Blending poly (3-hydroxybutyrate) with polyethylene glycol (PEG): Thermal behaviour and rheological study

Blending poly (3-hydroxybutyrate) with polyethylene glycol (PEG): Thermal behaviour and rheological study

Poly (3-hydroxybutyrate) (PHB) is a biodégradable polymer which its application in industrial was limited due to sensitive to high processing temperature and poor mechanical properties. The thermal and rheological behavior for blends of PHB extracted from dry weight of Jatropha and Poly (ethylene gl...

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Main Authors: Norfarisha, Achim, Hazlina, Husin, Zulkafli, Hassan
Format: Article
Language:English
Published: Faculty Mechanical Engineering, UMP 2019
Subjects:
QD Chemistry
TP Chemical technology
Online Access:http://umpir.ump.edu.my/id/eprint/26048/
http://umpir.ump.edu.my/id/eprint/26048/
http://umpir.ump.edu.my/id/eprint/26048/
http://umpir.ump.edu.my/id/eprint/26048/1/Blending%20poly%20%283-hydroxybutyrate%29%20with%20polyethylene%20glycol%20%28PEG%29.pdf
id ump-26048
recordtype eprints
spelling ump-260482019-11-21T03:36:01Z http://umpir.ump.edu.my/id/eprint/26048/ Blending poly (3-hydroxybutyrate) with polyethylene glycol (PEG): Thermal behaviour and rheological study Norfarisha, Achim Hazlina, Husin Zulkafli, Hassan QD Chemistry TP Chemical technology Poly (3-hydroxybutyrate) (PHB) is a biodégradable polymer which its application in industrial was limited due to sensitive to high processing temperature and poor mechanical properties. The thermal and rheological behavior for blends of PHB extracted from dry weight of Jatropha and Poly (ethylene glycol) (PEG) were investigated. Blends of PHB/PEG (PHB 100, PHB 80, PHB 60 and PHB 50) have been prepared through solution blending method. The thermal using Differential Scanning Calorimetry (DSC) and Thermogravimetric Analysis (TGA) and rheological behavior using Oscillating Disk Rheometer have been investigated. The results indicate all PHb/PEG blends showed decreased at lowest melting temperature crystallinity (Xc). The TGA result showed that PHB 80 less degraded and suggest better thermal stability compared to PHB 60 and PHB 50. Adding PEG to PHB also improved the rheological behavior of PHB. At higher frequency range, PHB 100 showed less dependency on frequency indicating the elastic structure it has compared to PHB 80, PHB 60 and PHB 50. Faculty Mechanical Engineering, UMP 2019-09-27 Article PeerReviewed pdf en cc_by_nc_4 http://umpir.ump.edu.my/id/eprint/26048/1/Blending%20poly%20%283-hydroxybutyrate%29%20with%20polyethylene%20glycol%20%28PEG%29.pdf Norfarisha, Achim and Hazlina, Husin and Zulkafli, Hassan (2019) Blending poly (3-hydroxybutyrate) with polyethylene glycol (PEG): Thermal behaviour and rheological study. Journal of Mechanical Engineering and Sciences (JMES), 13 (3). 5294 -5305. ISSN 2289-4659 (print); 2231-8380 (online) http://journal.ump.edu.my/jmes/article/view/3000 https://doi.org/10.15282/jmes.13.3.2019.06.0432
repository_type Digital Repository
institution_category Local University
institution Universiti Malaysia Pahang
building UMP Institutional Repository
collection Online Access
language English
topic QD Chemistry
TP Chemical technology
spellingShingle QD Chemistry
TP Chemical technology
Norfarisha, Achim
Hazlina, Husin
Zulkafli, Hassan
Blending poly (3-hydroxybutyrate) with polyethylene glycol (PEG): Thermal behaviour and rheological study
description Poly (3-hydroxybutyrate) (PHB) is a biodégradable polymer which its application in industrial was limited due to sensitive to high processing temperature and poor mechanical properties. The thermal and rheological behavior for blends of PHB extracted from dry weight of Jatropha and Poly (ethylene glycol) (PEG) were investigated. Blends of PHB/PEG (PHB 100, PHB 80, PHB 60 and PHB 50) have been prepared through solution blending method. The thermal using Differential Scanning Calorimetry (DSC) and Thermogravimetric Analysis (TGA) and rheological behavior using Oscillating Disk Rheometer have been investigated. The results indicate all PHb/PEG blends showed decreased at lowest melting temperature crystallinity (Xc). The TGA result showed that PHB 80 less degraded and suggest better thermal stability compared to PHB 60 and PHB 50. Adding PEG to PHB also improved the rheological behavior of PHB. At higher frequency range, PHB 100 showed less dependency on frequency indicating the elastic structure it has compared to PHB 80, PHB 60 and PHB 50.
format Article
author Norfarisha, Achim
Hazlina, Husin
Zulkafli, Hassan
author_facet Norfarisha, Achim
Hazlina, Husin
Zulkafli, Hassan
author_sort Norfarisha, Achim
title Blending poly (3-hydroxybutyrate) with polyethylene glycol (PEG): Thermal behaviour and rheological study
title_short Blending poly (3-hydroxybutyrate) with polyethylene glycol (PEG): Thermal behaviour and rheological study
title_full Blending poly (3-hydroxybutyrate) with polyethylene glycol (PEG): Thermal behaviour and rheological study
title_fullStr Blending poly (3-hydroxybutyrate) with polyethylene glycol (PEG): Thermal behaviour and rheological study
title_full_unstemmed Blending poly (3-hydroxybutyrate) with polyethylene glycol (PEG): Thermal behaviour and rheological study
title_sort blending poly (3-hydroxybutyrate) with polyethylene glycol (peg): thermal behaviour and rheological study
publisher Faculty Mechanical Engineering, UMP
publishDate 2019
url http://umpir.ump.edu.my/id/eprint/26048/
http://umpir.ump.edu.my/id/eprint/26048/
http://umpir.ump.edu.my/id/eprint/26048/
http://umpir.ump.edu.my/id/eprint/26048/1/Blending%20poly%20%283-hydroxybutyrate%29%20with%20polyethylene%20glycol%20%28PEG%29.pdf
first_indexed 2023-09-18T22:40:19Z
last_indexed 2023-09-18T22:40:19Z
_version_ 1777416871035797504

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