Process optimization of methylene blue adsorption onto eggshell-treated palm oil fuel ash

Palm oil fuel ash (POFA) and eggshell (EG) were explored towards efficient methylene blue (MB) removal. Calcined EG, with a high content of CaO was used as a low-cost activation replacement for the alkali treatment of POFA. The adsorption performance of EG–POFA was studied by comparing its performan...

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Main Authors:	Rosalyza, Hasan, C. C., Chong, Setiabudi, H. D., Rohayu, Jusoh, A. A., Jalil
Format:	Article
Language:	English
Published:	Elsevier 2019
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/22919/ http://umpir.ump.edu.my/id/eprint/22919/ http://umpir.ump.edu.my/id/eprint/22919/ http://umpir.ump.edu.my/id/eprint/22919/1/Process%20optimization%20of%20methylene%20blue%20adsorption%20onto%20eggshell.pdf

id	ump-22919
recordtype	eprints
spelling	ump-229192018-11-26T08:01:36Z http://umpir.ump.edu.my/id/eprint/22919/ Process optimization of methylene blue adsorption onto eggshell-treated palm oil fuel ash Rosalyza, Hasan C. C., Chong Setiabudi, H. D. Rohayu, Jusoh A. A., Jalil TP Chemical technology Palm oil fuel ash (POFA) and eggshell (EG) were explored towards efficient methylene blue (MB) removal. Calcined EG, with a high content of CaO was used as a low-cost activation replacement for the alkali treatment of POFA. The adsorption performance of EG–POFA was studied by comparing its performance with untreated POFA, calcined EG and commercially treated Ca–POFA, and the competency was following the order of EG < POFA< EG–POFA ≈ Ca–POFA, indicating that EG effectively enhanced the efficiency of POFA. The response surface methodology (RSM) was executed to optimize the operating conditions of MB adsorption onto EG–POFA by investigating the effect of EG–POFA dosage (X1), initial pH (X2) and initial MB concentration (X3) towards MB removal (Y). X1 = 1.18 g/L, X2 = 6, and X3 = 182 mg/L, with Y = 80.36% were found to be optimal conditions. The experimental data disclosed that the MB adsorption onto EG–POFA was in accordance with the Langmuir isotherm model (qm = 714.29 mg/g) and followed pseudo-second-order kinetic model. The thermodynamic study discovered the endothermic and spontaneous natures of MB adsorption onto EG–POFA. This study discovered the feasibility of EG as an eco-friendly activation alternative for the alkali treatment towards remarkable MB adsorption. Elsevier 2019 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/22919/1/Process%20optimization%20of%20methylene%20blue%20adsorption%20onto%20eggshell.pdf Rosalyza, Hasan and C. C., Chong and Setiabudi, H. D. and Rohayu, Jusoh and A. A., Jalil (2019) Process optimization of methylene blue adsorption onto eggshell-treated palm oil fuel ash. Environmental Technology & Innovation, 13. pp. 62-73. ISSN 2352-1864 https://doi.org/10.1016/j.eti.2018.10.004 doi: 10.1016/j.eti.2018.10.004
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	TP Chemical technology
spellingShingle	TP Chemical technology Rosalyza, Hasan C. C., Chong Setiabudi, H. D. Rohayu, Jusoh A. A., Jalil Process optimization of methylene blue adsorption onto eggshell-treated palm oil fuel ash
description	Palm oil fuel ash (POFA) and eggshell (EG) were explored towards efficient methylene blue (MB) removal. Calcined EG, with a high content of CaO was used as a low-cost activation replacement for the alkali treatment of POFA. The adsorption performance of EG–POFA was studied by comparing its performance with untreated POFA, calcined EG and commercially treated Ca–POFA, and the competency was following the order of EG < POFA< EG–POFA ≈ Ca–POFA, indicating that EG effectively enhanced the efficiency of POFA. The response surface methodology (RSM) was executed to optimize the operating conditions of MB adsorption onto EG–POFA by investigating the effect of EG–POFA dosage (X1), initial pH (X2) and initial MB concentration (X3) towards MB removal (Y). X1 = 1.18 g/L, X2 = 6, and X3 = 182 mg/L, with Y = 80.36% were found to be optimal conditions. The experimental data disclosed that the MB adsorption onto EG–POFA was in accordance with the Langmuir isotherm model (qm = 714.29 mg/g) and followed pseudo-second-order kinetic model. The thermodynamic study discovered the endothermic and spontaneous natures of MB adsorption onto EG–POFA. This study discovered the feasibility of EG as an eco-friendly activation alternative for the alkali treatment towards remarkable MB adsorption.
format	Article
author	Rosalyza, Hasan C. C., Chong Setiabudi, H. D. Rohayu, Jusoh A. A., Jalil
author_facet	Rosalyza, Hasan C. C., Chong Setiabudi, H. D. Rohayu, Jusoh A. A., Jalil
author_sort	Rosalyza, Hasan
title	Process optimization of methylene blue adsorption onto eggshell-treated palm oil fuel ash
title_short	Process optimization of methylene blue adsorption onto eggshell-treated palm oil fuel ash
title_full	Process optimization of methylene blue adsorption onto eggshell-treated palm oil fuel ash
title_fullStr	Process optimization of methylene blue adsorption onto eggshell-treated palm oil fuel ash
title_full_unstemmed	Process optimization of methylene blue adsorption onto eggshell-treated palm oil fuel ash
title_sort	process optimization of methylene blue adsorption onto eggshell-treated palm oil fuel ash
publisher	Elsevier
publishDate	2019
url	http://umpir.ump.edu.my/id/eprint/22919/ http://umpir.ump.edu.my/id/eprint/22919/ http://umpir.ump.edu.my/id/eprint/22919/ http://umpir.ump.edu.my/id/eprint/22919/1/Process%20optimization%20of%20methylene%20blue%20adsorption%20onto%20eggshell.pdf
first_indexed	2023-09-18T22:34:06Z
last_indexed	2023-09-18T22:34:06Z
_version_	1777416479619153920

Process optimization of methylene blue adsorption onto eggshell-treated palm oil fuel ash

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