Direct growth of triple cation metal-organic framework on a metal substrate for electrochemical energy storage

Metal−organic frameworks (MOFs) offer a robust structure with high surface area together with open metal center sites which easily undergo the reversible redox reaction without damaging the framework; therefore, they are actively considered as a medium for electrochemical energy storage. This articl...

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Main Authors:	Nurul Khairiyyah, Mohd Zain, Vijayan, Bincy Lathakumary, Izan Izwan, Misnon, Das, Santanu, Karuppiah, Chelladurai, Yang, Chun-Chen, M. M., Yusoff, Rajan, Jose
Format:	Article
Language:	English
Published:	American Chemical Society (ACS Publications) 2019
Subjects:	QC Physics QD Chemistry
Online Access:	http://umpir.ump.edu.my/id/eprint/24222/ http://umpir.ump.edu.my/id/eprint/24222/ http://umpir.ump.edu.my/id/eprint/24222/ http://umpir.ump.edu.my/id/eprint/24222/7/Direct%20Growth%20of%20Triple%20Cation%20Metal%20Organic%20Framework%20on%20a.pdf

id	ump-24222
recordtype	eprints
spelling	ump-242222019-03-15T04:30:35Z http://umpir.ump.edu.my/id/eprint/24222/ Direct growth of triple cation metal-organic framework on a metal substrate for electrochemical energy storage Nurul Khairiyyah, Mohd Zain Vijayan, Bincy Lathakumary Izan Izwan, Misnon Das, Santanu Karuppiah, Chelladurai Yang, Chun-Chen M. M., Yusoff Rajan, Jose QC Physics QD Chemistry Metal−organic frameworks (MOFs) offer a robust structure with high surface area together with open metal center sites which easily undergo the reversible redox reaction without damaging the framework; therefore, they are actively considered as a medium for electrochemical energy storage. This article demonstrates the superiority of triple cation metal-terephthalate as charge storage electrodes over their single component counterparts. We report the preparation of ternary metalterephthalate (CoCuNi-bdc/NF) containing equimolar precursors of Co, Cu, and Ni as metal centers and terephthalic acid (H2 bdc) as the organic linker and its single metal counterparts (Cobdc/NF, Cu-bdc/NF, and Ni-bdc/NF) on Ni-foam substrate via a one-step facile hydrothermal reaction. The structure and morphologies of the CoCuNi-bdc/NF composite and its single component counterparts are characterized by powder X-ray diffraction, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and field-emission scanning electron microscopy techniques. The charge storage capabilities of the electrodes are evaluated by cyclic voltammetry, charge−discharge cycling, and electrochemical impedance spectroscopy in an aqueous alkaline electrolyte (6 M KOH) in a three-electrode system (half-cell) configuration. The specific capacity of CoCuNibdc/NF was ∼321.3 mA h g−1 (∼2892 F g−1), which is over 50% larger than the best performing single metal-terephthalate, Cobdc/NF (∼208.2 mA h g−1; 1874 F g−1), followed by Cu-bdc/NF (∼171.3 mA h g−1; ∼1542 F g−1), and last Ni-bdc/NF with∼143.3 mA h g−1 (∼1290 F g−1). The specific capacity of CoCuNi-bdc/NF ranges from ∼191.9−321.3 mA h g−1 (∼1727−2892 F g−1) as current density varied from 40 to 1 A g−1 with ∼77% retention at 10 A g−1 and ∼59% at 40 A g−1. CoCuNi-bdc/ NF displays better electrochemical performance compared to its single component MOFs; hence, CoCuNi-bdc/NF could be the promising electrode material for supercapacitor materials. In the long term, this research would be expandable to a wide range of functional transition-organometallic materials for an energy storage paradigm. American Chemical Society (ACS Publications) 2019-01-01 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/24222/7/Direct%20Growth%20of%20Triple%20Cation%20Metal%20Organic%20Framework%20on%20a.pdf Nurul Khairiyyah, Mohd Zain and Vijayan, Bincy Lathakumary and Izan Izwan, Misnon and Das, Santanu and Karuppiah, Chelladurai and Yang, Chun-Chen and M. M., Yusoff and Rajan, Jose (2019) Direct growth of triple cation metal-organic framework on a metal substrate for electrochemical energy storage. Industrial and Engineering Chemistry Research, 58 (2). pp. 665-674. ISSN 0888-5885 https://pubs.acs.org/doi/10.1021/acs.iecr.8b03898 https://doi.org/10.1021/acs.iecr.8b03898
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	QC Physics QD Chemistry
spellingShingle	QC Physics QD Chemistry Nurul Khairiyyah, Mohd Zain Vijayan, Bincy Lathakumary Izan Izwan, Misnon Das, Santanu Karuppiah, Chelladurai Yang, Chun-Chen M. M., Yusoff Rajan, Jose Direct growth of triple cation metal-organic framework on a metal substrate for electrochemical energy storage
description	Metal−organic frameworks (MOFs) offer a robust structure with high surface area together with open metal center sites which easily undergo the reversible redox reaction without damaging the framework; therefore, they are actively considered as a medium for electrochemical energy storage. This article demonstrates the superiority of triple cation metal-terephthalate as charge storage electrodes over their single component counterparts. We report the preparation of ternary metalterephthalate (CoCuNi-bdc/NF) containing equimolar precursors of Co, Cu, and Ni as metal centers and terephthalic acid (H2 bdc) as the organic linker and its single metal counterparts (Cobdc/NF, Cu-bdc/NF, and Ni-bdc/NF) on Ni-foam substrate via a one-step facile hydrothermal reaction. The structure and morphologies of the CoCuNi-bdc/NF composite and its single component counterparts are characterized by powder X-ray diffraction, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and field-emission scanning electron microscopy techniques. The charge storage capabilities of the electrodes are evaluated by cyclic voltammetry, charge−discharge cycling, and electrochemical impedance spectroscopy in an aqueous alkaline electrolyte (6 M KOH) in a three-electrode system (half-cell) configuration. The specific capacity of CoCuNibdc/NF was ∼321.3 mA h g−1 (∼2892 F g−1), which is over 50% larger than the best performing single metal-terephthalate, Cobdc/NF (∼208.2 mA h g−1; 1874 F g−1), followed by Cu-bdc/NF (∼171.3 mA h g−1; ∼1542 F g−1), and last Ni-bdc/NF with∼143.3 mA h g−1 (∼1290 F g−1). The specific capacity of CoCuNi-bdc/NF ranges from ∼191.9−321.3 mA h g−1 (∼1727−2892 F g−1) as current density varied from 40 to 1 A g−1 with ∼77% retention at 10 A g−1 and ∼59% at 40 A g−1. CoCuNi-bdc/ NF displays better electrochemical performance compared to its single component MOFs; hence, CoCuNi-bdc/NF could be the promising electrode material for supercapacitor materials. In the long term, this research would be expandable to a wide range of functional transition-organometallic materials for an energy storage paradigm.
format	Article
author	Nurul Khairiyyah, Mohd Zain Vijayan, Bincy Lathakumary Izan Izwan, Misnon Das, Santanu Karuppiah, Chelladurai Yang, Chun-Chen M. M., Yusoff Rajan, Jose
author_facet	Nurul Khairiyyah, Mohd Zain Vijayan, Bincy Lathakumary Izan Izwan, Misnon Das, Santanu Karuppiah, Chelladurai Yang, Chun-Chen M. M., Yusoff Rajan, Jose
author_sort	Nurul Khairiyyah, Mohd Zain
title	Direct growth of triple cation metal-organic framework on a metal substrate for electrochemical energy storage
title_short	Direct growth of triple cation metal-organic framework on a metal substrate for electrochemical energy storage
title_full	Direct growth of triple cation metal-organic framework on a metal substrate for electrochemical energy storage
title_fullStr	Direct growth of triple cation metal-organic framework on a metal substrate for electrochemical energy storage
title_full_unstemmed	Direct growth of triple cation metal-organic framework on a metal substrate for electrochemical energy storage
title_sort	direct growth of triple cation metal-organic framework on a metal substrate for electrochemical energy storage
publisher	American Chemical Society (ACS Publications)
publishDate	2019
url	http://umpir.ump.edu.my/id/eprint/24222/ http://umpir.ump.edu.my/id/eprint/24222/ http://umpir.ump.edu.my/id/eprint/24222/ http://umpir.ump.edu.my/id/eprint/24222/7/Direct%20Growth%20of%20Triple%20Cation%20Metal%20Organic%20Framework%20on%20a.pdf
first_indexed	2023-09-18T22:36:32Z
last_indexed	2023-09-18T22:36:32Z
_version_	1777416632748998656

Direct growth of triple cation metal-organic framework on a metal substrate for electrochemical energy storage

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