Optimization of reaction parameters of esterification on the synthesis of palm oil-based alkyds using response surface methods

In this research, polyalkyd resins were prepared from palm oil by polycondensation reaction. A two-step method viz., alcoholysis and esterification were conducted to synthesize polyalkyd resins. Response surface methodology was used to optimize the reaction parameters for esterification like reactio...

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Main Authors:	Beg, M. D. H., Islam, M. R., Ahmed, Badlishah, R. M., Yunus, Abdullah, Abu Hannifa
Format:	Conference or Workshop Item
Language:	English
Published:	IOP Publishing 2019
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/26956/ http://umpir.ump.edu.my/id/eprint/26956/ http://umpir.ump.edu.my/id/eprint/26956/1/Optimization%20of%20reaction%20parameters%20of%20esterification%20on%20the%20synthesis.pdf

id	ump-26956
recordtype	eprints
spelling	ump-269562020-03-20T02:55:22Z http://umpir.ump.edu.my/id/eprint/26956/ Optimization of reaction parameters of esterification on the synthesis of palm oil-based alkyds using response surface methods Beg, M. D. H. Islam, M. R. Ahmed, Badlishah R. M., Yunus Abdullah, Abu Hannifa TP Chemical technology In this research, polyalkyd resins were prepared from palm oil by polycondensation reaction. A two-step method viz., alcoholysis and esterification were conducted to synthesize polyalkyd resins. Response surface methodology was used to optimize the reaction parameters for esterification like reaction temperature, reaction time, catalyst concentration, acid anhydride to mono-glyceride ratio and agitation speed. The optimum condition was used to prepare various types of polyalkyds using different types of acid anhydrides such as, maleic anhydride, succinic anhydride, phthalic anhydride, 3,4,5,6-tetrahydrophthalic anhydride and cis-1,2-cyclohexanedicarboxylic anhydride. Result analyses through RSM revealed a desirability of 0.985 for the reaction time of 88.64 min. Moreover, 91.5% fractional conversion was achieved actually, which is close to the predicted value. The analysis revealed that 3,4,5,6-tetrahydophthalic anhydride-based resin showed improved resinous property than others due to the high degree of crosslinking. IOP Publishing 2019-10-14 Conference or Workshop Item PeerReviewed pdf en cc_by http://umpir.ump.edu.my/id/eprint/26956/1/Optimization%20of%20reaction%20parameters%20of%20esterification%20on%20the%20synthesis.pdf Beg, M. D. H. and Islam, M. R. and Ahmed, Badlishah and R. M., Yunus and Abdullah, Abu Hannifa (2019) Optimization of reaction parameters of esterification on the synthesis of palm oil-based alkyds using response surface methods. In: IOP Conference Series: Materials Science and Engineering, 6th Global Conference on Polymer and Composite Materials (PCM 2019), 8-11 July 2019 , Bangkok, Thailand. pp. 1-8., 634 (012038). ISSN 1757-8981 (Print), 1757-899X (Online) https://doi.org/10.1088/1757-899X/634/1/012038
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	TP Chemical technology
spellingShingle	TP Chemical technology Beg, M. D. H. Islam, M. R. Ahmed, Badlishah R. M., Yunus Abdullah, Abu Hannifa Optimization of reaction parameters of esterification on the synthesis of palm oil-based alkyds using response surface methods
description	In this research, polyalkyd resins were prepared from palm oil by polycondensation reaction. A two-step method viz., alcoholysis and esterification were conducted to synthesize polyalkyd resins. Response surface methodology was used to optimize the reaction parameters for esterification like reaction temperature, reaction time, catalyst concentration, acid anhydride to mono-glyceride ratio and agitation speed. The optimum condition was used to prepare various types of polyalkyds using different types of acid anhydrides such as, maleic anhydride, succinic anhydride, phthalic anhydride, 3,4,5,6-tetrahydrophthalic anhydride and cis-1,2-cyclohexanedicarboxylic anhydride. Result analyses through RSM revealed a desirability of 0.985 for the reaction time of 88.64 min. Moreover, 91.5% fractional conversion was achieved actually, which is close to the predicted value. The analysis revealed that 3,4,5,6-tetrahydophthalic anhydride-based resin showed improved resinous property than others due to the high degree of crosslinking.
format	Conference or Workshop Item
author	Beg, M. D. H. Islam, M. R. Ahmed, Badlishah R. M., Yunus Abdullah, Abu Hannifa
author_facet	Beg, M. D. H. Islam, M. R. Ahmed, Badlishah R. M., Yunus Abdullah, Abu Hannifa
author_sort	Beg, M. D. H.
title	Optimization of reaction parameters of esterification on the synthesis of palm oil-based alkyds using response surface methods
title_short	Optimization of reaction parameters of esterification on the synthesis of palm oil-based alkyds using response surface methods
title_full	Optimization of reaction parameters of esterification on the synthesis of palm oil-based alkyds using response surface methods
title_fullStr	Optimization of reaction parameters of esterification on the synthesis of palm oil-based alkyds using response surface methods
title_full_unstemmed	Optimization of reaction parameters of esterification on the synthesis of palm oil-based alkyds using response surface methods
title_sort	optimization of reaction parameters of esterification on the synthesis of palm oil-based alkyds using response surface methods
publisher	IOP Publishing
publishDate	2019
url	http://umpir.ump.edu.my/id/eprint/26956/ http://umpir.ump.edu.my/id/eprint/26956/ http://umpir.ump.edu.my/id/eprint/26956/1/Optimization%20of%20reaction%20parameters%20of%20esterification%20on%20the%20synthesis.pdf
first_indexed	2023-09-18T22:42:18Z
last_indexed	2023-09-18T22:42:18Z
_version_	1777416995522740224

Optimization of reaction parameters of esterification on the synthesis of palm oil-based alkyds using response surface methods

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