Conductivity Study On Plasticized Solid Bioelectrolytes CMC-NH¬4BR and Application In Solid-State Proton Batteries

This paper present the development of plasticized solid bio-electrolytes (PSBs) which has been accomplished by incorporating various composition of plasticizer namely ethylene carbonate (EC) with carboxy methylcellulose doped NH4Br via solution casting method. The plasticized polymer–salt ionic cond...

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Main Authors:	A. S., Samsudin, M. I. N., Isa
Format:	Article
Language:	English English
Published:	Penerbit Universiti Teknologi Malaysia 2016
Subjects:	QC Physics
Online Access:	http://umpir.ump.edu.my/id/eprint/16328/ http://umpir.ump.edu.my/id/eprint/16328/ http://umpir.ump.edu.my/id/eprint/16328/ http://umpir.ump.edu.my/id/eprint/16328/1/CONDUCTIVITY%20STUDY%20ON%20PLASTICIZED%20SOLID%20BIOELECTROLYTES.pdf http://umpir.ump.edu.my/id/eprint/16328/7/fist-2016-conductivity.pdf

id	ump-16328
recordtype	eprints
spelling	ump-163282017-02-09T05:44:20Z http://umpir.ump.edu.my/id/eprint/16328/ Conductivity Study On Plasticized Solid Bioelectrolytes CMC-NH¬4BR and Application In Solid-State Proton Batteries A. S., Samsudin M. I. N., Isa QC Physics This paper present the development of plasticized solid bio-electrolytes (PSBs) which has been accomplished by incorporating various composition of plasticizer namely ethylene carbonate (EC) with carboxy methylcellulose doped NH4Br via solution casting method. The plasticized polymer–salt ionic conduction of PSBs has been analyzed by electrical impedance spectroscopy. Plasticization using EC in PSBs system assists the enhancement of NH4Br dissociation and therefore increases the protonation process in the system. The highest ionic conductivity obtained for CMC−NH4Br containing with 25 wt. % NH4Br was achieved at 1.12 x 10-4 Scm-1 and improved to 3.31 x 10-3 Scm-1 when EC was added in PSBs system. The ionic conductivity-temperature for PSBs system was found to obey the Arrhenius relationships where the ionic conductivity increases with temperature. The solid-state proton batteries were assembled with the formation of Zn + ZnSO4.7H2O \|\| highest conducting PSBs system \|\| MnO2 and achieve with a maximum open circuit voltage (OCV) of 1.48 V at room temperature and showed good in rechargeablity performance with more than 10 cycles. Penerbit Universiti Teknologi Malaysia 2016-01-12 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/16328/1/CONDUCTIVITY%20STUDY%20ON%20PLASTICIZED%20SOLID%20BIOELECTROLYTES.pdf application/pdf en http://umpir.ump.edu.my/id/eprint/16328/7/fist-2016-conductivity.pdf A. S., Samsudin and M. I. N., Isa (2016) Conductivity Study On Plasticized Solid Bioelectrolytes CMC-NH¬4BR and Application In Solid-State Proton Batteries. Jurnal Teknologi (Sciences and Engineering), 78 (6-5). pp. 43-48. ISSN 0127-9696 (print); 2180-3722 (online) http://www.jurnalteknologi.utm.my/index.php/jurnalteknologi/article/view/8997 http://dx.doi.org/10.11113/jt.v78.8997
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English English
topic	QC Physics
spellingShingle	QC Physics A. S., Samsudin M. I. N., Isa Conductivity Study On Plasticized Solid Bioelectrolytes CMC-NH¬4BR and Application In Solid-State Proton Batteries
description	This paper present the development of plasticized solid bio-electrolytes (PSBs) which has been accomplished by incorporating various composition of plasticizer namely ethylene carbonate (EC) with carboxy methylcellulose doped NH4Br via solution casting method. The plasticized polymer–salt ionic conduction of PSBs has been analyzed by electrical impedance spectroscopy. Plasticization using EC in PSBs system assists the enhancement of NH4Br dissociation and therefore increases the protonation process in the system. The highest ionic conductivity obtained for CMC−NH4Br containing with 25 wt. % NH4Br was achieved at 1.12 x 10-4 Scm-1 and improved to 3.31 x 10-3 Scm-1 when EC was added in PSBs system. The ionic conductivity-temperature for PSBs system was found to obey the Arrhenius relationships where the ionic conductivity increases with temperature. The solid-state proton batteries were assembled with the formation of Zn + ZnSO4.7H2O \|\| highest conducting PSBs system \|\| MnO2 and achieve with a maximum open circuit voltage (OCV) of 1.48 V at room temperature and showed good in rechargeablity performance with more than 10 cycles.
format	Article
author	A. S., Samsudin M. I. N., Isa
author_facet	A. S., Samsudin M. I. N., Isa
author_sort	A. S., Samsudin
title	Conductivity Study On Plasticized Solid Bioelectrolytes CMC-NH¬4BR and Application In Solid-State Proton Batteries
title_short	Conductivity Study On Plasticized Solid Bioelectrolytes CMC-NH¬4BR and Application In Solid-State Proton Batteries
title_full	Conductivity Study On Plasticized Solid Bioelectrolytes CMC-NH¬4BR and Application In Solid-State Proton Batteries
title_fullStr	Conductivity Study On Plasticized Solid Bioelectrolytes CMC-NH¬4BR and Application In Solid-State Proton Batteries
title_full_unstemmed	Conductivity Study On Plasticized Solid Bioelectrolytes CMC-NH¬4BR and Application In Solid-State Proton Batteries
title_sort	conductivity study on plasticized solid bioelectrolytes cmc-nh¬4br and application in solid-state proton batteries
publisher	Penerbit Universiti Teknologi Malaysia
publishDate	2016
url	http://umpir.ump.edu.my/id/eprint/16328/ http://umpir.ump.edu.my/id/eprint/16328/ http://umpir.ump.edu.my/id/eprint/16328/ http://umpir.ump.edu.my/id/eprint/16328/1/CONDUCTIVITY%20STUDY%20ON%20PLASTICIZED%20SOLID%20BIOELECTROLYTES.pdf http://umpir.ump.edu.my/id/eprint/16328/7/fist-2016-conductivity.pdf
first_indexed	2023-09-18T22:21:53Z
last_indexed	2023-09-18T22:21:53Z
_version_	1777415711563448320

Conductivity Study On Plasticized Solid Bioelectrolytes CMC-NH¬4BR and Application In Solid-State Proton Batteries

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