CO2-Philic [EMIM][Tf2N] modified silica in mixed matrix membrane for high performance CO2/CH4 separation

Separation of carbon dioxide (CO 2 ) from methane (CH 4 ) using polymeric membranes is limited by trade-off between permeability and selectivity as depicted in Robeson curve. To overcome this challenge, this study develops membranes by incorporating silica particles (Si) modified with [EMIM][Tf 2 N]...

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Main Authors:	Siti Nur Alwani, Shafie, Wen, Xuan Liew, Nik Abdul Hadi, Md Nordin, Bilad, Muhammad Roil, Norazlianie, Sazali, Zulfan, Adi Putra, Mohd Dzul Hakim, Wirzal
Format:	Article
Language:	English
Published:	Wiley 2019
Subjects:	QD Chemistry
Online Access:	http://umpir.ump.edu.my/id/eprint/25529/ http://umpir.ump.edu.my/id/eprint/25529/ http://umpir.ump.edu.my/id/eprint/25529/ http://umpir.ump.edu.my/id/eprint/25529/1/CO_2_-Philic_EMIMTf_2_N_Modified_Silica_in_Mixed_M.pdf

id	ump-25529
recordtype	eprints
spelling	ump-255292019-08-07T06:12:19Z http://umpir.ump.edu.my/id/eprint/25529/ CO2-Philic [EMIM][Tf2N] modified silica in mixed matrix membrane for high performance CO2/CH4 separation Siti Nur Alwani, Shafie Wen, Xuan Liew Nik Abdul Hadi, Md Nordin Bilad, Muhammad Roil Norazlianie, Sazali Zulfan, Adi Putra Mohd Dzul Hakim, Wirzal QD Chemistry Separation of carbon dioxide (CO 2 ) from methane (CH 4 ) using polymeric membranes is limited by trade-off between permeability and selectivity as depicted in Robeson curve. To overcome this challenge, this study develops membranes by incorporating silica particles (Si) modified with [EMIM][Tf 2 N] ionic liquid (IL) at different IL:Si ratio to achieve desirable membrane properties and gas separation performance. Results show that the IL:Si particle has been successfully prepared, indicated by the presence of fluorine and nitrogen elements, as observed via Fourier-Transform Infrared Spectroscopy (FTIR) and X-ray Photoelectron Spectrometer (XPS). Incorporation of the modified particles into membrane has given prominent effects on morphology and polymer chain flexibility. The mixed matrix membrane (MMM) cross-section morphology turns rougher in the presence of IL:Si during fracture due to higher loadings of silica particles and IL. Furthermore, the MMM becomes more flexible with IL presence due to IL-induced plasticization, independent of IL:Si ratio. The MMM with low IL content possesses CO 2 permeance of 34.60 ± 0.26 GPU with CO 2 /CH 4 selectivity of 85.10, which is far superior to a pure polycarbonate (PC) and PC-Sil membranes at 2 bar, which surpasses the Robeson Upper Bound. This higher CO 2 selectivity is due to the presences of CO 2 -philic IL within the MMM system. Wiley 2019 Article PeerReviewed pdf en cc_by_4 http://umpir.ump.edu.my/id/eprint/25529/1/CO_2_-Philic_EMIMTf_2_N_Modified_Silica_in_Mixed_M.pdf Siti Nur Alwani, Shafie and Wen, Xuan Liew and Nik Abdul Hadi, Md Nordin and Bilad, Muhammad Roil and Norazlianie, Sazali and Zulfan, Adi Putra and Mohd Dzul Hakim, Wirzal (2019) CO2-Philic [EMIM][Tf2N] modified silica in mixed matrix membrane for high performance CO2/CH4 separation. Advances in Polymer Technology, 2019 (2924961). pp. 1-10. ISSN 1098-2329 https://doi.org/10.1155/2019/2924961 https://doi.org/10.1155/2019/2924961
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	QD Chemistry
spellingShingle	QD Chemistry Siti Nur Alwani, Shafie Wen, Xuan Liew Nik Abdul Hadi, Md Nordin Bilad, Muhammad Roil Norazlianie, Sazali Zulfan, Adi Putra Mohd Dzul Hakim, Wirzal CO2-Philic [EMIM][Tf2N] modified silica in mixed matrix membrane for high performance CO2/CH4 separation
description	Separation of carbon dioxide (CO 2 ) from methane (CH 4 ) using polymeric membranes is limited by trade-off between permeability and selectivity as depicted in Robeson curve. To overcome this challenge, this study develops membranes by incorporating silica particles (Si) modified with [EMIM][Tf 2 N] ionic liquid (IL) at different IL:Si ratio to achieve desirable membrane properties and gas separation performance. Results show that the IL:Si particle has been successfully prepared, indicated by the presence of fluorine and nitrogen elements, as observed via Fourier-Transform Infrared Spectroscopy (FTIR) and X-ray Photoelectron Spectrometer (XPS). Incorporation of the modified particles into membrane has given prominent effects on morphology and polymer chain flexibility. The mixed matrix membrane (MMM) cross-section morphology turns rougher in the presence of IL:Si during fracture due to higher loadings of silica particles and IL. Furthermore, the MMM becomes more flexible with IL presence due to IL-induced plasticization, independent of IL:Si ratio. The MMM with low IL content possesses CO 2 permeance of 34.60 ± 0.26 GPU with CO 2 /CH 4 selectivity of 85.10, which is far superior to a pure polycarbonate (PC) and PC-Sil membranes at 2 bar, which surpasses the Robeson Upper Bound. This higher CO 2 selectivity is due to the presences of CO 2 -philic IL within the MMM system.
format	Article
author	Siti Nur Alwani, Shafie Wen, Xuan Liew Nik Abdul Hadi, Md Nordin Bilad, Muhammad Roil Norazlianie, Sazali Zulfan, Adi Putra Mohd Dzul Hakim, Wirzal
author_facet	Siti Nur Alwani, Shafie Wen, Xuan Liew Nik Abdul Hadi, Md Nordin Bilad, Muhammad Roil Norazlianie, Sazali Zulfan, Adi Putra Mohd Dzul Hakim, Wirzal
author_sort	Siti Nur Alwani, Shafie
title	CO2-Philic [EMIM][Tf2N] modified silica in mixed matrix membrane for high performance CO2/CH4 separation
title_short	CO2-Philic [EMIM][Tf2N] modified silica in mixed matrix membrane for high performance CO2/CH4 separation
title_full	CO2-Philic [EMIM][Tf2N] modified silica in mixed matrix membrane for high performance CO2/CH4 separation
title_fullStr	CO2-Philic [EMIM][Tf2N] modified silica in mixed matrix membrane for high performance CO2/CH4 separation
title_full_unstemmed	CO2-Philic [EMIM][Tf2N] modified silica in mixed matrix membrane for high performance CO2/CH4 separation
title_sort	co2-philic [emim][tf2n] modified silica in mixed matrix membrane for high performance co2/ch4 separation
publisher	Wiley
publishDate	2019
url	http://umpir.ump.edu.my/id/eprint/25529/ http://umpir.ump.edu.my/id/eprint/25529/ http://umpir.ump.edu.my/id/eprint/25529/ http://umpir.ump.edu.my/id/eprint/25529/1/CO_2_-Philic_EMIMTf_2_N_Modified_Silica_in_Mixed_M.pdf
first_indexed	2023-09-18T22:39:15Z
last_indexed	2023-09-18T22:39:15Z
_version_	1777416803716169728

CO2-Philic [EMIM][Tf2N] modified silica in mixed matrix membrane for high performance CO2/CH4 separation

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