On the preparation of EPDM-g-MAH compatibilizer via melt-blending method

This paper presents an experimental investigation to determine the optimum composition of maleic anhydride (MAH) and dicumyl peroxide (DCP) as initiator for ethylene-propylene-diene-monomer grafted MAH (EPDM-g-MAH) compatibilizer preparation, using response surface methodology (RSM) approach. EPDM-g...

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Main Authors:	A. Razak, J., Mohamad, N., Mahamood, M. A., Jaafar, R., Othman, I. S., Ismail, M. M., Tee, L. K., Ramli, Junid, Mustafa, Z.
Format:	Article
Language:	English
Published:	Faculty Mechanical Engineering, UMP 2019
Subjects:	TJ Mechanical engineering and machinery TP Chemical technology TS Manufactures
Online Access:	http://umpir.ump.edu.my/id/eprint/26054/ http://umpir.ump.edu.my/id/eprint/26054/ http://umpir.ump.edu.my/id/eprint/26054/ http://umpir.ump.edu.my/id/eprint/26054/1/On%20the%20preparation%20of%20EPDM-g-MAH%20compatibilizer%20.pdf

id	ump-26054
recordtype	eprints
spelling	ump-260542019-11-21T03:50:50Z http://umpir.ump.edu.my/id/eprint/26054/ On the preparation of EPDM-g-MAH compatibilizer via melt-blending method A. Razak, J. Mohamad, N. Mahamood, M. A. Jaafar, R. Othman, I. S. Ismail, M. M. Tee, L. K. Ramli, Junid Mustafa, Z. TJ Mechanical engineering and machinery TP Chemical technology TS Manufactures This paper presents an experimental investigation to determine the optimum composition of maleic anhydride (MAH) and dicumyl peroxide (DCP) as initiator for ethylene-propylene-diene-monomer grafted MAH (EPDM-g-MAH) compatibilizer preparation, using response surface methodology (RSM) approach. EPDM-g-MAH was prepared in the laboratory scale by melt blending method using an internal mixer. For this study, the effects of MAH (2.50 – 7.50 wt.%) and DCP (0.10 – 0.30 wt.%) towards grafting efficiency was determined. Two level full factorial design of experiment (DOE) is applied to establish the relationship between these two independent factors of raw materials. Analysis of variance (ANOVA) and the optimization menu were utilized to decide the raw materials formulation with maximum grafting efficiency. Quantitative analysis based on infra-red (IR) spectral intensity supported by 1H-NMR spectral are used to propose for EPDM-g-MAH grafting mechanism. Standard calibration curve for quantity ratio plot was exponential with R2 = 89.19%. It was found that an optimum about 8.52% of MAF grafting efficiency has been yielded with DCP factor has contributed larger effect at 67.45% of contribution effect. Anhydride stretching of grafted C=O as confirmed by FTIR peak at 1713 cm-1 and 1770 – 1792 cm-1 has responsible for MAH grafting into EPDM rubber. Based on FTIR, 1H-NMR and 2D-COSY spectral analysis, reaction mechanism for EPDM-g-MAH grafting was successfully proposed with two possible termination steps. Faculty Mechanical Engineering, UMP 2019-09-27 Article PeerReviewed pdf en cc_by_nc_4 http://umpir.ump.edu.my/id/eprint/26054/1/On%20the%20preparation%20of%20EPDM-g-MAH%20compatibilizer%20.pdf A. Razak, J. and Mohamad, N. and Mahamood, M. A. and Jaafar, R. and Othman, I. S. and Ismail, M. M. and Tee, L. K. and Ramli, Junid and Mustafa, Z. (2019) On the preparation of EPDM-g-MAH compatibilizer via melt-blending method. Journal of Mechanical Engineering and Sciences (JMES), 13 (3). 5424 -5440. ISSN 2289-4659 (print); 2231-8380 (online) http://journal.ump.edu.my/jmes/article/view/383 https://doi.org/10.15282/jmes.13.3.2019.14.0440
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	TJ Mechanical engineering and machinery TP Chemical technology TS Manufactures
spellingShingle	TJ Mechanical engineering and machinery TP Chemical technology TS Manufactures A. Razak, J. Mohamad, N. Mahamood, M. A. Jaafar, R. Othman, I. S. Ismail, M. M. Tee, L. K. Ramli, Junid Mustafa, Z. On the preparation of EPDM-g-MAH compatibilizer via melt-blending method
description	This paper presents an experimental investigation to determine the optimum composition of maleic anhydride (MAH) and dicumyl peroxide (DCP) as initiator for ethylene-propylene-diene-monomer grafted MAH (EPDM-g-MAH) compatibilizer preparation, using response surface methodology (RSM) approach. EPDM-g-MAH was prepared in the laboratory scale by melt blending method using an internal mixer. For this study, the effects of MAH (2.50 – 7.50 wt.%) and DCP (0.10 – 0.30 wt.%) towards grafting efficiency was determined. Two level full factorial design of experiment (DOE) is applied to establish the relationship between these two independent factors of raw materials. Analysis of variance (ANOVA) and the optimization menu were utilized to decide the raw materials formulation with maximum grafting efficiency. Quantitative analysis based on infra-red (IR) spectral intensity supported by 1H-NMR spectral are used to propose for EPDM-g-MAH grafting mechanism. Standard calibration curve for quantity ratio plot was exponential with R2 = 89.19%. It was found that an optimum about 8.52% of MAF grafting efficiency has been yielded with DCP factor has contributed larger effect at 67.45% of contribution effect. Anhydride stretching of grafted C=O as confirmed by FTIR peak at 1713 cm-1 and 1770 – 1792 cm-1 has responsible for MAH grafting into EPDM rubber. Based on FTIR, 1H-NMR and 2D-COSY spectral analysis, reaction mechanism for EPDM-g-MAH grafting was successfully proposed with two possible termination steps.
format	Article
author	A. Razak, J. Mohamad, N. Mahamood, M. A. Jaafar, R. Othman, I. S. Ismail, M. M. Tee, L. K. Ramli, Junid Mustafa, Z.
author_facet	A. Razak, J. Mohamad, N. Mahamood, M. A. Jaafar, R. Othman, I. S. Ismail, M. M. Tee, L. K. Ramli, Junid Mustafa, Z.
author_sort	A. Razak, J.
title	On the preparation of EPDM-g-MAH compatibilizer via melt-blending method
title_short	On the preparation of EPDM-g-MAH compatibilizer via melt-blending method
title_full	On the preparation of EPDM-g-MAH compatibilizer via melt-blending method
title_fullStr	On the preparation of EPDM-g-MAH compatibilizer via melt-blending method
title_full_unstemmed	On the preparation of EPDM-g-MAH compatibilizer via melt-blending method
title_sort	on the preparation of epdm-g-mah compatibilizer via melt-blending method
publisher	Faculty Mechanical Engineering, UMP
publishDate	2019
url	http://umpir.ump.edu.my/id/eprint/26054/ http://umpir.ump.edu.my/id/eprint/26054/ http://umpir.ump.edu.my/id/eprint/26054/ http://umpir.ump.edu.my/id/eprint/26054/1/On%20the%20preparation%20of%20EPDM-g-MAH%20compatibilizer%20.pdf
first_indexed	2023-09-18T22:40:20Z
last_indexed	2023-09-18T22:40:20Z
_version_	1777416871931281408

On the preparation of EPDM-g-MAH compatibilizer via melt-blending method

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