Producing a favorable ionic mobility based on cmc/ carrageenan derivative hybrid solid bio-polymer electrolytes system

The increasing interest in green energy storage materials for electrochemical devices with the development of bio-polymer materials as electrolytes candidate has attracted great attention recently. It can offer a number of high-value opportunities, provided that lower costs can be obtained besides e...

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Main Authors:	A. S., Samsudin, N. K., Zainuddin
Format:	Conference or Workshop Item
Language:	English
Published:	2018
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/22926/ http://umpir.ump.edu.my/id/eprint/22926/1/64.1%20Producing%20a%20favorable%20ionic%20mobility%20based%20on%20cmc.pdf

id	ump-22926
recordtype	eprints
spelling	ump-229262018-12-24T06:50:29Z http://umpir.ump.edu.my/id/eprint/22926/ Producing a favorable ionic mobility based on cmc/ carrageenan derivative hybrid solid bio-polymer electrolytes system A. S., Samsudin N. K., Zainuddin TP Chemical technology The increasing interest in green energy storage materials for electrochemical devices with the development of bio-polymer materials as electrolytes candidate has attracted great attention recently. It can offer a number of high-value opportunities, provided that lower costs can be obtained besides environmental friendly. In the present work, hybrid solid bio-polymer electrolytes (HSBEs) system were successfully prepared via solution casting approached comprises of CMC and blend with kappa carrageenan. The HSBEs system was characterized for structural and the conduction properties using FTIR, XRD and EIS technique. FTIR shown that the complexation has occurred between CMC and kappa carrageenan via -OH based on the coordination site and hydrogen ions for both polymers. The ionic conductivity is found to achieve the optimum value at ~10-7 S/cm for hybrid system with the ratio of CMC: KC is 80:20 and later was further increased to ~10-4 S/cm when NH4NO3 was added with 30 wt. %. The enhancement of ionic conductivity for HSBEs system was due to the increase in amorphous state between CMC/KC and addition of NH4NO3 as revealed by XRD analysis. From IR-deconvolution approach, it shows that the increasing of protonation (H+) from [N-H4+] [NO3-] towards coordinating site of hybrid CMC/KC system, lead to the increment in ionic mobility of ions and reflected the activation energy for transportation of ions. Based on the results, it shows that the CMC/KC HSBEs system is a promising candidate for proton conduction which has potential to be applied as an electrolytes system for application in electrochemical devices. 2018 Conference or Workshop Item NonPeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/22926/1/64.1%20Producing%20a%20favorable%20ionic%20mobility%20based%20on%20cmc.pdf A. S., Samsudin and N. K., Zainuddin (2018) Producing a favorable ionic mobility based on cmc/ carrageenan derivative hybrid solid bio-polymer electrolytes system. In: 4th IUPAC International Conference on Novel Materials and their Synthesis (NMS-XIV), 21 -26 October 2018 , Guangzhou, China. p. 1.. (Unpublished)
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	TP Chemical technology
spellingShingle	TP Chemical technology A. S., Samsudin N. K., Zainuddin Producing a favorable ionic mobility based on cmc/ carrageenan derivative hybrid solid bio-polymer electrolytes system
description	The increasing interest in green energy storage materials for electrochemical devices with the development of bio-polymer materials as electrolytes candidate has attracted great attention recently. It can offer a number of high-value opportunities, provided that lower costs can be obtained besides environmental friendly. In the present work, hybrid solid bio-polymer electrolytes (HSBEs) system were successfully prepared via solution casting approached comprises of CMC and blend with kappa carrageenan. The HSBEs system was characterized for structural and the conduction properties using FTIR, XRD and EIS technique. FTIR shown that the complexation has occurred between CMC and kappa carrageenan via -OH based on the coordination site and hydrogen ions for both polymers. The ionic conductivity is found to achieve the optimum value at ~10-7 S/cm for hybrid system with the ratio of CMC: KC is 80:20 and later was further increased to ~10-4 S/cm when NH4NO3 was added with 30 wt. %. The enhancement of ionic conductivity for HSBEs system was due to the increase in amorphous state between CMC/KC and addition of NH4NO3 as revealed by XRD analysis. From IR-deconvolution approach, it shows that the increasing of protonation (H+) from [N-H4+] [NO3-] towards coordinating site of hybrid CMC/KC system, lead to the increment in ionic mobility of ions and reflected the activation energy for transportation of ions. Based on the results, it shows that the CMC/KC HSBEs system is a promising candidate for proton conduction which has potential to be applied as an electrolytes system for application in electrochemical devices.
format	Conference or Workshop Item
author	A. S., Samsudin N. K., Zainuddin
author_facet	A. S., Samsudin N. K., Zainuddin
author_sort	A. S., Samsudin
title	Producing a favorable ionic mobility based on cmc/ carrageenan derivative hybrid solid bio-polymer electrolytes system
title_short	Producing a favorable ionic mobility based on cmc/ carrageenan derivative hybrid solid bio-polymer electrolytes system
title_full	Producing a favorable ionic mobility based on cmc/ carrageenan derivative hybrid solid bio-polymer electrolytes system
title_fullStr	Producing a favorable ionic mobility based on cmc/ carrageenan derivative hybrid solid bio-polymer electrolytes system
title_full_unstemmed	Producing a favorable ionic mobility based on cmc/ carrageenan derivative hybrid solid bio-polymer electrolytes system
title_sort	producing a favorable ionic mobility based on cmc/ carrageenan derivative hybrid solid bio-polymer electrolytes system
publishDate	2018
url	http://umpir.ump.edu.my/id/eprint/22926/ http://umpir.ump.edu.my/id/eprint/22926/1/64.1%20Producing%20a%20favorable%20ionic%20mobility%20based%20on%20cmc.pdf
first_indexed	2023-09-18T22:34:07Z
last_indexed	2023-09-18T22:34:07Z
_version_	1777416480654098432

Producing a favorable ionic mobility based on cmc/ carrageenan derivative hybrid solid bio-polymer electrolytes system

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