Highly Active Bio-Waste Cellulose Supported Poly(Amidoxime) Palladium(II) Complex for Heck Reactions

Highly Active Bio-Waste Cellulose Supported Poly(Amidoxime) Palladium(II) Complex for Heck Reactions

Corn-cob cellulose supported poly(amidoxime) Pd(II) complex was synthesized and characterized by field emission scanning electron microscopy (FE-SEM), high-resolution transmission electron microscopy (HR-TEM), energy dispersive X-ray (EDX), X-ray photoelectron spectroscopy (XPS), thermogravimetric a...

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Main Authors: Islam, Md. Shaharul, Lutfor, M. R., M. M., Yusoff, Sarkar, Shaheen M.
Format: Article
Language:English
Published: Elsevier 2017
Subjects:
Q Science (General)
Online Access:http://umpir.ump.edu.my/id/eprint/17471/
http://umpir.ump.edu.my/id/eprint/17471/
http://umpir.ump.edu.my/id/eprint/17471/
http://umpir.ump.edu.my/id/eprint/17471/2/Highly%20active%20bio-waste%20cellulose%20supported%20poly%28amidoxime%29%20palladium%28II%29%20complex%20for%20Heck%20reactions%201.pdf
id ump-17471
recordtype eprints
spelling ump-174712018-01-31T02:55:32Z http://umpir.ump.edu.my/id/eprint/17471/ Highly Active Bio-Waste Cellulose Supported Poly(Amidoxime) Palladium(II) Complex for Heck Reactions Islam, Md. Shaharul Lutfor, M. R. M. M., Yusoff Sarkar, Shaheen M. Q Science (General) Corn-cob cellulose supported poly(amidoxime) Pd(II) complex was synthesized and characterized by field emission scanning electron microscopy (FE-SEM), high-resolution transmission electron microscopy (HR-TEM), energy dispersive X-ray (EDX), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA) and inductively coupled plasma atomic emission spectroscopy (ICP-AES) analyses. The cellulose supported heterogeneous Pd(II) complex showed high stability and catalytic activity towards Mizoroki-Heck reaction of aryl halides and arenediazonium tetrafluoroborate with a variety of olefins to give the corresponding cross-coupling products in up to 97% yield. The Pd(II) complex was separated from the reaction mixtures and repeatedly used up to seven times without any significant decrease of its catalytic performance. Elsevier 2017 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/17471/2/Highly%20active%20bio-waste%20cellulose%20supported%20poly%28amidoxime%29%20palladium%28II%29%20complex%20for%20Heck%20reactions%201.pdf Islam, Md. Shaharul and Lutfor, M. R. and M. M., Yusoff and Sarkar, Shaheen M. (2017) Highly Active Bio-Waste Cellulose Supported Poly(Amidoxime) Palladium(II) Complex for Heck Reactions. Journal of Cleaner Production, 149. pp. 1045-1050. ISSN 0959-6526 (print), 1879-1786 (online) https://doi.org/10.1016/j.jclepro.2017.02.121 doi: 10.1016/j.jclepro.2017.02.121
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
language English
topic Q Science (General)
spellingShingle Q Science (General)
Islam, Md. Shaharul
Lutfor, M. R.
M. M., Yusoff
Sarkar, Shaheen M.
Highly Active Bio-Waste Cellulose Supported Poly(Amidoxime) Palladium(II) Complex for Heck Reactions
description Corn-cob cellulose supported poly(amidoxime) Pd(II) complex was synthesized and characterized by field emission scanning electron microscopy (FE-SEM), high-resolution transmission electron microscopy (HR-TEM), energy dispersive X-ray (EDX), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA) and inductively coupled plasma atomic emission spectroscopy (ICP-AES) analyses. The cellulose supported heterogeneous Pd(II) complex showed high stability and catalytic activity towards Mizoroki-Heck reaction of aryl halides and arenediazonium tetrafluoroborate with a variety of olefins to give the corresponding cross-coupling products in up to 97% yield. The Pd(II) complex was separated from the reaction mixtures and repeatedly used up to seven times without any significant decrease of its catalytic performance.
format Article
author Islam, Md. Shaharul
Lutfor, M. R.
M. M., Yusoff
Sarkar, Shaheen M.
author_facet Islam, Md. Shaharul
Lutfor, M. R.
M. M., Yusoff
Sarkar, Shaheen M.
author_sort Islam, Md. Shaharul
title Highly Active Bio-Waste Cellulose Supported Poly(Amidoxime) Palladium(II) Complex for Heck Reactions
title_short Highly Active Bio-Waste Cellulose Supported Poly(Amidoxime) Palladium(II) Complex for Heck Reactions
title_full Highly Active Bio-Waste Cellulose Supported Poly(Amidoxime) Palladium(II) Complex for Heck Reactions
title_fullStr Highly Active Bio-Waste Cellulose Supported Poly(Amidoxime) Palladium(II) Complex for Heck Reactions
title_full_unstemmed Highly Active Bio-Waste Cellulose Supported Poly(Amidoxime) Palladium(II) Complex for Heck Reactions
title_sort highly active bio-waste cellulose supported poly(amidoxime) palladium(ii) complex for heck reactions
publisher Elsevier
publishDate 2017
url http://umpir.ump.edu.my/id/eprint/17471/
http://umpir.ump.edu.my/id/eprint/17471/
http://umpir.ump.edu.my/id/eprint/17471/
http://umpir.ump.edu.my/id/eprint/17471/2/Highly%20active%20bio-waste%20cellulose%20supported%20poly%28amidoxime%29%20palladium%28II%29%20complex%20for%20Heck%20reactions%201.pdf
first_indexed 2023-09-18T22:24:08Z
last_indexed 2023-09-18T22:24:08Z
_version_ 1777415853303660544

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