Copper Nanoparticle in Cationized Palm Oil Fibres: Physic-Chemical Investigation

At ambient atmospheric condition copper nanoparticles (CuNPs) were prepared in aqueous medium using copper chloride, sodium borohydride, ascorbic acid and polyvinyl alcohol (PVA) of two different molecular weights (M ws). The physical appearance of the prepared sol of CuNPs has been found to be stab...

Full description

Bibliographic Details
Main Authors: M. N. K., Chowdury, Beg, M. D. H., Khan, Maksudur R., M. F., Mina, A. F., Ismail
Format: Article
Language:English
Published: Springer 2014
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/12355/
http://umpir.ump.edu.my/id/eprint/12355/
http://umpir.ump.edu.my/id/eprint/12355/
http://umpir.ump.edu.my/id/eprint/12355/1/Copper%20nanoparticle%20in%20cationized%20palm%20oil%20fibres.pdf
id ump-12355
recordtype eprints
spelling ump-123552017-09-11T07:45:00Z http://umpir.ump.edu.my/id/eprint/12355/ Copper Nanoparticle in Cationized Palm Oil Fibres: Physic-Chemical Investigation M. N. K., Chowdury Beg, M. D. H. Khan, Maksudur R. M. F., Mina A. F., Ismail QD Chemistry TP Chemical technology At ambient atmospheric condition copper nanoparticles (CuNPs) were prepared in aqueous medium using copper chloride, sodium borohydride, ascorbic acid and polyvinyl alcohol (PVA) of two different molecular weights (M ws). The physical appearance of the prepared sol of CuNPs has been found to be stable for a couple of weeks when kept in ambient atmospheric condition, as confirmed by ultraviolet–visible absorption spectroscopy. Transmission electron microscopy exhibits spherical morphology of CuNPs with an average size of 3.5 ± 1.1 nm developed in the sol, where PVA of highM w renders smaller size (2.5 nm) than that of low M w. The synthesised CuNPs were embedded in palm oil fibres (POFs) via cationisation process. The cationisation of POF was ascertained by Fourier-transformed infrared and zero point charge determination. The inclusion of nanoparticles (NPs) onto the fibres’ surface has been consistently proven by Fourier transformed infrared spectroscopy, X-ray diffraction study, field emission scanning electron microscopy, energy dispersive X-ray study and thermogravimetric analysis. CuNP-coated POF showed the increment of tensile strength (∼34 %) and antifungal activity (24 %) with respect to control fibres. The observed findings suggest that NPs can be effectively used as reinforcing agents in natural fibres to improve their property and durability. Springer 2014 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/12355/1/Copper%20nanoparticle%20in%20cationized%20palm%20oil%20fibres.pdf M. N. K., Chowdury and Beg, M. D. H. and Khan, Maksudur R. and M. F., Mina and A. F., Ismail (2014) Copper Nanoparticle in Cationized Palm Oil Fibres: Physic-Chemical Investigation. Colloid and Polymer Science, 293 (3). pp. 777-786. ISSN 0303-402X http://dx.doi.org/10.1007/s00396-014-3462-y DOI 10.1007/s00396-014-3462-y
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
language English
topic QD Chemistry
TP Chemical technology
spellingShingle QD Chemistry
TP Chemical technology
M. N. K., Chowdury
Beg, M. D. H.
Khan, Maksudur R.
M. F., Mina
A. F., Ismail
Copper Nanoparticle in Cationized Palm Oil Fibres: Physic-Chemical Investigation
description At ambient atmospheric condition copper nanoparticles (CuNPs) were prepared in aqueous medium using copper chloride, sodium borohydride, ascorbic acid and polyvinyl alcohol (PVA) of two different molecular weights (M ws). The physical appearance of the prepared sol of CuNPs has been found to be stable for a couple of weeks when kept in ambient atmospheric condition, as confirmed by ultraviolet–visible absorption spectroscopy. Transmission electron microscopy exhibits spherical morphology of CuNPs with an average size of 3.5 ± 1.1 nm developed in the sol, where PVA of highM w renders smaller size (2.5 nm) than that of low M w. The synthesised CuNPs were embedded in palm oil fibres (POFs) via cationisation process. The cationisation of POF was ascertained by Fourier-transformed infrared and zero point charge determination. The inclusion of nanoparticles (NPs) onto the fibres’ surface has been consistently proven by Fourier transformed infrared spectroscopy, X-ray diffraction study, field emission scanning electron microscopy, energy dispersive X-ray study and thermogravimetric analysis. CuNP-coated POF showed the increment of tensile strength (∼34 %) and antifungal activity (24 %) with respect to control fibres. The observed findings suggest that NPs can be effectively used as reinforcing agents in natural fibres to improve their property and durability.
format Article
author M. N. K., Chowdury
Beg, M. D. H.
Khan, Maksudur R.
M. F., Mina
A. F., Ismail
author_facet M. N. K., Chowdury
Beg, M. D. H.
Khan, Maksudur R.
M. F., Mina
A. F., Ismail
author_sort M. N. K., Chowdury
title Copper Nanoparticle in Cationized Palm Oil Fibres: Physic-Chemical Investigation
title_short Copper Nanoparticle in Cationized Palm Oil Fibres: Physic-Chemical Investigation
title_full Copper Nanoparticle in Cationized Palm Oil Fibres: Physic-Chemical Investigation
title_fullStr Copper Nanoparticle in Cationized Palm Oil Fibres: Physic-Chemical Investigation
title_full_unstemmed Copper Nanoparticle in Cationized Palm Oil Fibres: Physic-Chemical Investigation
title_sort copper nanoparticle in cationized palm oil fibres: physic-chemical investigation
publisher Springer
publishDate 2014
url http://umpir.ump.edu.my/id/eprint/12355/
http://umpir.ump.edu.my/id/eprint/12355/
http://umpir.ump.edu.my/id/eprint/12355/
http://umpir.ump.edu.my/id/eprint/12355/1/Copper%20nanoparticle%20in%20cationized%20palm%20oil%20fibres.pdf
first_indexed 2023-09-18T22:13:56Z
last_indexed 2023-09-18T22:13:56Z
_version_ 1777415211200806912