A novel approaches an enhancement of ammonium salts-based cellulose derivative proton conductive polymer electrolytes for protonic battery applications

A novel approaches an enhancement of ammonium salts-based cellulose derivative proton conductive polymer electrolytes for protonic battery applications

Since the introduction of solid polymer electrolytes in 1973, numerous polymers are particularly interesting especially bio-polymer have been investigate. The main interest in developing polymer electrolyte lies in the hope that such systems will avoid many of the problems encountered when using ele...

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Main Authors: A. S., Samsudin, M. I. N., Isa
Format: Conference or Workshop Item
Language:English
Published: 2017
Subjects:
TP Chemical technology
Online Access:http://umpir.ump.edu.my/id/eprint/18937/
http://umpir.ump.edu.my/id/eprint/18937/1/15.%20A%20novel%20approaches%20an%20enhancement%20of%20ammonium%20salts-based%20cellulose%20derivative%20proton%20conductive%20polymer%20electrolytes%20for%20protonic%20battery%20applications.pdf
id ump-18937
recordtype eprints
spelling ump-189372019-03-20T02:25:38Z http://umpir.ump.edu.my/id/eprint/18937/ A novel approaches an enhancement of ammonium salts-based cellulose derivative proton conductive polymer electrolytes for protonic battery applications A. S., Samsudin M. I. N., Isa TP Chemical technology Since the introduction of solid polymer electrolytes in 1973, numerous polymers are particularly interesting especially bio-polymer have been investigate. The main interest in developing polymer electrolyte lies in the hope that such systems will avoid many of the problems encountered when using electrochemical devices with liquid constituents which costly along with expensive materials processing. In arrears to the fact given, the development of plasticized polymer electrolytes (PPEs) has been accomplished in this work by incorporating various composition of plasticizer with CMC-NH4Br via solution casting method. The PPEs system formation has been analyzed through FTIR spectroscopy, X-RD, impedance and TNM method. The highest conducting CMC PPEs was achieved at ~10-4 Scm-1 with addition of 25 wt. % NH4Br and was improved to ~10-3 S cm-1 when plasticized with 8 wt. % EC. It has been shown that the conducting element in this work are predominantly due to proton (H+) which was confirmed via FTIR and TNM analysis. Proton conducting PPEs battery have been fabricated with the configuration of Zn+ZnSO4.7H2O//MnO2 and produced a maximum open circuit potential (OCP) of 1.48 V at ambient temperature and showed good rechargeability. This work implies that the possible practical application of the present electrolytes as a new candidates in the fabrication of electrochemical devices. 2017-03 Conference or Workshop Item PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/18937/1/15.%20A%20novel%20approaches%20an%20enhancement%20of%20ammonium%20salts-based%20cellulose%20derivative%20proton%20conductive%20polymer%20electrolytes%20for%20protonic%20battery%20applications.pdf A. S., Samsudin and M. I. N., Isa (2017) A novel approaches an enhancement of ammonium salts-based cellulose derivative proton conductive polymer electrolytes for protonic battery applications. In: Global Conference On Polymer And Composite Materials (PCM 2017), 23-25 Mei 2017 , Pusan National University. p. 1.. (Unpublished)
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
language English
topic TP Chemical technology
spellingShingle TP Chemical technology
A. S., Samsudin
M. I. N., Isa
A novel approaches an enhancement of ammonium salts-based cellulose derivative proton conductive polymer electrolytes for protonic battery applications
description Since the introduction of solid polymer electrolytes in 1973, numerous polymers are particularly interesting especially bio-polymer have been investigate. The main interest in developing polymer electrolyte lies in the hope that such systems will avoid many of the problems encountered when using electrochemical devices with liquid constituents which costly along with expensive materials processing. In arrears to the fact given, the development of plasticized polymer electrolytes (PPEs) has been accomplished in this work by incorporating various composition of plasticizer with CMC-NH4Br via solution casting method. The PPEs system formation has been analyzed through FTIR spectroscopy, X-RD, impedance and TNM method. The highest conducting CMC PPEs was achieved at ~10-4 Scm-1 with addition of 25 wt. % NH4Br and was improved to ~10-3 S cm-1 when plasticized with 8 wt. % EC. It has been shown that the conducting element in this work are predominantly due to proton (H+) which was confirmed via FTIR and TNM analysis. Proton conducting PPEs battery have been fabricated with the configuration of Zn+ZnSO4.7H2O//MnO2 and produced a maximum open circuit potential (OCP) of 1.48 V at ambient temperature and showed good rechargeability. This work implies that the possible practical application of the present electrolytes as a new candidates in the fabrication of electrochemical devices.
format Conference or Workshop Item
author A. S., Samsudin
M. I. N., Isa
author_facet A. S., Samsudin
M. I. N., Isa
author_sort A. S., Samsudin
title A novel approaches an enhancement of ammonium salts-based cellulose derivative proton conductive polymer electrolytes for protonic battery applications
title_short A novel approaches an enhancement of ammonium salts-based cellulose derivative proton conductive polymer electrolytes for protonic battery applications
title_full A novel approaches an enhancement of ammonium salts-based cellulose derivative proton conductive polymer electrolytes for protonic battery applications
title_fullStr A novel approaches an enhancement of ammonium salts-based cellulose derivative proton conductive polymer electrolytes for protonic battery applications
title_full_unstemmed A novel approaches an enhancement of ammonium salts-based cellulose derivative proton conductive polymer electrolytes for protonic battery applications
title_sort novel approaches an enhancement of ammonium salts-based cellulose derivative proton conductive polymer electrolytes for protonic battery applications
publishDate 2017
url http://umpir.ump.edu.my/id/eprint/18937/
http://umpir.ump.edu.my/id/eprint/18937/1/15.%20A%20novel%20approaches%20an%20enhancement%20of%20ammonium%20salts-based%20cellulose%20derivative%20proton%20conductive%20polymer%20electrolytes%20for%20protonic%20battery%20applications.pdf
first_indexed 2023-09-18T22:27:04Z
last_indexed 2023-09-18T22:27:04Z
_version_ 1777416037746081792

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