Glycerol Dry Reforming Over Alumina-Supported Nickel Catalysts

In this paper, dry (CO2)-reforming of glycerol, a new reforming route was carried out over alumina (Al2O3)-supported non-promoted and lanthanum-promoted Ni catalysts. Both sets of catalysts were synthesized via wet co-impregnation procedure. The physicochemical characterization of the catalysts show...

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Main Authors:	Siew, Kah Weng, Cheng, C. K., Jolius, Gimbun
Format:	Conference or Workshop Item
Language:	English
Published:	2013
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/3872/ http://umpir.ump.edu.my/id/eprint/3872/2/fkksa-2013-Siew-glycerol_dry_reforming.pdf

id	ump-3872
recordtype	eprints
spelling	ump-38722018-02-21T03:15:41Z http://umpir.ump.edu.my/id/eprint/3872/ Glycerol Dry Reforming Over Alumina-Supported Nickel Catalysts Siew, Kah Weng Cheng, C. K. Jolius, Gimbun TP Chemical technology In this paper, dry (CO2)-reforming of glycerol, a new reforming route was carried out over alumina (Al2O3)-supported non-promoted and lanthanum-promoted Ni catalysts. Both sets of catalysts were synthesized via wet co-impregnation procedure. The physicochemical characterization of the catalysts showed that the promoted catalysts possessed smaller metal crystallite size, hence higher metal dispersion compared to the virgin Ni/Al2O3 catalyst. This was also corroborated by estimations employing the Scherrer equation. In addition, modeling of gas-solid catalyst interaction from TGA analysis showed that the Order of Reaction model gave the best result with calcination energy ranged from 138 to 141 kJ mol-1 depending on the heating ramp. Preliminary reaction studies at 1023 K showed that glycerol dry reforming successfully produced syngas (H2 and CO mixture) and the catalytic performance was stable for at least 4 h of reaction. 2013 Conference or Workshop Item PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/3872/2/fkksa-2013-Siew-glycerol_dry_reforming.pdf Siew, Kah Weng and Cheng, C. K. and Jolius, Gimbun (2013) Glycerol Dry Reforming Over Alumina-Supported Nickel Catalysts. In: 2nd Postgraduate Colloquium for Environmental Research 2013 (POCER 2013) , 28-29 June 2013 , Awana Hotels and Resorts, Genting Highlands, Pahang. pp. 1-2.. (Unpublished)
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	TP Chemical technology
spellingShingle	TP Chemical technology Siew, Kah Weng Cheng, C. K. Jolius, Gimbun Glycerol Dry Reforming Over Alumina-Supported Nickel Catalysts
description	In this paper, dry (CO2)-reforming of glycerol, a new reforming route was carried out over alumina (Al2O3)-supported non-promoted and lanthanum-promoted Ni catalysts. Both sets of catalysts were synthesized via wet co-impregnation procedure. The physicochemical characterization of the catalysts showed that the promoted catalysts possessed smaller metal crystallite size, hence higher metal dispersion compared to the virgin Ni/Al2O3 catalyst. This was also corroborated by estimations employing the Scherrer equation. In addition, modeling of gas-solid catalyst interaction from TGA analysis showed that the Order of Reaction model gave the best result with calcination energy ranged from 138 to 141 kJ mol-1 depending on the heating ramp. Preliminary reaction studies at 1023 K showed that glycerol dry reforming successfully produced syngas (H2 and CO mixture) and the catalytic performance was stable for at least 4 h of reaction.
format	Conference or Workshop Item
author	Siew, Kah Weng Cheng, C. K. Jolius, Gimbun
author_facet	Siew, Kah Weng Cheng, C. K. Jolius, Gimbun
author_sort	Siew, Kah Weng
title	Glycerol Dry Reforming Over Alumina-Supported Nickel Catalysts
title_short	Glycerol Dry Reforming Over Alumina-Supported Nickel Catalysts
title_full	Glycerol Dry Reforming Over Alumina-Supported Nickel Catalysts
title_fullStr	Glycerol Dry Reforming Over Alumina-Supported Nickel Catalysts
title_full_unstemmed	Glycerol Dry Reforming Over Alumina-Supported Nickel Catalysts
title_sort	glycerol dry reforming over alumina-supported nickel catalysts
publishDate	2013
url	http://umpir.ump.edu.my/id/eprint/3872/ http://umpir.ump.edu.my/id/eprint/3872/2/fkksa-2013-Siew-glycerol_dry_reforming.pdf
first_indexed	2023-09-18T21:58:27Z
last_indexed	2023-09-18T21:58:27Z
_version_	1777414236671049728

Glycerol Dry Reforming Over Alumina-Supported Nickel Catalysts

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