Syngas Production from Methane Dry Reforming Over 15wt%Ni/85wt%CaFe2O4 Catalyst

In the present study, syngas production from methane dry reforming over 15wt%Ni/85%CaFe2O4 catalyst was investigated. The CaFe2O4 was synthesized by sol gel method using stoichiometric ratio of Ca(NO3)2.4H2O and Fe(NO3)3.9H2O mixed in 30% aqueous NH3 solution. The 15wt%Ni/85%CaFe2O4 catalysts was sy...

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Main Authors: Hossain, M. Anwar, Ayodele, Bamidele V., Cheng, C. K., Khan, Maksudur R.
Format: Conference or Workshop Item
Language:English
Published: Universiti Malaysia Pahang 2016
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/15932/
http://umpir.ump.edu.my/id/eprint/15932/
http://umpir.ump.edu.my/id/eprint/15932/1/P023%20pg147-156.pdf
id ump-15932
recordtype eprints
spelling ump-159322019-08-28T07:13:49Z http://umpir.ump.edu.my/id/eprint/15932/ Syngas Production from Methane Dry Reforming Over 15wt%Ni/85wt%CaFe2O4 Catalyst Hossain, M. Anwar Ayodele, Bamidele V. Cheng, C. K. Khan, Maksudur R. TP Chemical technology In the present study, syngas production from methane dry reforming over 15wt%Ni/85%CaFe2O4 catalyst was investigated. The CaFe2O4 was synthesized by sol gel method using stoichiometric ratio of Ca(NO3)2.4H2O and Fe(NO3)3.9H2O mixed in 30% aqueous NH3 solution. The 15wt%Ni/85%CaFe2O4 catalysts was synthesized by impregnating required amount of aqueous solution of Ni(NO3)2.6H2O in 1g of CaFe2O4. The as-synthesized catalyst was characterized by XRD, SEM, EDX and FTIR for phase identification and crystallinity, morphology, elemental composition, and nature of chemical bonds. The catalytic activity of the catalyst was tested in methane dry reforming using a fixed bed continuous flow reactor. The catalyst activities were measured in terms of the reactant (CH4 and CO2) conversions and the products (H2 and CO) yield. The activity of catalyst in the methane dry reforming reaction resulted to highest CH4 and CO2 conversions of 90.4% and 87.6% respectively with a corresponding H2 and CO yield of 73.42% and 74.43% respectively. Syngas with H2:CO ratio of 0.986 was obtained from the methane dry reforming reaction over the 15%Ni/CaFe2O4 catalyst making it suitable for use as chemical intermediate for the synthesis of oxygenated fuels. Universiti Malaysia Pahang 2016 Conference or Workshop Item PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/15932/1/P023%20pg147-156.pdf Hossain, M. Anwar and Ayodele, Bamidele V. and Cheng, C. K. and Khan, Maksudur R. (2016) Syngas Production from Methane Dry Reforming Over 15wt%Ni/85wt%CaFe2O4 Catalyst. In: Proceedings of The National Conference for Postgraduate Research (NCON-PGR 2016), 24-25 September 2016 , Universiti Malaysia Pahang (UMP), Pekan, Pahang. pp. 147-156.. http://ee.ump.edu.my/ncon/wp-content/uploads/2016/10/Proceeding-NCON-PGR-2016.zip
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
language English
topic TP Chemical technology
spellingShingle TP Chemical technology
Hossain, M. Anwar
Ayodele, Bamidele V.
Cheng, C. K.
Khan, Maksudur R.
Syngas Production from Methane Dry Reforming Over 15wt%Ni/85wt%CaFe2O4 Catalyst
description In the present study, syngas production from methane dry reforming over 15wt%Ni/85%CaFe2O4 catalyst was investigated. The CaFe2O4 was synthesized by sol gel method using stoichiometric ratio of Ca(NO3)2.4H2O and Fe(NO3)3.9H2O mixed in 30% aqueous NH3 solution. The 15wt%Ni/85%CaFe2O4 catalysts was synthesized by impregnating required amount of aqueous solution of Ni(NO3)2.6H2O in 1g of CaFe2O4. The as-synthesized catalyst was characterized by XRD, SEM, EDX and FTIR for phase identification and crystallinity, morphology, elemental composition, and nature of chemical bonds. The catalytic activity of the catalyst was tested in methane dry reforming using a fixed bed continuous flow reactor. The catalyst activities were measured in terms of the reactant (CH4 and CO2) conversions and the products (H2 and CO) yield. The activity of catalyst in the methane dry reforming reaction resulted to highest CH4 and CO2 conversions of 90.4% and 87.6% respectively with a corresponding H2 and CO yield of 73.42% and 74.43% respectively. Syngas with H2:CO ratio of 0.986 was obtained from the methane dry reforming reaction over the 15%Ni/CaFe2O4 catalyst making it suitable for use as chemical intermediate for the synthesis of oxygenated fuels.
format Conference or Workshop Item
author Hossain, M. Anwar
Ayodele, Bamidele V.
Cheng, C. K.
Khan, Maksudur R.
author_facet Hossain, M. Anwar
Ayodele, Bamidele V.
Cheng, C. K.
Khan, Maksudur R.
author_sort Hossain, M. Anwar
title Syngas Production from Methane Dry Reforming Over 15wt%Ni/85wt%CaFe2O4 Catalyst
title_short Syngas Production from Methane Dry Reforming Over 15wt%Ni/85wt%CaFe2O4 Catalyst
title_full Syngas Production from Methane Dry Reforming Over 15wt%Ni/85wt%CaFe2O4 Catalyst
title_fullStr Syngas Production from Methane Dry Reforming Over 15wt%Ni/85wt%CaFe2O4 Catalyst
title_full_unstemmed Syngas Production from Methane Dry Reforming Over 15wt%Ni/85wt%CaFe2O4 Catalyst
title_sort syngas production from methane dry reforming over 15wt%ni/85wt%cafe2o4 catalyst
publisher Universiti Malaysia Pahang
publishDate 2016
url http://umpir.ump.edu.my/id/eprint/15932/
http://umpir.ump.edu.my/id/eprint/15932/
http://umpir.ump.edu.my/id/eprint/15932/1/P023%20pg147-156.pdf
first_indexed 2023-09-18T22:21:09Z
last_indexed 2023-09-18T22:21:09Z
_version_ 1777415665552982016