Carrier selection in liquid membrane for extraction of levulinic acid using hybrid graphene-polyethersulfone supported liquid membrane

Carrier selection in liquid membrane for extraction of levulinic acid using hybrid graphene-polyethersulfone supported liquid membrane

Levulinic acid (LA) and its valuable derivatives are growing demand in various applications such as in pharmaceuticals, food additives, agriculture, cosmetics, plasticizers and other industries. LA can be prepared through degradation of hexose from lignocellulosic biomass by using acids. However, th...

Full description

Bibliographic Details
Main Authors: Vickneswary, Rajendaran, Syed Mohd Saufi, Tuan Chik, Mior Ahmad Khushairi, Mohd Zahari, Abdul Wahab, Mohamad
Format: Conference or Workshop Item
Language:English
Published: Elsevier Ltd 2019
Subjects:
TP Chemical technology
Online Access:http://umpir.ump.edu.my/id/eprint/25825/
http://umpir.ump.edu.my/id/eprint/25825/
http://umpir.ump.edu.my/id/eprint/25825/1/Paper%2023%20%28Carrier%20Selection%20in%20Liquid%20Membrane%20for%20Extraction%20of%20Levulinic%20Acid%20using%20Hybrid%20Graphene-Polyethersulfone%20Supported%20Liquid%20Membrane%20_%20Elsevier%20Enhanced%20Reader%29.pdf
id ump-25825
recordtype eprints
spelling ump-258252019-11-22T08:30:34Z http://umpir.ump.edu.my/id/eprint/25825/ Carrier selection in liquid membrane for extraction of levulinic acid using hybrid graphene-polyethersulfone supported liquid membrane Vickneswary, Rajendaran Syed Mohd Saufi, Tuan Chik Mior Ahmad Khushairi, Mohd Zahari Abdul Wahab, Mohamad TP Chemical technology Levulinic acid (LA) and its valuable derivatives are growing demand in various applications such as in pharmaceuticals, food additives, agriculture, cosmetics, plasticizers and other industries. LA can be prepared through degradation of hexose from lignocellulosic biomass by using acids. However, the cost for LA recovery was higher than the production cost and some separation technique raise some environmental problem. Thus, it is essential to develop an economical separation process which can resulted in high yield of LA recovery with low cost and had less impacted to the environment. In this study, five different type of carriers were investigated during organic liquid membrane formulation which are tri-n-octyl phosphine oxide (TOPO), Aliquat 336, trioctylamine (TOA), tridodecylamin (TDA) and mixture of 50% TOA and 50% TDA. Hybrid graphene- polyethersulfone flat sheet membrane was prepared through vapour-induced phase separation and used as membrane support in the SLM process. The extraction was conducted using 10 g/L aqueous LA solution for 8 hours in the SLM system. The best carrier for extraction of LA was achieved using TOA which showed 74% of LA recovery. The LA extraction using TOPO, TDA, Aliquat 336, and mixture of TOA/TDA were 22%, 47%, 62%, and 67%, respectively. The selection of the carrier in liquid membrane formulation is important for achieving high recovery of LA using SLM process. Elsevier Ltd 2019-08-08 Conference or Workshop Item PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/25825/1/Paper%2023%20%28Carrier%20Selection%20in%20Liquid%20Membrane%20for%20Extraction%20of%20Levulinic%20Acid%20using%20Hybrid%20Graphene-Polyethersulfone%20Supported%20Liquid%20Membrane%20_%20Elsevier%20Enhanced%20Reader%29.pdf Vickneswary, Rajendaran and Syed Mohd Saufi, Tuan Chik and Mior Ahmad Khushairi, Mohd Zahari and Abdul Wahab, Mohamad (2019) Carrier selection in liquid membrane for extraction of levulinic acid using hybrid graphene-polyethersulfone supported liquid membrane. In: 6th International Conference on Recent Advances in Materials, Minerals and Environment, 27-29 November 2018 , Penang, Malaysia. pp. 1117-1125., 17. ISSN 22147853 https://doi.org/10.1016/j.matpr.2019.06.535
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
language English
topic TP Chemical technology
spellingShingle TP Chemical technology
Vickneswary, Rajendaran
Syed Mohd Saufi, Tuan Chik
Mior Ahmad Khushairi, Mohd Zahari
Abdul Wahab, Mohamad
Carrier selection in liquid membrane for extraction of levulinic acid using hybrid graphene-polyethersulfone supported liquid membrane
description Levulinic acid (LA) and its valuable derivatives are growing demand in various applications such as in pharmaceuticals, food additives, agriculture, cosmetics, plasticizers and other industries. LA can be prepared through degradation of hexose from lignocellulosic biomass by using acids. However, the cost for LA recovery was higher than the production cost and some separation technique raise some environmental problem. Thus, it is essential to develop an economical separation process which can resulted in high yield of LA recovery with low cost and had less impacted to the environment. In this study, five different type of carriers were investigated during organic liquid membrane formulation which are tri-n-octyl phosphine oxide (TOPO), Aliquat 336, trioctylamine (TOA), tridodecylamin (TDA) and mixture of 50% TOA and 50% TDA. Hybrid graphene- polyethersulfone flat sheet membrane was prepared through vapour-induced phase separation and used as membrane support in the SLM process. The extraction was conducted using 10 g/L aqueous LA solution for 8 hours in the SLM system. The best carrier for extraction of LA was achieved using TOA which showed 74% of LA recovery. The LA extraction using TOPO, TDA, Aliquat 336, and mixture of TOA/TDA were 22%, 47%, 62%, and 67%, respectively. The selection of the carrier in liquid membrane formulation is important for achieving high recovery of LA using SLM process.
format Conference or Workshop Item
author Vickneswary, Rajendaran
Syed Mohd Saufi, Tuan Chik
Mior Ahmad Khushairi, Mohd Zahari
Abdul Wahab, Mohamad
author_facet Vickneswary, Rajendaran
Syed Mohd Saufi, Tuan Chik
Mior Ahmad Khushairi, Mohd Zahari
Abdul Wahab, Mohamad
author_sort Vickneswary, Rajendaran
title Carrier selection in liquid membrane for extraction of levulinic acid using hybrid graphene-polyethersulfone supported liquid membrane
title_short Carrier selection in liquid membrane for extraction of levulinic acid using hybrid graphene-polyethersulfone supported liquid membrane
title_full Carrier selection in liquid membrane for extraction of levulinic acid using hybrid graphene-polyethersulfone supported liquid membrane
title_fullStr Carrier selection in liquid membrane for extraction of levulinic acid using hybrid graphene-polyethersulfone supported liquid membrane
title_full_unstemmed Carrier selection in liquid membrane for extraction of levulinic acid using hybrid graphene-polyethersulfone supported liquid membrane
title_sort carrier selection in liquid membrane for extraction of levulinic acid using hybrid graphene-polyethersulfone supported liquid membrane
publisher Elsevier Ltd
publishDate 2019
url http://umpir.ump.edu.my/id/eprint/25825/
http://umpir.ump.edu.my/id/eprint/25825/
http://umpir.ump.edu.my/id/eprint/25825/1/Paper%2023%20%28Carrier%20Selection%20in%20Liquid%20Membrane%20for%20Extraction%20of%20Levulinic%20Acid%20using%20Hybrid%20Graphene-Polyethersulfone%20Supported%20Liquid%20Membrane%20_%20Elsevier%20Enhanced%20Reader%29.pdf
first_indexed 2023-09-18T22:39:52Z
last_indexed 2023-09-18T22:39:52Z
_version_ 1777416843023089664

Similar Items