Synthesis, Spectral Characterization and Crystal Structure of (E)-4- Hydroxy-N -(2-methoxybenzylidene) benzohydrazide

Synthesis, Spectral Characterization and Crystal Structure of (E)-4- Hydroxy-N -(2-methoxybenzylidene) benzohydrazide

A Schiff base, (E)-4-Hydroxy-N -(2-methoxybenzylidene) benzohydrazide, (E4HB) had been synthesized in good yield by the acid-catalyzed condensation methoxybenzaldehyde and 4-hydroxybenzhydrazide in synthesized compound was elucidated by elemental analysis (CHN), FTIR, 13C-NMR and single crystal X-ra...

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Main Authors: Rassem, Hesham H. A., Nour, A. H.
Format: Article
Language:English
Published: AENSI Publishing 2016
Subjects:
TP Chemical technology
Online Access:http://umpir.ump.edu.my/id/eprint/16838/
http://umpir.ump.edu.my/id/eprint/16838/
http://umpir.ump.edu.my/id/eprint/16838/1/fkksa-2016-nhabdurahman-Synthesis%2C%20Spectra.pdf
id ump-16838
recordtype eprints
spelling ump-168382018-01-24T04:09:52Z http://umpir.ump.edu.my/id/eprint/16838/ Synthesis, Spectral Characterization and Crystal Structure of (E)-4- Hydroxy-N -(2-methoxybenzylidene) benzohydrazide Rassem, Hesham H. A. Nour, A. H. TP Chemical technology A Schiff base, (E)-4-Hydroxy-N -(2-methoxybenzylidene) benzohydrazide, (E4HB) had been synthesized in good yield by the acid-catalyzed condensation methoxybenzaldehyde and 4-hydroxybenzhydrazide in synthesized compound was elucidated by elemental analysis (CHN), FTIR, 13C-NMR and single crystal X-ray diffraction. E4HB crystallized in the crystal system with space group Z = 8, V = 2656.74(10) Å3 14.3951(3) Å, b = 8.7449(2) Å, c =21.1047(4) Å . The crystal structure of the compound is stabilized by intermolecular N1—H1N1….O2, O1 C13—H13A…O1 hydrogen bonds. A π—π interaction with centroid of 3.628 (6) A also occurs (Cg1 = C9— C14, -x, -y, -z). AENSI Publishing 2016 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/16838/1/fkksa-2016-nhabdurahman-Synthesis%2C%20Spectra.pdf Rassem, Hesham H. A. and Nour, A. H. (2016) Synthesis, Spectral Characterization and Crystal Structure of (E)-4- Hydroxy-N -(2-methoxybenzylidene) benzohydrazide. Australian Journal of Basic and Applied Sciences, 10 (1). pp. 513-516. ISSN 1991-8178 http://ajbasweb.com/old/ajbas/2016/January/513-516.pdf
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
language English
topic TP Chemical technology
spellingShingle TP Chemical technology
Rassem, Hesham H. A.
Nour, A. H.
Synthesis, Spectral Characterization and Crystal Structure of (E)-4- Hydroxy-N -(2-methoxybenzylidene) benzohydrazide
description A Schiff base, (E)-4-Hydroxy-N -(2-methoxybenzylidene) benzohydrazide, (E4HB) had been synthesized in good yield by the acid-catalyzed condensation methoxybenzaldehyde and 4-hydroxybenzhydrazide in synthesized compound was elucidated by elemental analysis (CHN), FTIR, 13C-NMR and single crystal X-ray diffraction. E4HB crystallized in the crystal system with space group Z = 8, V = 2656.74(10) Å3 14.3951(3) Å, b = 8.7449(2) Å, c =21.1047(4) Å . The crystal structure of the compound is stabilized by intermolecular N1—H1N1….O2, O1 C13—H13A…O1 hydrogen bonds. A π—π interaction with centroid of 3.628 (6) A also occurs (Cg1 = C9— C14, -x, -y, -z).
format Article
author Rassem, Hesham H. A.
Nour, A. H.
author_facet Rassem, Hesham H. A.
Nour, A. H.
author_sort Rassem, Hesham H. A.
title Synthesis, Spectral Characterization and Crystal Structure of (E)-4- Hydroxy-N -(2-methoxybenzylidene) benzohydrazide
title_short Synthesis, Spectral Characterization and Crystal Structure of (E)-4- Hydroxy-N -(2-methoxybenzylidene) benzohydrazide
title_full Synthesis, Spectral Characterization and Crystal Structure of (E)-4- Hydroxy-N -(2-methoxybenzylidene) benzohydrazide
title_fullStr Synthesis, Spectral Characterization and Crystal Structure of (E)-4- Hydroxy-N -(2-methoxybenzylidene) benzohydrazide
title_full_unstemmed Synthesis, Spectral Characterization and Crystal Structure of (E)-4- Hydroxy-N -(2-methoxybenzylidene) benzohydrazide
title_sort synthesis, spectral characterization and crystal structure of (e)-4- hydroxy-n -(2-methoxybenzylidene) benzohydrazide
publisher AENSI Publishing
publishDate 2016
url http://umpir.ump.edu.my/id/eprint/16838/
http://umpir.ump.edu.my/id/eprint/16838/
http://umpir.ump.edu.my/id/eprint/16838/1/fkksa-2016-nhabdurahman-Synthesis%2C%20Spectra.pdf
first_indexed 2023-09-18T22:22:51Z
last_indexed 2023-09-18T22:22:51Z
_version_ 1777415772677603328

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