Hydrogen production by glycerol dry reforming over rhenium promoted Ni-based catalyst supported on Santa Barbara Amorphous 15 (SBA-15)

This paper presents the glycerol dry reforming (GDR) reaction using rhenium (Re) promoted on Ni-based catalyst supported on Santa Barbara Amorphous 15 (SBA-15) for the production of hydrogen. In this study, the non-promoted (15%Ni/SBA-15) and promoted (3%Re-15%Ni/SBA-15) catalysts were first synthes...

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Main Authors:	Nurul Asmawati, Roslan, Nur Nabillah, Mohd Arif, Jessy, Lynn Jaspin, Nurul Aini, Mohamed Razali, Sumaiya, Zainal Abidin
Format:	Article
Language:	English
Published:	Taylor & Francis 2019
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/26213/ http://umpir.ump.edu.my/id/eprint/26213/ http://umpir.ump.edu.my/id/eprint/26213/ http://umpir.ump.edu.my/id/eprint/26213/1/Hydrogen%20production%20by%20glycerol%20dry%20reforming%20over%20rhenium1.pdf

id	ump-26213
recordtype	eprints
spelling	ump-262132019-10-30T03:29:54Z http://umpir.ump.edu.my/id/eprint/26213/ Hydrogen production by glycerol dry reforming over rhenium promoted Ni-based catalyst supported on Santa Barbara Amorphous 15 (SBA-15) Nurul Asmawati, Roslan Nur Nabillah, Mohd Arif Jessy, Lynn Jaspin Nurul Aini, Mohamed Razali Sumaiya, Zainal Abidin TP Chemical technology This paper presents the glycerol dry reforming (GDR) reaction using rhenium (Re) promoted on Ni-based catalyst supported on Santa Barbara Amorphous 15 (SBA-15) for the production of hydrogen. In this study, the non-promoted (15%Ni/SBA-15) and promoted (3%Re-15%Ni/SBA-15) catalysts were first synthesized using wet impregnation method and their physicochemical characteristics were analyzed with Brunauer–Emmet–Teller (BET), scanning electron microscopy (SEM), X-ray diffraction (XRD), and thermogravimetric (TGA) analyses. Their performances were evaluated in GDR reaction and it was found that 3%Re-15%Ni/SBA-15 exhibited higher glycerol conversion (57%) and hydrogen yield (55%) than 15%Ni/SBA-15 (i.e., 20% glycerol conversion and 18% hydrogen yield). From the GDR study, the highest glycerol conversion (57%) and hydrogen yield (55%) for 3%Re-15%Ni/SBA-15 were obtained at 0.2 g catalyst, 700°C of reaction temperature, and CO2 to glycerol ratio (CGR) of 1:1. The small crystallite size and BET surface area of 3%Re-15%Ni/SBA-15 had successfully reduced the carbon deposition and indirectly contributed to high glycerol conversion and product yield. Taylor & Francis 2019 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/26213/1/Hydrogen%20production%20by%20glycerol%20dry%20reforming%20over%20rhenium1.pdf Nurul Asmawati, Roslan and Nur Nabillah, Mohd Arif and Jessy, Lynn Jaspin and Nurul Aini, Mohamed Razali and Sumaiya, Zainal Abidin (2019) Hydrogen production by glycerol dry reforming over rhenium promoted Ni-based catalyst supported on Santa Barbara Amorphous 15 (SBA-15). Energy Sources, Part A: Recovery, Utilization, and Environmental Effects. pp. 1-13. ISSN 1556-7036 (Print); 1556-7230 (Online) (In Press) https://doi.org/10.1080/15567036.2019.1645762 https://doi.org/10.1080/15567036.2019.1645762
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	TP Chemical technology
spellingShingle	TP Chemical technology Nurul Asmawati, Roslan Nur Nabillah, Mohd Arif Jessy, Lynn Jaspin Nurul Aini, Mohamed Razali Sumaiya, Zainal Abidin Hydrogen production by glycerol dry reforming over rhenium promoted Ni-based catalyst supported on Santa Barbara Amorphous 15 (SBA-15)
description	This paper presents the glycerol dry reforming (GDR) reaction using rhenium (Re) promoted on Ni-based catalyst supported on Santa Barbara Amorphous 15 (SBA-15) for the production of hydrogen. In this study, the non-promoted (15%Ni/SBA-15) and promoted (3%Re-15%Ni/SBA-15) catalysts were first synthesized using wet impregnation method and their physicochemical characteristics were analyzed with Brunauer–Emmet–Teller (BET), scanning electron microscopy (SEM), X-ray diffraction (XRD), and thermogravimetric (TGA) analyses. Their performances were evaluated in GDR reaction and it was found that 3%Re-15%Ni/SBA-15 exhibited higher glycerol conversion (57%) and hydrogen yield (55%) than 15%Ni/SBA-15 (i.e., 20% glycerol conversion and 18% hydrogen yield). From the GDR study, the highest glycerol conversion (57%) and hydrogen yield (55%) for 3%Re-15%Ni/SBA-15 were obtained at 0.2 g catalyst, 700°C of reaction temperature, and CO2 to glycerol ratio (CGR) of 1:1. The small crystallite size and BET surface area of 3%Re-15%Ni/SBA-15 had successfully reduced the carbon deposition and indirectly contributed to high glycerol conversion and product yield.
format	Article
author	Nurul Asmawati, Roslan Nur Nabillah, Mohd Arif Jessy, Lynn Jaspin Nurul Aini, Mohamed Razali Sumaiya, Zainal Abidin
author_facet	Nurul Asmawati, Roslan Nur Nabillah, Mohd Arif Jessy, Lynn Jaspin Nurul Aini, Mohamed Razali Sumaiya, Zainal Abidin
author_sort	Nurul Asmawati, Roslan
title	Hydrogen production by glycerol dry reforming over rhenium promoted Ni-based catalyst supported on Santa Barbara Amorphous 15 (SBA-15)
title_short	Hydrogen production by glycerol dry reforming over rhenium promoted Ni-based catalyst supported on Santa Barbara Amorphous 15 (SBA-15)
title_full	Hydrogen production by glycerol dry reforming over rhenium promoted Ni-based catalyst supported on Santa Barbara Amorphous 15 (SBA-15)
title_fullStr	Hydrogen production by glycerol dry reforming over rhenium promoted Ni-based catalyst supported on Santa Barbara Amorphous 15 (SBA-15)
title_full_unstemmed	Hydrogen production by glycerol dry reforming over rhenium promoted Ni-based catalyst supported on Santa Barbara Amorphous 15 (SBA-15)
title_sort	hydrogen production by glycerol dry reforming over rhenium promoted ni-based catalyst supported on santa barbara amorphous 15 (sba-15)
publisher	Taylor & Francis
publishDate	2019
url	http://umpir.ump.edu.my/id/eprint/26213/ http://umpir.ump.edu.my/id/eprint/26213/ http://umpir.ump.edu.my/id/eprint/26213/ http://umpir.ump.edu.my/id/eprint/26213/1/Hydrogen%20production%20by%20glycerol%20dry%20reforming%20over%20rhenium1.pdf
first_indexed	2023-09-18T22:40:41Z
last_indexed	2023-09-18T22:40:41Z
_version_	1777416894047846400

Hydrogen production by glycerol dry reforming over rhenium promoted Ni-based catalyst supported on Santa Barbara Amorphous 15 (SBA-15)

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