Syngas Production via Methane Dry Reforming: A Novel Application of SmCoO3 Perovskite Catalyst

In this study, SmCoO3 perovskite catalyst have been synthesized by the sol-gel citrate method and for the first time, applied as catalyst for the production of syngas (H2 and CO) via methane dry reforming reaction. The perovskite catalyst was characterized (pre- and post-reaction) to determine its p...

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Main Authors:	Osazuwa, Osarieme U., Setiabudi, H. D., Ruwaida, Abdul Rasid, Cheng, C. K.
Format:	Article
Language:	English English
Published:	Elsevier Ltd 2017
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/15723/ http://umpir.ump.edu.my/id/eprint/15723/ http://umpir.ump.edu.my/id/eprint/15723/ http://umpir.ump.edu.my/id/eprint/15723/1/pagination_JNGSE_1970.pdf http://umpir.ump.edu.my/id/eprint/15723/7/fkksa-2017-ck-syngas%20production%20via%20methane.pdf

id	ump-15723
recordtype	eprints
spelling	ump-157232019-10-16T08:32:11Z http://umpir.ump.edu.my/id/eprint/15723/ Syngas Production via Methane Dry Reforming: A Novel Application of SmCoO3 Perovskite Catalyst Osazuwa, Osarieme U. Setiabudi, H. D. Ruwaida, Abdul Rasid Cheng, C. K. TP Chemical technology In this study, SmCoO3 perovskite catalyst have been synthesized by the sol-gel citrate method and for the first time, applied as catalyst for the production of syngas (H2 and CO) via methane dry reforming reaction. The perovskite catalyst was characterized (pre- and post-reaction) to determine its physicochemical properties. Characterization of the calcined perovskite catalyst showed the formation of perovskite structure only. No other crystalline phases were detected. Prior to the catalytic test, the effects of reducing SmCoO3 perovskite catalyst with H2 (for activation) in the methane dry reforming reaction were investigated. Results showed no significant effects of H2 reduction on the activity of the SmCoO3 perovskite catalyst. This suggests that there was an in-situ reduction of SmCoO3 which was confirmed by XRD analysis of spent catalyst. Subsequently, reactant gases (CO2 and CH4) with partial pressure ranged 6.8-60.8 kPa and reaction temperature ranged 973-1073 K were employed for the reaction study. Results from the catalytic activity yielded maximum conversion of 93% for both reactants, at reactants partial pressure of 20.3 kPa (stoichiometric point). In addition, syngas with maximum percentage yield of 67% and 65% for H2 and CO, respectively, was produced from the methane dry reforming reaction. Used catalyst characterization showed the existence of carbon deposit which could have emanated from methane decomposition. Elsevier Ltd 2017 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/15723/1/pagination_JNGSE_1970.pdf application/pdf en http://umpir.ump.edu.my/id/eprint/15723/7/fkksa-2017-ck-syngas%20production%20via%20methane.pdf Osazuwa, Osarieme U. and Setiabudi, H. D. and Ruwaida, Abdul Rasid and Cheng, C. K. (2017) Syngas Production via Methane Dry Reforming: A Novel Application of SmCoO3 Perovskite Catalyst. Journal of Natural Gas Science and Engineering, 37. pp. 435-448. ISSN 1875-5100 http://dx.doi.org/10.1016/j.jngse.2016.11.060 doi: 10.1016/j.jngse.2016.11.060
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English English
topic	TP Chemical technology
spellingShingle	TP Chemical technology Osazuwa, Osarieme U. Setiabudi, H. D. Ruwaida, Abdul Rasid Cheng, C. K. Syngas Production via Methane Dry Reforming: A Novel Application of SmCoO3 Perovskite Catalyst
description	In this study, SmCoO3 perovskite catalyst have been synthesized by the sol-gel citrate method and for the first time, applied as catalyst for the production of syngas (H2 and CO) via methane dry reforming reaction. The perovskite catalyst was characterized (pre- and post-reaction) to determine its physicochemical properties. Characterization of the calcined perovskite catalyst showed the formation of perovskite structure only. No other crystalline phases were detected. Prior to the catalytic test, the effects of reducing SmCoO3 perovskite catalyst with H2 (for activation) in the methane dry reforming reaction were investigated. Results showed no significant effects of H2 reduction on the activity of the SmCoO3 perovskite catalyst. This suggests that there was an in-situ reduction of SmCoO3 which was confirmed by XRD analysis of spent catalyst. Subsequently, reactant gases (CO2 and CH4) with partial pressure ranged 6.8-60.8 kPa and reaction temperature ranged 973-1073 K were employed for the reaction study. Results from the catalytic activity yielded maximum conversion of 93% for both reactants, at reactants partial pressure of 20.3 kPa (stoichiometric point). In addition, syngas with maximum percentage yield of 67% and 65% for H2 and CO, respectively, was produced from the methane dry reforming reaction. Used catalyst characterization showed the existence of carbon deposit which could have emanated from methane decomposition.
format	Article
author	Osazuwa, Osarieme U. Setiabudi, H. D. Ruwaida, Abdul Rasid Cheng, C. K.
author_facet	Osazuwa, Osarieme U. Setiabudi, H. D. Ruwaida, Abdul Rasid Cheng, C. K.
author_sort	Osazuwa, Osarieme U.
title	Syngas Production via Methane Dry Reforming: A Novel Application of SmCoO3 Perovskite Catalyst
title_short	Syngas Production via Methane Dry Reforming: A Novel Application of SmCoO3 Perovskite Catalyst
title_full	Syngas Production via Methane Dry Reforming: A Novel Application of SmCoO3 Perovskite Catalyst
title_fullStr	Syngas Production via Methane Dry Reforming: A Novel Application of SmCoO3 Perovskite Catalyst
title_full_unstemmed	Syngas Production via Methane Dry Reforming: A Novel Application of SmCoO3 Perovskite Catalyst
title_sort	syngas production via methane dry reforming: a novel application of smcoo3 perovskite catalyst
publisher	Elsevier Ltd
publishDate	2017
url	http://umpir.ump.edu.my/id/eprint/15723/ http://umpir.ump.edu.my/id/eprint/15723/ http://umpir.ump.edu.my/id/eprint/15723/ http://umpir.ump.edu.my/id/eprint/15723/1/pagination_JNGSE_1970.pdf http://umpir.ump.edu.my/id/eprint/15723/7/fkksa-2017-ck-syngas%20production%20via%20methane.pdf
first_indexed	2023-09-18T22:20:42Z
last_indexed	2023-09-18T22:20:42Z
_version_	1777415636681490432

Syngas Production via Methane Dry Reforming: A Novel Application of SmCoO3 Perovskite Catalyst

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