Bio-Waste Corn–cob Cellulose Supported Poly(amidoxime) Palladium Nanoparticles for Suzuki-Miyaura Cross-Coupling Reactions

Waste corn-cob cellulose supported poly(amidoxime) palladium nanoparticles (PdNs@PA) were prepared by the surface modification of waste corn-cob cellulose through graft co-polymerization and subsequent amidoximation. The supported nanoperticles showed high catalytic activity (45-400 mol ppm) toward...

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Main Authors:	Sultana, Tahnim, Mandal, Bablu Hira, Lutfor, M. R., Sarkar, Shaheen M.
Format:	Article
Published:	Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim 2016
Subjects:	QD Chemistry
Online Access:	http://umpir.ump.edu.my/id/eprint/16925/ http://umpir.ump.edu.my/id/eprint/16925/ http://umpir.ump.edu.my/id/eprint/16925/

id	ump-16925
recordtype	eprints
spelling	ump-169252019-09-10T02:29:00Z http://umpir.ump.edu.my/id/eprint/16925/ Bio-Waste Corn–cob Cellulose Supported Poly(amidoxime) Palladium Nanoparticles for Suzuki-Miyaura Cross-Coupling Reactions Sultana, Tahnim Mandal, Bablu Hira Lutfor, M. R. Sarkar, Shaheen M. QD Chemistry Waste corn-cob cellulose supported poly(amidoxime) palladium nanoparticles (PdNs@PA) were prepared by the surface modification of waste corn-cob cellulose through graft co-polymerization and subsequent amidoximation. The supported nanoperticles showed high catalytic activity (45-400 mol ppm) towards Suzuki-Miyaura cross-coupling of aryl bromides/chlorides with organoboronic acids to give the corresponding biaryl products up to 99% yield with high turnover number (TON) 19777 and turnover frequency (TOF) 4944 h-1. The PdNs@PA was easily recovered from the reaction mixture and reused several times without significant loss of its catalytic activity Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim 2016 Article PeerReviewed Sultana, Tahnim and Mandal, Bablu Hira and Lutfor, M. R. and Sarkar, Shaheen M. (2016) Bio-Waste Corn–cob Cellulose Supported Poly(amidoxime) Palladium Nanoparticles for Suzuki-Miyaura Cross-Coupling Reactions. ChemistrySelect, 1 (13). pp. 4108-4112. ISSN 2365-6549 http://dx.doi.org/10.1002/slct.201600537 DOI: 10.1002/slct.201600537
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
topic	QD Chemistry
spellingShingle	QD Chemistry Sultana, Tahnim Mandal, Bablu Hira Lutfor, M. R. Sarkar, Shaheen M. Bio-Waste Corn–cob Cellulose Supported Poly(amidoxime) Palladium Nanoparticles for Suzuki-Miyaura Cross-Coupling Reactions
description	Waste corn-cob cellulose supported poly(amidoxime) palladium nanoparticles (PdNs@PA) were prepared by the surface modification of waste corn-cob cellulose through graft co-polymerization and subsequent amidoximation. The supported nanoperticles showed high catalytic activity (45-400 mol ppm) towards Suzuki-Miyaura cross-coupling of aryl bromides/chlorides with organoboronic acids to give the corresponding biaryl products up to 99% yield with high turnover number (TON) 19777 and turnover frequency (TOF) 4944 h-1. The PdNs@PA was easily recovered from the reaction mixture and reused several times without significant loss of its catalytic activity
format	Article
author	Sultana, Tahnim Mandal, Bablu Hira Lutfor, M. R. Sarkar, Shaheen M.
author_facet	Sultana, Tahnim Mandal, Bablu Hira Lutfor, M. R. Sarkar, Shaheen M.
author_sort	Sultana, Tahnim
title	Bio-Waste Corn–cob Cellulose Supported Poly(amidoxime) Palladium Nanoparticles for Suzuki-Miyaura Cross-Coupling Reactions
title_short	Bio-Waste Corn–cob Cellulose Supported Poly(amidoxime) Palladium Nanoparticles for Suzuki-Miyaura Cross-Coupling Reactions
title_full	Bio-Waste Corn–cob Cellulose Supported Poly(amidoxime) Palladium Nanoparticles for Suzuki-Miyaura Cross-Coupling Reactions
title_fullStr	Bio-Waste Corn–cob Cellulose Supported Poly(amidoxime) Palladium Nanoparticles for Suzuki-Miyaura Cross-Coupling Reactions
title_full_unstemmed	Bio-Waste Corn–cob Cellulose Supported Poly(amidoxime) Palladium Nanoparticles for Suzuki-Miyaura Cross-Coupling Reactions
title_sort	bio-waste corn–cob cellulose supported poly(amidoxime) palladium nanoparticles for suzuki-miyaura cross-coupling reactions
publisher	Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
publishDate	2016
url	http://umpir.ump.edu.my/id/eprint/16925/ http://umpir.ump.edu.my/id/eprint/16925/ http://umpir.ump.edu.my/id/eprint/16925/
first_indexed	2023-09-18T22:23:01Z
last_indexed	2023-09-18T22:23:01Z
_version_	1777415782576160768

Bio-Waste Corn–cob Cellulose Supported Poly(amidoxime) Palladium Nanoparticles for Suzuki-Miyaura Cross-Coupling Reactions

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