Investigation on Electrical Conduction Mechanism of Plasticized Carboxymethyl Cellulose-NH4Br Solid Bio-Polymer Electrolytes

Since the introduction of solid polymer based electrolytes in 1973, numerous polymers are particularly interesting especially bio-polymer have been investigate (Kadir et al., 2014; Samsudin et al., 2012; Buraidah et al., 2011). The main interest in developing solid-state polymer electrolyte lies in...

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Main Authors:	A. S., Samsudin, M. I. N., Isa
Format:	Conference or Workshop Item
Language:	English English
Published:	2017
Subjects:	Q Science (General)
Online Access:	http://umpir.ump.edu.my/id/eprint/17659/ http://umpir.ump.edu.my/id/eprint/17659/1/Investigation%20on%20electrical%20conduction%20mechanism%20of%20plasticized%20carboxymethyl%20cellulose-NH4Br%20solid%20bio-polymer%20electrolytes.pdf http://umpir.ump.edu.my/id/eprint/17659/7/Investigation%20on%20electrical%20conduction%20mechanism%20of%20plasticized%20carboxymethyl%20cellulose-NH4Br%20solid%20bio-polymer%20electrolytes%201.pdf

id	ump-17659
recordtype	eprints
spelling	ump-176592018-07-20T01:41:59Z http://umpir.ump.edu.my/id/eprint/17659/ Investigation on Electrical Conduction Mechanism of Plasticized Carboxymethyl Cellulose-NH4Br Solid Bio-Polymer Electrolytes A. S., Samsudin M. I. N., Isa Q Science (General) Since the introduction of solid polymer based electrolytes in 1973, numerous polymers are particularly interesting especially bio-polymer have been investigate (Kadir et al., 2014; Samsudin et al., 2012; Buraidah et al., 2011). The main interest in developing solid-state polymer electrolyte lies in the hope that such systems will avoid many of the problems encountered when using electrochemical devices with liquid constituents. The costly and rare raw materials that are required, along with expensive materials processing, make for steep barriers to overcome when it comes to power source development. In arrears to the fact given the development of plasticized solid bio-polymer electrolytes (SBEs) has been accomplished in this work by incorporating various composition of plasticizer with CMC-NH4Br via solution casting method. The plasticized biopolymer–salt complex ionic conduction and electrical properties of the SBEs have been analyzed through impedance measurement. The ionic conductivity at room temperature for the CMC-NH4Br SBEs system was achieved at ~10-4 S cm-1 when 25 wt. % NH4Br was added and were improved to (~ 10-3 S cm-1) with introducing of plasticizer in SBEs system. The temperature dependence of the prepared SBEs system exhibits Arrhenius behavior. The Jonschers power law was used to study the ac conductivity data and the conduction mechanism studies shown the highest conducting CMC SBEs system can be best represented by OLPT model (PEG), SPH model (glycerol) and QMT model (EC). 2017 Conference or Workshop Item PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/17659/1/Investigation%20on%20electrical%20conduction%20mechanism%20of%20plasticized%20carboxymethyl%20cellulose-NH4Br%20solid%20bio-polymer%20electrolytes.pdf pdf en http://umpir.ump.edu.my/id/eprint/17659/7/Investigation%20on%20electrical%20conduction%20mechanism%20of%20plasticized%20carboxymethyl%20cellulose-NH4Br%20solid%20bio-polymer%20electrolytes%201.pdf A. S., Samsudin and M. I. N., Isa (2017) Investigation on Electrical Conduction Mechanism of Plasticized Carboxymethyl Cellulose-NH4Br Solid Bio-Polymer Electrolytes. In: The 5th International Symposium on Fundamental and Applied Sciences, 29-31 March 2017 , Nagoya, Japan. pp. 1-3.. (Unpublished)
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English English
topic	Q Science (General)
spellingShingle	Q Science (General) A. S., Samsudin M. I. N., Isa Investigation on Electrical Conduction Mechanism of Plasticized Carboxymethyl Cellulose-NH4Br Solid Bio-Polymer Electrolytes
description	Since the introduction of solid polymer based electrolytes in 1973, numerous polymers are particularly interesting especially bio-polymer have been investigate (Kadir et al., 2014; Samsudin et al., 2012; Buraidah et al., 2011). The main interest in developing solid-state polymer electrolyte lies in the hope that such systems will avoid many of the problems encountered when using electrochemical devices with liquid constituents. The costly and rare raw materials that are required, along with expensive materials processing, make for steep barriers to overcome when it comes to power source development. In arrears to the fact given the development of plasticized solid bio-polymer electrolytes (SBEs) has been accomplished in this work by incorporating various composition of plasticizer with CMC-NH4Br via solution casting method. The plasticized biopolymer–salt complex ionic conduction and electrical properties of the SBEs have been analyzed through impedance measurement. The ionic conductivity at room temperature for the CMC-NH4Br SBEs system was achieved at ~10-4 S cm-1 when 25 wt. % NH4Br was added and were improved to (~ 10-3 S cm-1) with introducing of plasticizer in SBEs system. The temperature dependence of the prepared SBEs system exhibits Arrhenius behavior. The Jonschers power law was used to study the ac conductivity data and the conduction mechanism studies shown the highest conducting CMC SBEs system can be best represented by OLPT model (PEG), SPH model (glycerol) and QMT model (EC).
format	Conference or Workshop Item
author	A. S., Samsudin M. I. N., Isa
author_facet	A. S., Samsudin M. I. N., Isa
author_sort	A. S., Samsudin
title	Investigation on Electrical Conduction Mechanism of Plasticized Carboxymethyl Cellulose-NH4Br Solid Bio-Polymer Electrolytes
title_short	Investigation on Electrical Conduction Mechanism of Plasticized Carboxymethyl Cellulose-NH4Br Solid Bio-Polymer Electrolytes
title_full	Investigation on Electrical Conduction Mechanism of Plasticized Carboxymethyl Cellulose-NH4Br Solid Bio-Polymer Electrolytes
title_fullStr	Investigation on Electrical Conduction Mechanism of Plasticized Carboxymethyl Cellulose-NH4Br Solid Bio-Polymer Electrolytes
title_full_unstemmed	Investigation on Electrical Conduction Mechanism of Plasticized Carboxymethyl Cellulose-NH4Br Solid Bio-Polymer Electrolytes
title_sort	investigation on electrical conduction mechanism of plasticized carboxymethyl cellulose-nh4br solid bio-polymer electrolytes
publishDate	2017
url	http://umpir.ump.edu.my/id/eprint/17659/ http://umpir.ump.edu.my/id/eprint/17659/1/Investigation%20on%20electrical%20conduction%20mechanism%20of%20plasticized%20carboxymethyl%20cellulose-NH4Br%20solid%20bio-polymer%20electrolytes.pdf http://umpir.ump.edu.my/id/eprint/17659/7/Investigation%20on%20electrical%20conduction%20mechanism%20of%20plasticized%20carboxymethyl%20cellulose-NH4Br%20solid%20bio-polymer%20electrolytes%201.pdf
first_indexed	2023-09-18T22:24:32Z
last_indexed	2023-09-18T22:24:32Z
_version_	1777415877742821376

Investigation on Electrical Conduction Mechanism of Plasticized Carboxymethyl Cellulose-NH4Br Solid Bio-Polymer Electrolytes

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