CO2 reforming of CH4 over Ni/SBA-15 catalyst: Effect of Nickel Loading

CO2 reforming of CH4 has recently attracted considerable attention due to the simultaneous utilization and reduction of two greenhouse gases, into the synthesis gas (syngas) with low H2/CO ratio than those available industrial processes. CO2 reforming of CH4 has been studied extensively using variet...

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Main Authors:	Setiabudi, H. D., Nurul, Ainirazali, S. F. R. M., Suhaimi, Fatin Nadia, Pauzi, K. H., Lim, Chin, S. Y.
Format:	Conference or Workshop Item
Language:	English
Published:	2015
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/11907/ http://umpir.ump.edu.my/id/eprint/11907/1/CO2%20reforming%20of%20CH4%20over%20Ni-SBA-15%20catalyst-%20Effect%20of%20Nickel%20Loading.pdf

id	ump-11907
recordtype	eprints
spelling	ump-119072018-05-22T01:27:50Z http://umpir.ump.edu.my/id/eprint/11907/ CO2 reforming of CH4 over Ni/SBA-15 catalyst: Effect of Nickel Loading Setiabudi, H. D. Nurul, Ainirazali S. F. R. M., Suhaimi Fatin Nadia, Pauzi K. H., Lim Chin, S. Y. TP Chemical technology CO2 reforming of CH4 has recently attracted considerable attention due to the simultaneous utilization and reduction of two greenhouse gases, into the synthesis gas (syngas) with low H2/CO ratio than those available industrial processes. CO2 reforming of CH4 has been studied extensively using variety of supported metal catalysts. Regarding to the choice of catalyst, Nickel (Ni) supported on mesoporous material shows good catalytic activity and selectivity. This study investigates the effects of Ni loading (0-10 wt%) on the properties and catalytic performance of Ni/SBA-15 towards CO2 reforming of CH4, owing to the fact that metal has a significant influence on the properties and catalytic performance of the catalyst. Characterization using XRD, BET, FTIR and TG/DTA revealed that the amount of Ni content plays an important role in controlling the properties and catalytic performance of Ni/SBA-15. The activity of CO2 reforming of CH4 followed the order of 5wt%Ni/SBA-15 > 10wt%Ni/SBA-15 > 3wt%Ni/SBA-15 > SBA-15. The superior catalytic behaviour of 5wt%Ni/SBA-15 towards CO2 reforming of CH4 was related with the interaction of Ni with SBA-15, which altered the properties of catalyst towards an excellent catalytic performance. The conversion of CH4 and CO2 over 5wt%Ni/SBA-15 was about 88.2% and 91.4%, respectively with CO2/CH4 ratio of 1. This study provides new perspectives on the Ni-based catalyst, particularly on the effects of Ni on the properties and catalytic performance of Ni/SBA-15 towards CO2 reforming of CH4. 2015 Conference or Workshop Item PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/11907/1/CO2%20reforming%20of%20CH4%20over%20Ni-SBA-15%20catalyst-%20Effect%20of%20Nickel%20Loading.pdf Setiabudi, H. D. and Nurul, Ainirazali and S. F. R. M., Suhaimi and Fatin Nadia, Pauzi and K. H., Lim and Chin, S. Y. (2015) CO2 reforming of CH4 over Ni/SBA-15 catalyst: Effect of Nickel Loading. In: 4th Conference on Emerging Energy and Process Technology (CONCEPT2015), 15-16 December 2015 , Melaka. p. 1.. (Unpublished)
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	TP Chemical technology
spellingShingle	TP Chemical technology Setiabudi, H. D. Nurul, Ainirazali S. F. R. M., Suhaimi Fatin Nadia, Pauzi K. H., Lim Chin, S. Y. CO2 reforming of CH4 over Ni/SBA-15 catalyst: Effect of Nickel Loading
description	CO2 reforming of CH4 has recently attracted considerable attention due to the simultaneous utilization and reduction of two greenhouse gases, into the synthesis gas (syngas) with low H2/CO ratio than those available industrial processes. CO2 reforming of CH4 has been studied extensively using variety of supported metal catalysts. Regarding to the choice of catalyst, Nickel (Ni) supported on mesoporous material shows good catalytic activity and selectivity. This study investigates the effects of Ni loading (0-10 wt%) on the properties and catalytic performance of Ni/SBA-15 towards CO2 reforming of CH4, owing to the fact that metal has a significant influence on the properties and catalytic performance of the catalyst. Characterization using XRD, BET, FTIR and TG/DTA revealed that the amount of Ni content plays an important role in controlling the properties and catalytic performance of Ni/SBA-15. The activity of CO2 reforming of CH4 followed the order of 5wt%Ni/SBA-15 > 10wt%Ni/SBA-15 > 3wt%Ni/SBA-15 > SBA-15. The superior catalytic behaviour of 5wt%Ni/SBA-15 towards CO2 reforming of CH4 was related with the interaction of Ni with SBA-15, which altered the properties of catalyst towards an excellent catalytic performance. The conversion of CH4 and CO2 over 5wt%Ni/SBA-15 was about 88.2% and 91.4%, respectively with CO2/CH4 ratio of 1. This study provides new perspectives on the Ni-based catalyst, particularly on the effects of Ni on the properties and catalytic performance of Ni/SBA-15 towards CO2 reforming of CH4.
format	Conference or Workshop Item
author	Setiabudi, H. D. Nurul, Ainirazali S. F. R. M., Suhaimi Fatin Nadia, Pauzi K. H., Lim Chin, S. Y.
author_facet	Setiabudi, H. D. Nurul, Ainirazali S. F. R. M., Suhaimi Fatin Nadia, Pauzi K. H., Lim Chin, S. Y.
author_sort	Setiabudi, H. D.
title	CO2 reforming of CH4 over Ni/SBA-15 catalyst: Effect of Nickel Loading
title_short	CO2 reforming of CH4 over Ni/SBA-15 catalyst: Effect of Nickel Loading
title_full	CO2 reforming of CH4 over Ni/SBA-15 catalyst: Effect of Nickel Loading
title_fullStr	CO2 reforming of CH4 over Ni/SBA-15 catalyst: Effect of Nickel Loading
title_full_unstemmed	CO2 reforming of CH4 over Ni/SBA-15 catalyst: Effect of Nickel Loading
title_sort	co2 reforming of ch4 over ni/sba-15 catalyst: effect of nickel loading
publishDate	2015
url	http://umpir.ump.edu.my/id/eprint/11907/ http://umpir.ump.edu.my/id/eprint/11907/1/CO2%20reforming%20of%20CH4%20over%20Ni-SBA-15%20catalyst-%20Effect%20of%20Nickel%20Loading.pdf
first_indexed	2023-09-18T22:12:58Z
last_indexed	2023-09-18T22:12:58Z
_version_	1777415150139080704

CO2 reforming of CH4 over Ni/SBA-15 catalyst: Effect of Nickel Loading

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