Facile synthesis of N- (4-bromophenyl)-1- (3-bromothiophen-2-yl)methanimine derivatives via Suzuki cross-coupling reaction: their characterization and DFT studies

A variety of imine derivatives have been synthesized via Suzuki cross coupling of N-(4-bromophenyl)-1-(3-bromothiophen-2-yl)methanimine with various arylboronic acids in moderate to good yields (58–72%). A wide range of electron donating and withdrawing functional groups were well tolerated in react...

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Main Authors:	Rizwan, Komal, Rasool, Nasir, Rehman, Ravya, Mahmood, Tariq, Ayub, Khurshid, Rasheed, Tahir, Ahmad, Gulraiz, Malik, Ayesha, Khan, Shakeel Ahmad, Akhtar, Muhammad Nadeem, Noorjahan Banu, Alitheen, Muhammad Nazirul, Mubin Aziz
Format:	Article
Language:	English
Published:	Springer Open 2018
Subjects:	QC Physics
Online Access:	http://umpir.ump.edu.my/id/eprint/21781/ http://umpir.ump.edu.my/id/eprint/21781/ http://umpir.ump.edu.my/id/eprint/21781/ http://umpir.ump.edu.my/id/eprint/21781/1/Facile%20synthesis%20of%20N-.pdf

id	ump-21781
recordtype	eprints
spelling	ump-217812018-07-25T03:26:33Z http://umpir.ump.edu.my/id/eprint/21781/ Facile synthesis of N- (4-bromophenyl)-1- (3-bromothiophen-2-yl)methanimine derivatives via Suzuki cross-coupling reaction: their characterization and DFT studies Rizwan, Komal Rasool, Nasir Rehman, Ravya Mahmood, Tariq Ayub, Khurshid Rasheed, Tahir Ahmad, Gulraiz Malik, Ayesha Khan, Shakeel Ahmad Akhtar, Muhammad Nadeem Noorjahan Banu, Alitheen Muhammad Nazirul, Mubin Aziz QC Physics A variety of imine derivatives have been synthesized via Suzuki cross coupling of N-(4-bromophenyl)-1-(3-bromothiophen-2-yl)methanimine with various arylboronic acids in moderate to good yields (58–72%). A wide range of electron donating and withdrawing functional groups were well tolerated in reaction conditions. To explore the structural properties, Density functional theory (DFT) investigations on all synthesized molecules (3a–3i) were performed. Conceptual DFT reactivity descriptors and molecular electrostatic potential analyses were performed by using B3LYP/6-31G(d,p) method to explore the reactivity and reacting sites of all derivatives (3a–3i). Springer Open 2018 Article PeerReviewed pdf en cc_by http://umpir.ump.edu.my/id/eprint/21781/1/Facile%20synthesis%20of%20N-.pdf Rizwan, Komal and Rasool, Nasir and Rehman, Ravya and Mahmood, Tariq and Ayub, Khurshid and Rasheed, Tahir and Ahmad, Gulraiz and Malik, Ayesha and Khan, Shakeel Ahmad and Akhtar, Muhammad Nadeem and Noorjahan Banu, Alitheen and Muhammad Nazirul, Mubin Aziz (2018) Facile synthesis of N- (4-bromophenyl)-1- (3-bromothiophen-2-yl)methanimine derivatives via Suzuki cross-coupling reaction: their characterization and DFT studies. Chemistry Central Journal, 12 (18). pp. 1-9. ISSN 1752-153X https://doi.org/10.1186/s13065-018-0451-0 doi: 10.1186/s13065-018-0451-0
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	QC Physics
spellingShingle	QC Physics Rizwan, Komal Rasool, Nasir Rehman, Ravya Mahmood, Tariq Ayub, Khurshid Rasheed, Tahir Ahmad, Gulraiz Malik, Ayesha Khan, Shakeel Ahmad Akhtar, Muhammad Nadeem Noorjahan Banu, Alitheen Muhammad Nazirul, Mubin Aziz Facile synthesis of N- (4-bromophenyl)-1- (3-bromothiophen-2-yl)methanimine derivatives via Suzuki cross-coupling reaction: their characterization and DFT studies
description	A variety of imine derivatives have been synthesized via Suzuki cross coupling of N-(4-bromophenyl)-1-(3-bromothiophen-2-yl)methanimine with various arylboronic acids in moderate to good yields (58–72%). A wide range of electron donating and withdrawing functional groups were well tolerated in reaction conditions. To explore the structural properties, Density functional theory (DFT) investigations on all synthesized molecules (3a–3i) were performed. Conceptual DFT reactivity descriptors and molecular electrostatic potential analyses were performed by using B3LYP/6-31G(d,p) method to explore the reactivity and reacting sites of all derivatives (3a–3i).
format	Article
author	Rizwan, Komal Rasool, Nasir Rehman, Ravya Mahmood, Tariq Ayub, Khurshid Rasheed, Tahir Ahmad, Gulraiz Malik, Ayesha Khan, Shakeel Ahmad Akhtar, Muhammad Nadeem Noorjahan Banu, Alitheen Muhammad Nazirul, Mubin Aziz
author_facet	Rizwan, Komal Rasool, Nasir Rehman, Ravya Mahmood, Tariq Ayub, Khurshid Rasheed, Tahir Ahmad, Gulraiz Malik, Ayesha Khan, Shakeel Ahmad Akhtar, Muhammad Nadeem Noorjahan Banu, Alitheen Muhammad Nazirul, Mubin Aziz
author_sort	Rizwan, Komal
title	Facile synthesis of N- (4-bromophenyl)-1- (3-bromothiophen-2-yl)methanimine derivatives via Suzuki cross-coupling reaction: their characterization and DFT studies
title_short	Facile synthesis of N- (4-bromophenyl)-1- (3-bromothiophen-2-yl)methanimine derivatives via Suzuki cross-coupling reaction: their characterization and DFT studies
title_full	Facile synthesis of N- (4-bromophenyl)-1- (3-bromothiophen-2-yl)methanimine derivatives via Suzuki cross-coupling reaction: their characterization and DFT studies
title_fullStr	Facile synthesis of N- (4-bromophenyl)-1- (3-bromothiophen-2-yl)methanimine derivatives via Suzuki cross-coupling reaction: their characterization and DFT studies
title_full_unstemmed	Facile synthesis of N- (4-bromophenyl)-1- (3-bromothiophen-2-yl)methanimine derivatives via Suzuki cross-coupling reaction: their characterization and DFT studies
title_sort	facile synthesis of n- (4-bromophenyl)-1- (3-bromothiophen-2-yl)methanimine derivatives via suzuki cross-coupling reaction: their characterization and dft studies
publisher	Springer Open
publishDate	2018
url	http://umpir.ump.edu.my/id/eprint/21781/ http://umpir.ump.edu.my/id/eprint/21781/ http://umpir.ump.edu.my/id/eprint/21781/ http://umpir.ump.edu.my/id/eprint/21781/1/Facile%20synthesis%20of%20N-.pdf
first_indexed	2023-09-18T22:32:07Z
last_indexed	2023-09-18T22:32:07Z
_version_	1777416354776743936

Facile synthesis of N- (4-bromophenyl)-1- (3-bromothiophen-2-yl)methanimine derivatives via Suzuki cross-coupling reaction: their characterization and DFT studies

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