Influence of Polyethylene Glycol (PEG) in CMC-NH4BR Based Polymer Electrolytes: Conductivity and Electrical Study

The present work was carried with new type and promising polymer electrolytes system by development of carboxyl methylcellulose (CMC) doped NH4Br and plasticized with polyethylene glycol (PEG). The sample was successfully prepared via solution casting with no separation phase and good mechanical p...

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Main Authors:	Nur Khalidah, Zainuddin, Ahmad Salihin, Samsudin
Format:	Article
Language:	English
Published:	DRPM Universitas Indonesia 2017
Subjects:	Q Science (General)
Online Access:	http://umpir.ump.edu.my/id/eprint/17756/ http://umpir.ump.edu.my/id/eprint/17756/ http://umpir.ump.edu.my/id/eprint/17756/ http://umpir.ump.edu.my/id/eprint/17756/1/Influence%20of%20Polyethylene%20Glycol%20%28PEG%29%20in%20CMC-NH4BR%20Based%20Polymer%20Electrolytes%20Conductivity%20and%20Electrical%20Study.pdf

id	ump-17756
recordtype	eprints
spelling	ump-177562018-07-26T01:51:16Z http://umpir.ump.edu.my/id/eprint/17756/ Influence of Polyethylene Glycol (PEG) in CMC-NH4BR Based Polymer Electrolytes: Conductivity and Electrical Study Nur Khalidah, Zainuddin Ahmad Salihin, Samsudin Q Science (General) The present work was carried with new type and promising polymer electrolytes system by development of carboxyl methylcellulose (CMC) doped NH4Br and plasticized with polyethylene glycol (PEG). The sample was successfully prepared via solution casting with no separation phase and good mechanical properties. The electrical conductivity and thermal conductivity of CMC-NH4Br-PEG based PEs system have been measured by the electrical impedance spectroscopy method in the temperature range of 303–373 K. The highest ionic conductivity gained is 2.48 x 10-3 Scm-1 at ambient temperature for sample contain with 8 wt. % PEG. It can be concluded that the plasticized is accountable for the conductance and assist to enhancing the ionic conductivity of the CMC-NH4Br-PEG electrolyte system. The addition of PEG to the CMC-based electrolyte can enhance towards the cation mobility which is turn increases ionic conductivity. The conductivity-temperature of plasticized BdPEs system was found obeys the Arrhenius relation where the ionic conductivity increases with temperature and activation energy for the ions hopping of the highest conducting PEs system only required small value to migrate. The electrical studies show a non-Debye behaviour of BdPEs based on the analyzed data using complex permittivity, ε* and complex electrical modulus, M* of the sample at different temperature. DRPM Universitas Indonesia 2017 Article PeerReviewed application/pdf en cc_by http://umpir.ump.edu.my/id/eprint/17756/1/Influence%20of%20Polyethylene%20Glycol%20%28PEG%29%20in%20CMC-NH4BR%20Based%20Polymer%20Electrolytes%20Conductivity%20and%20Electrical%20Study.pdf Nur Khalidah, Zainuddin and Ahmad Salihin, Samsudin (2017) Influence of Polyethylene Glycol (PEG) in CMC-NH4BR Based Polymer Electrolytes: Conductivity and Electrical Study. Makara Journal of Technology, 21 (1). pp. 37-42. ISSN 2355-2786 http://journal.ui.ac.id/technology/index.php/journal/article/view/3078 DOI: 10.7454/mst.v21i1.3078
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	Q Science (General)
spellingShingle	Q Science (General) Nur Khalidah, Zainuddin Ahmad Salihin, Samsudin Influence of Polyethylene Glycol (PEG) in CMC-NH4BR Based Polymer Electrolytes: Conductivity and Electrical Study
description	The present work was carried with new type and promising polymer electrolytes system by development of carboxyl methylcellulose (CMC) doped NH4Br and plasticized with polyethylene glycol (PEG). The sample was successfully prepared via solution casting with no separation phase and good mechanical properties. The electrical conductivity and thermal conductivity of CMC-NH4Br-PEG based PEs system have been measured by the electrical impedance spectroscopy method in the temperature range of 303–373 K. The highest ionic conductivity gained is 2.48 x 10-3 Scm-1 at ambient temperature for sample contain with 8 wt. % PEG. It can be concluded that the plasticized is accountable for the conductance and assist to enhancing the ionic conductivity of the CMC-NH4Br-PEG electrolyte system. The addition of PEG to the CMC-based electrolyte can enhance towards the cation mobility which is turn increases ionic conductivity. The conductivity-temperature of plasticized BdPEs system was found obeys the Arrhenius relation where the ionic conductivity increases with temperature and activation energy for the ions hopping of the highest conducting PEs system only required small value to migrate. The electrical studies show a non-Debye behaviour of BdPEs based on the analyzed data using complex permittivity, ε* and complex electrical modulus, M* of the sample at different temperature.
format	Article
author	Nur Khalidah, Zainuddin Ahmad Salihin, Samsudin
author_facet	Nur Khalidah, Zainuddin Ahmad Salihin, Samsudin
author_sort	Nur Khalidah, Zainuddin
title	Influence of Polyethylene Glycol (PEG) in CMC-NH4BR Based Polymer Electrolytes: Conductivity and Electrical Study
title_short	Influence of Polyethylene Glycol (PEG) in CMC-NH4BR Based Polymer Electrolytes: Conductivity and Electrical Study
title_full	Influence of Polyethylene Glycol (PEG) in CMC-NH4BR Based Polymer Electrolytes: Conductivity and Electrical Study
title_fullStr	Influence of Polyethylene Glycol (PEG) in CMC-NH4BR Based Polymer Electrolytes: Conductivity and Electrical Study
title_full_unstemmed	Influence of Polyethylene Glycol (PEG) in CMC-NH4BR Based Polymer Electrolytes: Conductivity and Electrical Study
title_sort	influence of polyethylene glycol (peg) in cmc-nh4br based polymer electrolytes: conductivity and electrical study
publisher	DRPM Universitas Indonesia
publishDate	2017
url	http://umpir.ump.edu.my/id/eprint/17756/ http://umpir.ump.edu.my/id/eprint/17756/ http://umpir.ump.edu.my/id/eprint/17756/ http://umpir.ump.edu.my/id/eprint/17756/1/Influence%20of%20Polyethylene%20Glycol%20%28PEG%29%20in%20CMC-NH4BR%20Based%20Polymer%20Electrolytes%20Conductivity%20and%20Electrical%20Study.pdf
first_indexed	2023-09-18T22:24:43Z
last_indexed	2023-09-18T22:24:43Z
_version_	1777415889315954688

Influence of Polyethylene Glycol (PEG) in CMC-NH4BR Based Polymer Electrolytes: Conductivity and Electrical Study

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