Characterization of Ag-promoted Ni/SiO2 Catalysts for Syngas Production via Carbon Dioxide (CO2) Dry Reforming of Glycerol

Characterization of Ag-promoted Ni/SiO2 Catalysts for Syngas Production via Carbon Dioxide (CO2) Dry Reforming of Glycerol

The carbon dioxide (CO2) dry reforming of glycerol for syngas production is one of the promising ways to benefit the oversupply crisis of glycerol worldwide. It is an attractive process as it converts carbon dioxide, a greenhouse gas into a synthesis gas and simultaneously removed from the carbon bi...

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Main Authors: Norazimah, Harun, Jolius, Gimbun, Mohammad Tazli, Azizan, Sumaiya, Zainal Abidin
Format: Article
Language:English
Published: Department of Chemical Engineering, Diponegoro University 2016
Subjects:
TP Chemical technology
Online Access:http://umpir.ump.edu.my/id/eprint/13304/
http://umpir.ump.edu.my/id/eprint/13304/
http://umpir.ump.edu.my/id/eprint/13304/
http://umpir.ump.edu.my/id/eprint/13304/1/Characterization%20of%20Ag-promoted%20Ni-SiO2%20Catalysts%20for%20Syngas%20Production%20via%20Carbon%20Dioxide%20%28CO2%29%20Dry%20Reforming%20of%20Glycerol.pdf
id ump-13304
recordtype eprints
spelling ump-133042019-10-18T03:07:31Z http://umpir.ump.edu.my/id/eprint/13304/ Characterization of Ag-promoted Ni/SiO2 Catalysts for Syngas Production via Carbon Dioxide (CO2) Dry Reforming of Glycerol Norazimah, Harun Jolius, Gimbun Mohammad Tazli, Azizan Sumaiya, Zainal Abidin TP Chemical technology The carbon dioxide (CO2) dry reforming of glycerol for syngas production is one of the promising ways to benefit the oversupply crisis of glycerol worldwide. It is an attractive process as it converts carbon dioxide, a greenhouse gas into a synthesis gas and simultaneously removed from the carbon biosphere cycle. In this study, the glycerol dry reforming was carried out using Silver (Ag) promoted Nickel (Ni) based catalysts supported on silicon oxide (SiO2). The catalysts were prepared through wet impregnation method and characterized by using Bruanaer-Emmett-Teller (BET) surface area, Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), and Thermo Gravimetric (TGA) analysis. The experiment was conducted in a tubular reactor which condition fixed at 973 K and CO2: glycerol ratio of 1, under atmospheric pressure. It was found that the main gaseous products are H₂, CO and CH4 with H₂:CO < 1.0. From the reaction study, Ag(5)NiSiO2 results in highest glycerol conversion and hydrogen yield, accounted for 32.6% and 27.4%, respectively. Department of Chemical Engineering, Diponegoro University 2016 Article PeerReviewed application/pdf en cc_by_sa http://umpir.ump.edu.my/id/eprint/13304/1/Characterization%20of%20Ag-promoted%20Ni-SiO2%20Catalysts%20for%20Syngas%20Production%20via%20Carbon%20Dioxide%20%28CO2%29%20Dry%20Reforming%20of%20Glycerol.pdf Norazimah, Harun and Jolius, Gimbun and Mohammad Tazli, Azizan and Sumaiya, Zainal Abidin (2016) Characterization of Ag-promoted Ni/SiO2 Catalysts for Syngas Production via Carbon Dioxide (CO2) Dry Reforming of Glycerol. Bulletin of Chemical Reaction Engineering & Catalysis, 11 (2). pp. 220-229. ISSN 1978-2993 http://dx.doi.org/10.9767/bcrec.11.2.553.220-229 DOI: 10.9767/bcrec.11.2.553.220-229
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
language English
topic TP Chemical technology
spellingShingle TP Chemical technology
Norazimah, Harun
Jolius, Gimbun
Mohammad Tazli, Azizan
Sumaiya, Zainal Abidin
Characterization of Ag-promoted Ni/SiO2 Catalysts for Syngas Production via Carbon Dioxide (CO2) Dry Reforming of Glycerol
description The carbon dioxide (CO2) dry reforming of glycerol for syngas production is one of the promising ways to benefit the oversupply crisis of glycerol worldwide. It is an attractive process as it converts carbon dioxide, a greenhouse gas into a synthesis gas and simultaneously removed from the carbon biosphere cycle. In this study, the glycerol dry reforming was carried out using Silver (Ag) promoted Nickel (Ni) based catalysts supported on silicon oxide (SiO2). The catalysts were prepared through wet impregnation method and characterized by using Bruanaer-Emmett-Teller (BET) surface area, Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), and Thermo Gravimetric (TGA) analysis. The experiment was conducted in a tubular reactor which condition fixed at 973 K and CO2: glycerol ratio of 1, under atmospheric pressure. It was found that the main gaseous products are H₂, CO and CH4 with H₂:CO < 1.0. From the reaction study, Ag(5)NiSiO2 results in highest glycerol conversion and hydrogen yield, accounted for 32.6% and 27.4%, respectively.
format Article
author Norazimah, Harun
Jolius, Gimbun
Mohammad Tazli, Azizan
Sumaiya, Zainal Abidin
author_facet Norazimah, Harun
Jolius, Gimbun
Mohammad Tazli, Azizan
Sumaiya, Zainal Abidin
author_sort Norazimah, Harun
title Characterization of Ag-promoted Ni/SiO2 Catalysts for Syngas Production via Carbon Dioxide (CO2) Dry Reforming of Glycerol
title_short Characterization of Ag-promoted Ni/SiO2 Catalysts for Syngas Production via Carbon Dioxide (CO2) Dry Reforming of Glycerol
title_full Characterization of Ag-promoted Ni/SiO2 Catalysts for Syngas Production via Carbon Dioxide (CO2) Dry Reforming of Glycerol
title_fullStr Characterization of Ag-promoted Ni/SiO2 Catalysts for Syngas Production via Carbon Dioxide (CO2) Dry Reforming of Glycerol
title_full_unstemmed Characterization of Ag-promoted Ni/SiO2 Catalysts for Syngas Production via Carbon Dioxide (CO2) Dry Reforming of Glycerol
title_sort characterization of ag-promoted ni/sio2 catalysts for syngas production via carbon dioxide (co2) dry reforming of glycerol
publisher Department of Chemical Engineering, Diponegoro University
publishDate 2016
url http://umpir.ump.edu.my/id/eprint/13304/
http://umpir.ump.edu.my/id/eprint/13304/
http://umpir.ump.edu.my/id/eprint/13304/
http://umpir.ump.edu.my/id/eprint/13304/1/Characterization%20of%20Ag-promoted%20Ni-SiO2%20Catalysts%20for%20Syngas%20Production%20via%20Carbon%20Dioxide%20%28CO2%29%20Dry%20Reforming%20of%20Glycerol.pdf
first_indexed 2023-09-18T22:15:47Z
last_indexed 2023-09-18T22:15:47Z
_version_ 1777415327157583872

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