Hydrogen production form ethanol dry reforming over lanthania-promoted Co/Al2O3 catalyst

La-promoted and unpromoted 10%Co/Al2O3 catalysts were synthesized using wet a impregnation method and evaluated in a quartz fixed-bed reactor at different CO2:C2H5OH ratios of 2.5:1-1:2.5 and a reaction temperature of 973 K under atmospheric pressure. X-ray diffraction measurements detected the pres...

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Main Authors:	Fayaz, Fahim, Herma Dina, Setiabudi, Nguyen Vo, Dai-Viet, Nguyen Thi, Anh Nga, Thong Lee, Minh Pham, Huong Thi, Danh, Bawadi, Abdullah
Format:	Article
Language:	English
Published:	IIUM, Malaysia 2018
Subjects:	T Technology (General) TA Engineering (General). Civil engineering (General) TD Environmental technology. Sanitary engineering
Online Access:	http://umpir.ump.edu.my/id/eprint/22075/ http://umpir.ump.edu.my/id/eprint/22075/ http://umpir.ump.edu.my/id/eprint/22075/1/Fahim%20Fayaz.pdf

id	ump-22075
recordtype	eprints
spelling	ump-220752019-10-03T07:56:07Z http://umpir.ump.edu.my/id/eprint/22075/ Hydrogen production form ethanol dry reforming over lanthania-promoted Co/Al2O3 catalyst Fayaz, Fahim Herma Dina, Setiabudi Nguyen Vo, Dai-Viet Nguyen Thi, Anh Nga Thong Lee, Minh Pham Huong Thi, Danh Bawadi, Abdullah T Technology (General) TA Engineering (General). Civil engineering (General) TD Environmental technology. Sanitary engineering La-promoted and unpromoted 10%Co/Al2O3 catalysts were synthesized using wet a impregnation method and evaluated in a quartz fixed-bed reactor at different CO2:C2H5OH ratios of 2.5:1-1:2.5 and a reaction temperature of 973 K under atmospheric pressure. X-ray diffraction measurements detected the presence of Co3O4 and CoAl2O4 phases on the surface of both promoted and unpromoted catalysts. BET surface area of promoted and unpromoted 10%Co/Al2O3 catalysts was about 143.09 and 136.04 m2.g-1, respectively. The La promoter facilitated Co3O4 reduction, improved the degree of reduction from 86 to 98% and increased metal dispersion from 9.11% to 16.64%. The La-promoted catalyst appeared to be a better catalyst in terms of catalytic activity and product yield regardless of reactant partial pressure. Both C2H5OH and CO2 conversions improved significantly with an increase in CO2 partial pressure from 20 to 50 kPa for both catalysts whilst a decline in catalytic performance was observed with rising C2H5OH partial pressure. La addition improved C2H5OH and CO2 conversions up to about 74.22% and 33.80%, respectively. IIUM, Malaysia 2018 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/22075/1/Fahim%20Fayaz.pdf Fayaz, Fahim and Herma Dina, Setiabudi and Nguyen Vo, Dai-Viet and Nguyen Thi, Anh Nga and Thong Lee, Minh Pham and Huong Thi, Danh and Bawadi, Abdullah (2018) Hydrogen production form ethanol dry reforming over lanthania-promoted Co/Al2O3 catalyst. IIUM Engineering Journal, 19 (1). pp. 24-33. ISSN 1511-788X https://doi.org/10.31436/iiumej.v19i1.813
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	T Technology (General) TA Engineering (General). Civil engineering (General) TD Environmental technology. Sanitary engineering
spellingShingle	T Technology (General) TA Engineering (General). Civil engineering (General) TD Environmental technology. Sanitary engineering Fayaz, Fahim Herma Dina, Setiabudi Nguyen Vo, Dai-Viet Nguyen Thi, Anh Nga Thong Lee, Minh Pham Huong Thi, Danh Bawadi, Abdullah Hydrogen production form ethanol dry reforming over lanthania-promoted Co/Al2O3 catalyst
description	La-promoted and unpromoted 10%Co/Al2O3 catalysts were synthesized using wet a impregnation method and evaluated in a quartz fixed-bed reactor at different CO2:C2H5OH ratios of 2.5:1-1:2.5 and a reaction temperature of 973 K under atmospheric pressure. X-ray diffraction measurements detected the presence of Co3O4 and CoAl2O4 phases on the surface of both promoted and unpromoted catalysts. BET surface area of promoted and unpromoted 10%Co/Al2O3 catalysts was about 143.09 and 136.04 m2.g-1, respectively. The La promoter facilitated Co3O4 reduction, improved the degree of reduction from 86 to 98% and increased metal dispersion from 9.11% to 16.64%. The La-promoted catalyst appeared to be a better catalyst in terms of catalytic activity and product yield regardless of reactant partial pressure. Both C2H5OH and CO2 conversions improved significantly with an increase in CO2 partial pressure from 20 to 50 kPa for both catalysts whilst a decline in catalytic performance was observed with rising C2H5OH partial pressure. La addition improved C2H5OH and CO2 conversions up to about 74.22% and 33.80%, respectively.
format	Article
author	Fayaz, Fahim Herma Dina, Setiabudi Nguyen Vo, Dai-Viet Nguyen Thi, Anh Nga Thong Lee, Minh Pham Huong Thi, Danh Bawadi, Abdullah
author_facet	Fayaz, Fahim Herma Dina, Setiabudi Nguyen Vo, Dai-Viet Nguyen Thi, Anh Nga Thong Lee, Minh Pham Huong Thi, Danh Bawadi, Abdullah
author_sort	Fayaz, Fahim
title	Hydrogen production form ethanol dry reforming over lanthania-promoted Co/Al2O3 catalyst
title_short	Hydrogen production form ethanol dry reforming over lanthania-promoted Co/Al2O3 catalyst
title_full	Hydrogen production form ethanol dry reforming over lanthania-promoted Co/Al2O3 catalyst
title_fullStr	Hydrogen production form ethanol dry reforming over lanthania-promoted Co/Al2O3 catalyst
title_full_unstemmed	Hydrogen production form ethanol dry reforming over lanthania-promoted Co/Al2O3 catalyst
title_sort	hydrogen production form ethanol dry reforming over lanthania-promoted co/al2o3 catalyst
publisher	IIUM, Malaysia
publishDate	2018
url	http://umpir.ump.edu.my/id/eprint/22075/ http://umpir.ump.edu.my/id/eprint/22075/ http://umpir.ump.edu.my/id/eprint/22075/1/Fahim%20Fayaz.pdf
first_indexed	2023-09-18T22:32:40Z
last_indexed	2023-09-18T22:32:40Z
_version_	1777416389980585984

Hydrogen production form ethanol dry reforming over lanthania-promoted Co/Al2O3 catalyst

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