Tuned acidic properties of hmor@kcc-1 for enhanced n-hexane isomerization

Fibrous silica encapsulated mordenite zeolite (HMOR@KCC-1) was prepared by using microemulsion system coupled with zeolite crystal-seed crystallization technique. While the activity of the catalysts were tested for n-hexane isomerization in a microcatalytic pulse reactor. XRD analysis shows reductio...

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Main Authors:	M., Ibrahim, A. A., Jalil, S., Triwahyono, M. Y., S. Hamid, Y., Gambo, A. A., Abdulrasheed, Herma Dina, Setiabudi
Format:	Conference or Workshop Item
Language:	English
Published:	2018
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/23891/ http://umpir.ump.edu.my/id/eprint/23891/1/33.%20Tuned%20acidic%20properties%20of%20hmor%40kcc-1%20for%20enhanced.pdf

id	ump-23891
recordtype	eprints
spelling	ump-238912019-01-22T06:56:56Z http://umpir.ump.edu.my/id/eprint/23891/ Tuned acidic properties of hmor@kcc-1 for enhanced n-hexane isomerization M., Ibrahim A. A., Jalil S., Triwahyono M. Y., S. Hamid Y., Gambo A. A., Abdulrasheed Herma Dina, Setiabudi TP Chemical technology Fibrous silica encapsulated mordenite zeolite (HMOR@KCC-1) was prepared by using microemulsion system coupled with zeolite crystal-seed crystallization technique. While the activity of the catalysts were tested for n-hexane isomerization in a microcatalytic pulse reactor. XRD analysis shows reduction of modernite crystallinity phase due to silica encapsulation. IR studies of pyridine adsorption gave the concentration of both Brönsted acid sites (BAS) and Lewis acid sites (LAS). 2,6- Lutidine as probe molecule showed that Pt/HMOR contains strong Brönsted acid sites while Pt/HMOR@KCC-1 contains medium strength Brönsted acid sites. The relatively mild acid sites and improved acid sites accessibility introduced by the fibrous silica morphology enhanced the catalytic yield of Pt/HMOR@KCC-1 by 22% compared to Pt/HMOR in isomerization of n-hexane. 2018-08 Conference or Workshop Item PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/23891/1/33.%20Tuned%20acidic%20properties%20of%20hmor%40kcc-1%20for%20enhanced.pdf M., Ibrahim and A. A., Jalil and S., Triwahyono and M. Y., S. Hamid and Y., Gambo and A. A., Abdulrasheed and Herma Dina, Setiabudi (2018) Tuned acidic properties of hmor@kcc-1 for enhanced n-hexane isomerization. In: 4th International Conference Of Chemical Engineering And Industrial Biotechnology (ICCEIB 2018), 1-2 Aug 2018 , Seri Pacific Hotel, Kuala Lumpur. pp. 302-304..
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	TP Chemical technology
spellingShingle	TP Chemical technology M., Ibrahim A. A., Jalil S., Triwahyono M. Y., S. Hamid Y., Gambo A. A., Abdulrasheed Herma Dina, Setiabudi Tuned acidic properties of hmor@kcc-1 for enhanced n-hexane isomerization
description	Fibrous silica encapsulated mordenite zeolite (HMOR@KCC-1) was prepared by using microemulsion system coupled with zeolite crystal-seed crystallization technique. While the activity of the catalysts were tested for n-hexane isomerization in a microcatalytic pulse reactor. XRD analysis shows reduction of modernite crystallinity phase due to silica encapsulation. IR studies of pyridine adsorption gave the concentration of both Brönsted acid sites (BAS) and Lewis acid sites (LAS). 2,6- Lutidine as probe molecule showed that Pt/HMOR contains strong Brönsted acid sites while Pt/HMOR@KCC-1 contains medium strength Brönsted acid sites. The relatively mild acid sites and improved acid sites accessibility introduced by the fibrous silica morphology enhanced the catalytic yield of Pt/HMOR@KCC-1 by 22% compared to Pt/HMOR in isomerization of n-hexane.
format	Conference or Workshop Item
author	M., Ibrahim A. A., Jalil S., Triwahyono M. Y., S. Hamid Y., Gambo A. A., Abdulrasheed Herma Dina, Setiabudi
author_facet	M., Ibrahim A. A., Jalil S., Triwahyono M. Y., S. Hamid Y., Gambo A. A., Abdulrasheed Herma Dina, Setiabudi
author_sort	M., Ibrahim
title	Tuned acidic properties of hmor@kcc-1 for enhanced n-hexane isomerization
title_short	Tuned acidic properties of hmor@kcc-1 for enhanced n-hexane isomerization
title_full	Tuned acidic properties of hmor@kcc-1 for enhanced n-hexane isomerization
title_fullStr	Tuned acidic properties of hmor@kcc-1 for enhanced n-hexane isomerization
title_full_unstemmed	Tuned acidic properties of hmor@kcc-1 for enhanced n-hexane isomerization
title_sort	tuned acidic properties of hmor@kcc-1 for enhanced n-hexane isomerization
publishDate	2018
url	http://umpir.ump.edu.my/id/eprint/23891/ http://umpir.ump.edu.my/id/eprint/23891/1/33.%20Tuned%20acidic%20properties%20of%20hmor%40kcc-1%20for%20enhanced.pdf
first_indexed	2023-09-18T22:35:59Z
last_indexed	2023-09-18T22:35:59Z
_version_	1777416598683910144

Tuned acidic properties of hmor@kcc-1 for enhanced n-hexane isomerization

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