Interplay between promoters and Ni-based mesoporous silica for methane dry reforming reaction

Commercially viable Ni-based heterogeneous catalysts have immense potential for the application in reforming reactions, but their rapid catalyst deactivation due to coking still remains a major challenge during these catalytic reforming applications. Herein, the endurance test of 72 h for methane dr...

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Main Authors:	Singh, Sharanjit, Long, Giang Bach, Bawadi, Abdullah, Truong, Quang Duc, Pham T., T. Phuong, Nguyen Hu, Huy Phuc, Vo, Dai-Viet N.
Format:	Conference or Workshop Item
Language:	English English
Published:	2018
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/22434/ http://umpir.ump.edu.my/id/eprint/22434/1/57.%20Interplay%20between%20promoters%20and%20Ni-based%20mesoporous.pdf http://umpir.ump.edu.my/id/eprint/22434/2/57.1%20Interplay%20between%20promoters%20and%20Ni-based%20mesoporous.pdf

id	ump-22434
recordtype	eprints
spelling	ump-224342019-10-03T07:44:54Z http://umpir.ump.edu.my/id/eprint/22434/ Interplay between promoters and Ni-based mesoporous silica for methane dry reforming reaction Singh, Sharanjit Long, Giang Bach Bawadi, Abdullah Truong, Quang Duc Pham T., T. Phuong Nguyen Hu, Huy Phuc Vo, Dai-Viet N. TP Chemical technology Commercially viable Ni-based heterogeneous catalysts have immense potential for the application in reforming reactions, but their rapid catalyst deactivation due to coking still remains a major challenge during these catalytic reforming applications. Herein, the endurance test of 72 h for methane dry reforming at low temperature and atmospheric conditions was conducted over a series of different promoted Ni-based catalysts. Intriguingly, bare SBA-15 supported Ni catalyst blocked the reactor after 51 time-on-stream due to excess carbon formation during the reaction. In addition, the catalyst promoted with yttrium showed the outstanding catalytic performance with CH4 and CO2 conversion of about 83.0% and 90.9%, respectively. On the other hand, boron promoted catalysts greatly improved the Ni and SBA-15 support interaction by facilitating the formation of NiSO3 and detected lowest coke formation and catalytic activity among counterparts. Moreover, different carbon species (herringbone fibers, amorphous and carbon shell) were identified in the spent catalysts. 2018 Conference or Workshop Item NonPeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/22434/1/57.%20Interplay%20between%20promoters%20and%20Ni-based%20mesoporous.pdf pdf en http://umpir.ump.edu.my/id/eprint/22434/2/57.1%20Interplay%20between%20promoters%20and%20Ni-based%20mesoporous.pdf Singh, Sharanjit and Long, Giang Bach and Bawadi, Abdullah and Truong, Quang Duc and Pham T., T. Phuong and Nguyen Hu, Huy Phuc and Vo, Dai-Viet N. (2018) Interplay between promoters and Ni-based mesoporous silica for methane dry reforming reaction. In: 4th International Conference of Chemical Engineering & Industrial Biotechnology, 1-2 August 2018 , Seri Pacific Hotel Kuala Lumpur. pp. 1-18.. (Unpublished)
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English English
topic	TP Chemical technology
spellingShingle	TP Chemical technology Singh, Sharanjit Long, Giang Bach Bawadi, Abdullah Truong, Quang Duc Pham T., T. Phuong Nguyen Hu, Huy Phuc Vo, Dai-Viet N. Interplay between promoters and Ni-based mesoporous silica for methane dry reforming reaction
description	Commercially viable Ni-based heterogeneous catalysts have immense potential for the application in reforming reactions, but their rapid catalyst deactivation due to coking still remains a major challenge during these catalytic reforming applications. Herein, the endurance test of 72 h for methane dry reforming at low temperature and atmospheric conditions was conducted over a series of different promoted Ni-based catalysts. Intriguingly, bare SBA-15 supported Ni catalyst blocked the reactor after 51 time-on-stream due to excess carbon formation during the reaction. In addition, the catalyst promoted with yttrium showed the outstanding catalytic performance with CH4 and CO2 conversion of about 83.0% and 90.9%, respectively. On the other hand, boron promoted catalysts greatly improved the Ni and SBA-15 support interaction by facilitating the formation of NiSO3 and detected lowest coke formation and catalytic activity among counterparts. Moreover, different carbon species (herringbone fibers, amorphous and carbon shell) were identified in the spent catalysts.
format	Conference or Workshop Item
author	Singh, Sharanjit Long, Giang Bach Bawadi, Abdullah Truong, Quang Duc Pham T., T. Phuong Nguyen Hu, Huy Phuc Vo, Dai-Viet N.
author_facet	Singh, Sharanjit Long, Giang Bach Bawadi, Abdullah Truong, Quang Duc Pham T., T. Phuong Nguyen Hu, Huy Phuc Vo, Dai-Viet N.
author_sort	Singh, Sharanjit
title	Interplay between promoters and Ni-based mesoporous silica for methane dry reforming reaction
title_short	Interplay between promoters and Ni-based mesoporous silica for methane dry reforming reaction
title_full	Interplay between promoters and Ni-based mesoporous silica for methane dry reforming reaction
title_fullStr	Interplay between promoters and Ni-based mesoporous silica for methane dry reforming reaction
title_full_unstemmed	Interplay between promoters and Ni-based mesoporous silica for methane dry reforming reaction
title_sort	interplay between promoters and ni-based mesoporous silica for methane dry reforming reaction
publishDate	2018
url	http://umpir.ump.edu.my/id/eprint/22434/ http://umpir.ump.edu.my/id/eprint/22434/1/57.%20Interplay%20between%20promoters%20and%20Ni-based%20mesoporous.pdf http://umpir.ump.edu.my/id/eprint/22434/2/57.1%20Interplay%20between%20promoters%20and%20Ni-based%20mesoporous.pdf
first_indexed	2023-09-18T22:33:23Z
last_indexed	2023-09-18T22:33:23Z
_version_	1777416435142754304

Interplay between promoters and Ni-based mesoporous silica for methane dry reforming reaction

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