The effect of different coupling agent on zeolite modification for development of polyetehersulfone mmms for O2/N2 separation

The industrial gas separations have been attracted in using membrane for gas separations since membrane separation technologies have the advantages of energy efficiency, simplicity and low cost.This lead to the exploration mixed matrix membrane (MMMs) that combining the polymeric membrane filled wit...

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Main Author:	Nik Nur Zanaryah, Nik Hassan
Format:	Undergraduates Project Papers
Language:	English
Published:	2012
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/4395/ http://umpir.ump.edu.my/id/eprint/4395/ http://umpir.ump.edu.my/id/eprint/4395/1/CD6350_NIK_NUR_ZARNAYAH.pdf

id	ump-4395
recordtype	eprints
spelling	ump-43952015-03-03T09:18:49Z http://umpir.ump.edu.my/id/eprint/4395/ The effect of different coupling agent on zeolite modification for development of polyetehersulfone mmms for O2/N2 separation Nik Nur Zanaryah, Nik Hassan TP Chemical technology The industrial gas separations have been attracted in using membrane for gas separations since membrane separation technologies have the advantages of energy efficiency, simplicity and low cost.This lead to the exploration mixed matrix membrane (MMMs) that combining the polymeric membrane filled with organics particles.In order to improve the interaction between polymer and zeolite,chemical modification on the surface of zeolite using silane coupling agents need to be done to increase the compatibility between zeolite and polymer.In this study,the effect of difference coupling agents used on zeolite modification in development of Polyethersulfone MMMs for O2/N2 separation was studied. Three types of coupling agents were used which are 3-aminopropyltriethoxysilane,glycidoxypropyltrimethoxysilane and aminopropyltriethoxysilane (APTMOS).The polymer solution was prepared contains of 30% Polyethersulfone (PES) as the polymer, 55% of N-Methyl Pyrolidone (NMP) as the solvent and 15% of zeolite 5A.The dry/wet phase inversion method was used to produce the membrane.The membrane was coated with silicone and n-hexane in order to decrease the surface defect and tested using O2 and N2 gases to determine the membrane performance.For surface and cross section image of membrane were identified using Scanning Electron Microscope (SEM).Membrane was also characterized using Fourier Transform Infrared Spectroscopy (FTIR) to analyze the presence of silane coupling agent functional group.As a conclusion,the best performance was identified by using glycidoxypropyltrimethoxysilane which gives high selectivity about 3.14. 2012-01 Undergraduates Project Papers NonPeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/4395/1/CD6350_NIK_NUR_ZARNAYAH.pdf Nik Nur Zanaryah, Nik Hassan (2012) The effect of different coupling agent on zeolite modification for development of polyetehersulfone mmms for O2/N2 separation. Faculty of Chemical & Natural Resource Engineering, Universiti Malaysia Pahang. http://iportal.ump.edu.my/lib/item?id=chamo:67166&theme=UMP2
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English
topic	TP Chemical technology
spellingShingle	TP Chemical technology Nik Nur Zanaryah, Nik Hassan The effect of different coupling agent on zeolite modification for development of polyetehersulfone mmms for O2/N2 separation
description	The industrial gas separations have been attracted in using membrane for gas separations since membrane separation technologies have the advantages of energy efficiency, simplicity and low cost.This lead to the exploration mixed matrix membrane (MMMs) that combining the polymeric membrane filled with organics particles.In order to improve the interaction between polymer and zeolite,chemical modification on the surface of zeolite using silane coupling agents need to be done to increase the compatibility between zeolite and polymer.In this study,the effect of difference coupling agents used on zeolite modification in development of Polyethersulfone MMMs for O2/N2 separation was studied. Three types of coupling agents were used which are 3-aminopropyltriethoxysilane,glycidoxypropyltrimethoxysilane and aminopropyltriethoxysilane (APTMOS).The polymer solution was prepared contains of 30% Polyethersulfone (PES) as the polymer, 55% of N-Methyl Pyrolidone (NMP) as the solvent and 15% of zeolite 5A.The dry/wet phase inversion method was used to produce the membrane.The membrane was coated with silicone and n-hexane in order to decrease the surface defect and tested using O2 and N2 gases to determine the membrane performance.For surface and cross section image of membrane were identified using Scanning Electron Microscope (SEM).Membrane was also characterized using Fourier Transform Infrared Spectroscopy (FTIR) to analyze the presence of silane coupling agent functional group.As a conclusion,the best performance was identified by using glycidoxypropyltrimethoxysilane which gives high selectivity about 3.14.
format	Undergraduates Project Papers
author	Nik Nur Zanaryah, Nik Hassan
author_facet	Nik Nur Zanaryah, Nik Hassan
author_sort	Nik Nur Zanaryah, Nik Hassan
title	The effect of different coupling agent on zeolite modification for development of polyetehersulfone mmms for O2/N2 separation
title_short	The effect of different coupling agent on zeolite modification for development of polyetehersulfone mmms for O2/N2 separation
title_full	The effect of different coupling agent on zeolite modification for development of polyetehersulfone mmms for O2/N2 separation
title_fullStr	The effect of different coupling agent on zeolite modification for development of polyetehersulfone mmms for O2/N2 separation
title_full_unstemmed	The effect of different coupling agent on zeolite modification for development of polyetehersulfone mmms for O2/N2 separation
title_sort	effect of different coupling agent on zeolite modification for development of polyetehersulfone mmms for o2/n2 separation
publishDate	2012
url	http://umpir.ump.edu.my/id/eprint/4395/ http://umpir.ump.edu.my/id/eprint/4395/ http://umpir.ump.edu.my/id/eprint/4395/1/CD6350_NIK_NUR_ZARNAYAH.pdf
first_indexed	2023-09-18T21:58:56Z
last_indexed	2023-09-18T21:58:56Z
_version_	1777414267472969728

The effect of different coupling agent on zeolite modification for development of polyetehersulfone mmms for O2/N2 separation

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