The Effects of Increasing Unsaturation in Palm Oil and Incorporation of Carbon Nanotubes on Resinous Properties

Considering palm oil as non-drying oil owing to its low iodine value, an attempt was taken to increase the unsaturation in the fatty acid chains of palm oil for the preparation of alkyds. To increase the unsaturation in the palm oil, sulphuric acid (SA) and para-toluene sulphonic acid (PTSA) was us...

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Main Authors:	M. R., Islam, Beg, M. D. H., Saidatul Shima, Jamari
Format:	Article
Language:	English English
Published:	World Academy of Science, Engineering and Technology 2015
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/6165/ http://umpir.ump.edu.my/id/eprint/6165/ http://umpir.ump.edu.my/id/eprint/6165/1/The%20Effects%20of%20Increasing%20Unsaturation%20in%20Palm%20Oil%20and%20Incorporation%20of%20Carbon%20Nanotubes%20on%20Resinous%20Properties.pdf http://umpir.ump.edu.my/id/eprint/6165/7/fkksa-2015-mdh-Effects%20of%20Increasing.pdf

id	ump-6165
recordtype	eprints
spelling	ump-61652018-01-10T03:15:34Z http://umpir.ump.edu.my/id/eprint/6165/ The Effects of Increasing Unsaturation in Palm Oil and Incorporation of Carbon Nanotubes on Resinous Properties M. R., Islam Beg, M. D. H. Saidatul Shima, Jamari TP Chemical technology Considering palm oil as non-drying oil owing to its low iodine value, an attempt was taken to increase the unsaturation in the fatty acid chains of palm oil for the preparation of alkyds. To increase the unsaturation in the palm oil, sulphuric acid (SA) and para-toluene sulphonic acid (PTSA) was used prior to alcoholysis for the dehydration process. The iodine number of the oil samples was checked for the unsaturation measurement by Wijs method. Alkyd resin was prepared using the dehydrated palm oil by following alcoholysis and esterification reaction. To improve the film properties 0.5wt.% multi-wall carbon nano tubes (MWCNTs) were used to manufacture polymeric film. The properties of the resins were characterized by various physico-chemical properties such as density, viscosity, iodine value, saponification value, etc. Structural elucidation was confirmed by Fourier transform of infrared spectroscopy and proton nuclear magnetic resonance; surfaces of the films were examined by field-emission scanning electron microscope. In addition, pencil hardness and chemical resistivity was also measured by using standard methods. The effect of enhancement of the unsaturation in the fatty acid chain found significant and motivational. The resin prepared with dehydrated palm oil showed improved properties regarding hardness and chemical resistivity testing. The incorporation of MWCNTs enhanced the thermal stability and hardness of the films as well. World Academy of Science, Engineering and Technology 2015 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/6165/1/The%20Effects%20of%20Increasing%20Unsaturation%20in%20Palm%20Oil%20and%20Incorporation%20of%20Carbon%20Nanotubes%20on%20Resinous%20Properties.pdf application/pdf en cc_by http://umpir.ump.edu.my/id/eprint/6165/7/fkksa-2015-mdh-Effects%20of%20Increasing.pdf M. R., Islam and Beg, M. D. H. and Saidatul Shima, Jamari (2015) The Effects of Increasing Unsaturation in Palm Oil and Incorporation of Carbon Nanotubes on Resinous Properties. International Journal of Chemical, Nuclear, Materials and Metallurgical Engineering, 9 (3). pp. 475-480. http://waset.org/publications/10001064/the-effects-of-increasing-unsaturation-in-palm-oil-and-incorporation-of-carbon-nanotubes-on-resinous-properties
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English English
topic	TP Chemical technology
spellingShingle	TP Chemical technology M. R., Islam Beg, M. D. H. Saidatul Shima, Jamari The Effects of Increasing Unsaturation in Palm Oil and Incorporation of Carbon Nanotubes on Resinous Properties
description	Considering palm oil as non-drying oil owing to its low iodine value, an attempt was taken to increase the unsaturation in the fatty acid chains of palm oil for the preparation of alkyds. To increase the unsaturation in the palm oil, sulphuric acid (SA) and para-toluene sulphonic acid (PTSA) was used prior to alcoholysis for the dehydration process. The iodine number of the oil samples was checked for the unsaturation measurement by Wijs method. Alkyd resin was prepared using the dehydrated palm oil by following alcoholysis and esterification reaction. To improve the film properties 0.5wt.% multi-wall carbon nano tubes (MWCNTs) were used to manufacture polymeric film. The properties of the resins were characterized by various physico-chemical properties such as density, viscosity, iodine value, saponification value, etc. Structural elucidation was confirmed by Fourier transform of infrared spectroscopy and proton nuclear magnetic resonance; surfaces of the films were examined by field-emission scanning electron microscope. In addition, pencil hardness and chemical resistivity was also measured by using standard methods. The effect of enhancement of the unsaturation in the fatty acid chain found significant and motivational. The resin prepared with dehydrated palm oil showed improved properties regarding hardness and chemical resistivity testing. The incorporation of MWCNTs enhanced the thermal stability and hardness of the films as well.
format	Article
author	M. R., Islam Beg, M. D. H. Saidatul Shima, Jamari
author_facet	M. R., Islam Beg, M. D. H. Saidatul Shima, Jamari
author_sort	M. R., Islam
title	The Effects of Increasing Unsaturation in Palm Oil and Incorporation of Carbon Nanotubes on Resinous Properties
title_short	The Effects of Increasing Unsaturation in Palm Oil and Incorporation of Carbon Nanotubes on Resinous Properties
title_full	The Effects of Increasing Unsaturation in Palm Oil and Incorporation of Carbon Nanotubes on Resinous Properties
title_fullStr	The Effects of Increasing Unsaturation in Palm Oil and Incorporation of Carbon Nanotubes on Resinous Properties
title_full_unstemmed	The Effects of Increasing Unsaturation in Palm Oil and Incorporation of Carbon Nanotubes on Resinous Properties
title_sort	effects of increasing unsaturation in palm oil and incorporation of carbon nanotubes on resinous properties
publisher	World Academy of Science, Engineering and Technology
publishDate	2015
url	http://umpir.ump.edu.my/id/eprint/6165/ http://umpir.ump.edu.my/id/eprint/6165/ http://umpir.ump.edu.my/id/eprint/6165/1/The%20Effects%20of%20Increasing%20Unsaturation%20in%20Palm%20Oil%20and%20Incorporation%20of%20Carbon%20Nanotubes%20on%20Resinous%20Properties.pdf http://umpir.ump.edu.my/id/eprint/6165/7/fkksa-2015-mdh-Effects%20of%20Increasing.pdf
first_indexed	2023-09-18T22:01:43Z
last_indexed	2023-09-18T22:01:43Z
_version_	1777414442105962496

The Effects of Increasing Unsaturation in Palm Oil and Incorporation of Carbon Nanotubes on Resinous Properties

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