Optical Detection and Efficient Removal of Transition Metal Ions from Water using Poly(hydroxamic acid) Ligand

A copolymer, cellulose-graft-poly(methyl acrylate), was synthesized by a free-radical initiating process, and the ester functional groups converted into the hydroxamic acid ligand. The pH of the solution acts as a key factor in achieving optical color signals of metal-complexation. The reflectance s...

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Main Authors:	Lutfor, M. R., Sarkar, Shaheen M., M. M., Yusoff, Mohd Harun, Abdullah
Format:	Article
Language:	English
Published:	Elsevier Ltd 2017
Subjects:	Q Science (General)
Online Access:	http://umpir.ump.edu.my/id/eprint/16398/ http://umpir.ump.edu.my/id/eprint/16398/ http://umpir.ump.edu.my/id/eprint/16398/ http://umpir.ump.edu.my/id/eprint/16398/1/Optical%20detection%20and%20efficient%20removal%20of%20transition%20metal%20ions.pdf

id	ump-16398
recordtype	eprints
spelling	ump-163982018-02-14T08:21:33Z http://umpir.ump.edu.my/id/eprint/16398/ Optical Detection and Efficient Removal of Transition Metal Ions from Water using Poly(hydroxamic acid) Ligand Lutfor, M. R. Sarkar, Shaheen M. M. M., Yusoff Mohd Harun, Abdullah Q Science (General) A copolymer, cellulose-graft-poly(methyl acrylate), was synthesized by a free-radical initiating process, and the ester functional groups converted into the hydroxamic acid ligand. The pH of the solution acts as a key factor in achieving optical color signals of metal-complexation. The reflectance spectra of the [M-ligand]n+ complex was found to be at the highest absorbance, ranging from 92 to 99% at pH 6, with absorbance noted to increase as metal ion concentrations were increased. A broad peak at 673 nm for Cu2+ was observed, indicating the presence of the charge transfer (π–π transition) complex. The developed ligand demonstrated superior adsorption capacity for copper (305.3 mg g−1), as well as strong adsorption capacity for other metals; the adsorption capacities for Fe3+, Mn2+, Co2+, Cr3+, Ni2+, and Zn2+ were 275.6, 258.5, 256.6, 254.3, 198.5, and 190.1 mg g−1, respectively. The experimental data of the adsorption kinetics of the metal ions fitted well with a pseudo-second-order rate equation. The obtained data demonstrated that the observed metal ion sorption was well fitted with the Langmuir isotherm model (R2 > 0.99), suggesting that the surface of the adsorbent is homogenous and monolayer. The reusability of the ligand was verified using the sorption/desorption process, demonstrating that the developed adsorbent can be reused for 12 cycles without significant loss of its original sensing and removal performance. Elsevier Ltd 2017 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/16398/1/Optical%20detection%20and%20efficient%20removal%20of%20transition%20metal%20ions.pdf Lutfor, M. R. and Sarkar, Shaheen M. and M. M., Yusoff and Mohd Harun, Abdullah (2017) Optical Detection and Efficient Removal of Transition Metal Ions from Water using Poly(hydroxamic acid) Ligand. Sensors and Actuators B: Chemical, 242. pp. 595-608. ISSN 0925-4005 http://doi.org/10.1016/j.snb.2016.11.007 DOI: 10.1016/j.snb.2016.11.007
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	Q Science (General)
spellingShingle	Q Science (General) Lutfor, M. R. Sarkar, Shaheen M. M. M., Yusoff Mohd Harun, Abdullah Optical Detection and Efficient Removal of Transition Metal Ions from Water using Poly(hydroxamic acid) Ligand
description	A copolymer, cellulose-graft-poly(methyl acrylate), was synthesized by a free-radical initiating process, and the ester functional groups converted into the hydroxamic acid ligand. The pH of the solution acts as a key factor in achieving optical color signals of metal-complexation. The reflectance spectra of the [M-ligand]n+ complex was found to be at the highest absorbance, ranging from 92 to 99% at pH 6, with absorbance noted to increase as metal ion concentrations were increased. A broad peak at 673 nm for Cu2+ was observed, indicating the presence of the charge transfer (π–π transition) complex. The developed ligand demonstrated superior adsorption capacity for copper (305.3 mg g−1), as well as strong adsorption capacity for other metals; the adsorption capacities for Fe3+, Mn2+, Co2+, Cr3+, Ni2+, and Zn2+ were 275.6, 258.5, 256.6, 254.3, 198.5, and 190.1 mg g−1, respectively. The experimental data of the adsorption kinetics of the metal ions fitted well with a pseudo-second-order rate equation. The obtained data demonstrated that the observed metal ion sorption was well fitted with the Langmuir isotherm model (R2 > 0.99), suggesting that the surface of the adsorbent is homogenous and monolayer. The reusability of the ligand was verified using the sorption/desorption process, demonstrating that the developed adsorbent can be reused for 12 cycles without significant loss of its original sensing and removal performance.
format	Article
author	Lutfor, M. R. Sarkar, Shaheen M. M. M., Yusoff Mohd Harun, Abdullah
author_facet	Lutfor, M. R. Sarkar, Shaheen M. M. M., Yusoff Mohd Harun, Abdullah
author_sort	Lutfor, M. R.
title	Optical Detection and Efficient Removal of Transition Metal Ions from Water using Poly(hydroxamic acid) Ligand
title_short	Optical Detection and Efficient Removal of Transition Metal Ions from Water using Poly(hydroxamic acid) Ligand
title_full	Optical Detection and Efficient Removal of Transition Metal Ions from Water using Poly(hydroxamic acid) Ligand
title_fullStr	Optical Detection and Efficient Removal of Transition Metal Ions from Water using Poly(hydroxamic acid) Ligand
title_full_unstemmed	Optical Detection and Efficient Removal of Transition Metal Ions from Water using Poly(hydroxamic acid) Ligand
title_sort	optical detection and efficient removal of transition metal ions from water using poly(hydroxamic acid) ligand
publisher	Elsevier Ltd
publishDate	2017
url	http://umpir.ump.edu.my/id/eprint/16398/ http://umpir.ump.edu.my/id/eprint/16398/ http://umpir.ump.edu.my/id/eprint/16398/ http://umpir.ump.edu.my/id/eprint/16398/1/Optical%20detection%20and%20efficient%20removal%20of%20transition%20metal%20ions.pdf
first_indexed	2023-09-18T22:22:02Z
last_indexed	2023-09-18T22:22:02Z
_version_	1777415720443838464

Optical Detection and Efficient Removal of Transition Metal Ions from Water using Poly(hydroxamic acid) Ligand

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