Ni-samaria-doped Ceria (Ni-SDC) Anode-supported Solid Oxide Fuel Cell (SOFC) Operating with CO

The performance of nickel-samaria-doped ceria (Ni-SDC) anode-supported cell with CO-CO2 feed was evaluated. The aim of this work is to examine carbon formation on the Ni-SDC anode when feeding with CO under conditions when carbon deposition is thermodynamically favoured. Electrochemical tests were c...

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Main Authors:	Asmida, Ideris, Croiset, Eric, Pritzker, Mark
Format:	Article
Language:	English
Published:	Elsevier 2017
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/13694/ http://umpir.ump.edu.my/id/eprint/13694/ http://umpir.ump.edu.my/id/eprint/13694/ http://umpir.ump.edu.my/id/eprint/13694/1/fkksa-2017-asmida-Ni-samaria-doped%20ceria%20%28Ni-SDC1.pdf

id	ump-13694
recordtype	eprints
spelling	ump-136942018-02-08T04:45:02Z http://umpir.ump.edu.my/id/eprint/13694/ Ni-samaria-doped Ceria (Ni-SDC) Anode-supported Solid Oxide Fuel Cell (SOFC) Operating with CO Asmida, Ideris Croiset, Eric Pritzker, Mark TP Chemical technology The performance of nickel-samaria-doped ceria (Ni-SDC) anode-supported cell with CO-CO2 feed was evaluated. The aim of this work is to examine carbon formation on the Ni-SDC anode when feeding with CO under conditions when carbon deposition is thermodynamically favoured. Electrochemical tests were conducted at intermediate temperatures (550–700 °C) using 20 and 40% CO concentrations. Cell operating with 40% CO at 600–700 °C provided maximum power densities of 239–270 mW cm−2, 1.5 times smaller than that achieved with humidified H2. Much lower maximum power densities were attained with 20% CO (50–88 mW cm−2). Some degradation was observed during the 6 h galvanostatic operation at 0.1 A cm−2 with 40% CO fuel at 550 °C which is believed due to the accumulation of carbon at the anode. The degradation in cell potential occurred at a rate of 4.5 mV h−1, but it did not lead to cell collapse. EDX mapping at the cross-section of the anode revealed that carbon formed in the Ni-SDC cell was primarily deposited in the anode section close to the fuel entry point. Carbon was not detected at the electrolyte-anode interface and the middle of the anode, allowing the cell to continue operation with CO fuel without a catastrophic failure Elsevier 2017 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/13694/1/fkksa-2017-asmida-Ni-samaria-doped%20ceria%20%28Ni-SDC1.pdf Asmida, Ideris and Croiset, Eric and Pritzker, Mark (2017) Ni-samaria-doped Ceria (Ni-SDC) Anode-supported Solid Oxide Fuel Cell (SOFC) Operating with CO. International Journal of Hydrogen Energy, 42 (14). pp. 9180-9187. ISSN 0360-3199 http://dx.doi.org/10.1016/j.ijhydene.2016.05.203 DOI: 10.1016/j.ijhydene.2016.05.203
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	TP Chemical technology
spellingShingle	TP Chemical technology Asmida, Ideris Croiset, Eric Pritzker, Mark Ni-samaria-doped Ceria (Ni-SDC) Anode-supported Solid Oxide Fuel Cell (SOFC) Operating with CO
description	The performance of nickel-samaria-doped ceria (Ni-SDC) anode-supported cell with CO-CO2 feed was evaluated. The aim of this work is to examine carbon formation on the Ni-SDC anode when feeding with CO under conditions when carbon deposition is thermodynamically favoured. Electrochemical tests were conducted at intermediate temperatures (550–700 °C) using 20 and 40% CO concentrations. Cell operating with 40% CO at 600–700 °C provided maximum power densities of 239–270 mW cm−2, 1.5 times smaller than that achieved with humidified H2. Much lower maximum power densities were attained with 20% CO (50–88 mW cm−2). Some degradation was observed during the 6 h galvanostatic operation at 0.1 A cm−2 with 40% CO fuel at 550 °C which is believed due to the accumulation of carbon at the anode. The degradation in cell potential occurred at a rate of 4.5 mV h−1, but it did not lead to cell collapse. EDX mapping at the cross-section of the anode revealed that carbon formed in the Ni-SDC cell was primarily deposited in the anode section close to the fuel entry point. Carbon was not detected at the electrolyte-anode interface and the middle of the anode, allowing the cell to continue operation with CO fuel without a catastrophic failure
format	Article
author	Asmida, Ideris Croiset, Eric Pritzker, Mark
author_facet	Asmida, Ideris Croiset, Eric Pritzker, Mark
author_sort	Asmida, Ideris
title	Ni-samaria-doped Ceria (Ni-SDC) Anode-supported Solid Oxide Fuel Cell (SOFC) Operating with CO
title_short	Ni-samaria-doped Ceria (Ni-SDC) Anode-supported Solid Oxide Fuel Cell (SOFC) Operating with CO
title_full	Ni-samaria-doped Ceria (Ni-SDC) Anode-supported Solid Oxide Fuel Cell (SOFC) Operating with CO
title_fullStr	Ni-samaria-doped Ceria (Ni-SDC) Anode-supported Solid Oxide Fuel Cell (SOFC) Operating with CO
title_full_unstemmed	Ni-samaria-doped Ceria (Ni-SDC) Anode-supported Solid Oxide Fuel Cell (SOFC) Operating with CO
title_sort	ni-samaria-doped ceria (ni-sdc) anode-supported solid oxide fuel cell (sofc) operating with co
publisher	Elsevier
publishDate	2017
url	http://umpir.ump.edu.my/id/eprint/13694/ http://umpir.ump.edu.my/id/eprint/13694/ http://umpir.ump.edu.my/id/eprint/13694/ http://umpir.ump.edu.my/id/eprint/13694/1/fkksa-2017-asmida-Ni-samaria-doped%20ceria%20%28Ni-SDC1.pdf
first_indexed	2023-09-18T22:16:36Z
last_indexed	2023-09-18T22:16:36Z
_version_	1777415378783174656

Ni-samaria-doped Ceria (Ni-SDC) Anode-supported Solid Oxide Fuel Cell (SOFC) Operating with CO

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