes CMC-NH4Br and Application in Solid-state Proton Batteries
title_fullStr	Conductivity Study on Plasticized Solid bio-electrolytes CMC-NH4Br and Application in Solid-state Proton Batteries
title_full_unstemmed	Conductivity Study on Plasticized Solid bio-electrolytes CMC-NH4Br and Application in Solid-state Proton Batteries
title_sort	conductivity study on plasticized solid bio-electrolytes cmc-nh4br and application in solid-state proton batteries
publishDate	2015
url	http://umpir.ump.edu.my/id/eprint/10533/ http://umpir.ump.edu.my/id/eprint/10533/1/Conductivity%20study%20on%20plasticized%20solid%20bio-electrolytes%20CMC-NH4Br%20and.pdf http://umpir.ump.edu.my/id/eprint/10533/7/fist-2015-samsudin-Conductivity%20Study%20on%20Plasticized.pdf
first_indexed	2023-09-18T22:10:15Z
last_indexed	2023-09-18T22:10:15Z
_version_	1777414979006234624

Conductivity Study on Plasticized Solid bio-electrolytes CMC-NH4Br and Application in Solid-state Proton Batteries

Similar Items