Synthesis and Characterization of Radiation Grafted Films for Removal of Arsenic and Some Heavy Metals from Contaminated Water

Grafting of styrene/maleic anhydride and methyl methacrylate/maleic anhydride binary monomers onto the low density polyethylene film was performed using the γ-ray irradiation technique. Then, the synthesized grafted films were treated with different ammonia derivatives for developing chelating funct...

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Main Authors:	Chowdhury, M. N. K., M. W., Khan, M. F., Fina, Beg, M. D. H., Khan, Maksudur R., A. K. M., Moshiul Alam
Format:	Article
Language:	English English
Published:	Elsevier Ltd 2012
Subjects:	TP Chemical technology
Online Access:	http://umpir.ump.edu.my/id/eprint/6472/ http://umpir.ump.edu.my/id/eprint/6472/ http://umpir.ump.edu.my/id/eprint/6472/ http://umpir.ump.edu.my/id/eprint/6472/1/Synthesis_and_characterization_of_radiation_grafted_films_for_removal_of_arsenic_and_some_heavy_metals_from_contaminated_water.pdf http://umpir.ump.edu.my/id/eprint/6472/4/Synthesis%20and%20characterization%20of%20radiation%20grafted%20films%20for%20removal%20of%20arsenic%20and%20some%20heavy%20metals%20from%20contaminated%20water.pdf

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spelling	ump-64722018-03-08T07:31:57Z http://umpir.ump.edu.my/id/eprint/6472/ Synthesis and Characterization of Radiation Grafted Films for Removal of Arsenic and Some Heavy Metals from Contaminated Water Chowdhury, M. N. K. M. W., Khan M. F., Fina Beg, M. D. H. Khan, Maksudur R. A. K. M., Moshiul Alam TP Chemical technology Grafting of styrene/maleic anhydride and methyl methacrylate/maleic anhydride binary monomers onto the low density polyethylene film was performed using the γ-ray irradiation technique. Then, the synthesized grafted films were treated with different ammonia derivatives for developing chelating functionalization. These chelating products were characterized by the gravimetric method as well as by the Fourier transformed infrared spectroscopic method, and were used for removal of arsenic and some heavy metals from aqueous solutions. The optimum absorbed dose of 30 kGy reveals the graft yielding of about 325% in the films. Uptake of arsenic and some heavy-metal ions (Cr(III), Mn(II), Fe(III), Ni(II), Cu(II) and Pb(II)) from contaminated water by the chelating functionalized films (CFF) was examined by an atomic absorption spectrophotometer. The maximum arsenic removal capacity of 5062 mg/kg has been observed for the film treated with hydroxylamine hydrochloride. The CFF prepared by semicarbazide and thiol analogs show affinity toward the metal ions with an order: Cu(II)>Fe(III)>Mn(II) etc. The results obtained from this study indicate that the functionalized films show good chelating and ion-exchange property for metal ions. Elsevier Ltd 2012 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/6472/1/Synthesis_and_characterization_of_radiation_grafted_films_for_removal_of_arsenic_and_some_heavy_metals_from_contaminated_water.pdf application/pdf en http://umpir.ump.edu.my/id/eprint/6472/4/Synthesis%20and%20characterization%20of%20radiation%20grafted%20films%20for%20removal%20of%20arsenic%20and%20some%20heavy%20metals%20from%20contaminated%20water.pdf Chowdhury, M. N. K. and M. W., Khan and M. F., Fina and Beg, M. D. H. and Khan, Maksudur R. and A. K. M., Moshiul Alam (2012) Synthesis and Characterization of Radiation Grafted Films for Removal of Arsenic and Some Heavy Metals from Contaminated Water. Radiation Physics and Chemistry, 81 (10). pp. 1606-1611. ISSN 0969-806X http://dx.doi.org/10.1016/j.radphyschem.2012.04.014 DOI: 10.1016/j.radphyschem.2012.04.014
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Pahang
building	UMP Institutional Repository
collection	Online Access
language	English English
topic	TP Chemical technology
spellingShingle	TP Chemical technology Chowdhury, M. N. K. M. W., Khan M. F., Fina Beg, M. D. H. Khan, Maksudur R. A. K. M., Moshiul Alam Synthesis and Characterization of Radiation Grafted Films for Removal of Arsenic and Some Heavy Metals from Contaminated Water
description	Grafting of styrene/maleic anhydride and methyl methacrylate/maleic anhydride binary monomers onto the low density polyethylene film was performed using the γ-ray irradiation technique. Then, the synthesized grafted films were treated with different ammonia derivatives for developing chelating functionalization. These chelating products were characterized by the gravimetric method as well as by the Fourier transformed infrared spectroscopic method, and were used for removal of arsenic and some heavy metals from aqueous solutions. The optimum absorbed dose of 30 kGy reveals the graft yielding of about 325% in the films. Uptake of arsenic and some heavy-metal ions (Cr(III), Mn(II), Fe(III), Ni(II), Cu(II) and Pb(II)) from contaminated water by the chelating functionalized films (CFF) was examined by an atomic absorption spectrophotometer. The maximum arsenic removal capacity of 5062 mg/kg has been observed for the film treated with hydroxylamine hydrochloride. The CFF prepared by semicarbazide and thiol analogs show affinity toward the metal ions with an order: Cu(II)>Fe(III)>Mn(II) etc. The results obtained from this study indicate that the functionalized films show good chelating and ion-exchange property for metal ions.
format	Article
author	Chowdhury, M. N. K. M. W., Khan M. F., Fina Beg, M. D. H. Khan, Maksudur R. A. K. M., Moshiul Alam
author_facet	Chowdhury, M. N. K. M. W., Khan M. F., Fina Beg, M. D. H. Khan, Maksudur R. A. K. M., Moshiul Alam
author_sort	Chowdhury, M. N. K.
title	Synthesis and Characterization of Radiation Grafted Films for Removal of Arsenic and Some Heavy Metals from Contaminated Water
title_short	Synthesis and Characterization of Radiation Grafted Films for Removal of Arsenic and Some Heavy Metals from Contaminated Water
title_full	Synthesis and Characterization of Radiation Grafted Films for Removal of Arsenic and Some Heavy Metals from Contaminated Water
title_fullStr	Synthesis and Characterization of Radiation Grafted Films for Removal of Arsenic and Some Heavy Metals from Contaminated Water
title_full_unstemmed	Synthesis and Characterization of Radiation Grafted Films for Removal of Arsenic and Some Heavy Metals from Contaminated Water
title_sort	synthesis and characterization of radiation grafted films for removal of arsenic and some heavy metals from contaminated water
publisher	Elsevier Ltd
publishDate	2012
url	http://umpir.ump.edu.my/id/eprint/6472/ http://umpir.ump.edu.my/id/eprint/6472/ http://umpir.ump.edu.my/id/eprint/6472/ http://umpir.ump.edu.my/id/eprint/6472/1/Synthesis_and_characterization_of_radiation_grafted_films_for_removal_of_arsenic_and_some_heavy_metals_from_contaminated_water.pdf http://umpir.ump.edu.my/id/eprint/6472/4/Synthesis%20and%20characterization%20of%20radiation%20grafted%20films%20for%20removal%20of%20arsenic%20and%20some%20heavy%20metals%20from%20contaminated%20water.pdf
first_indexed	2023-09-18T22:02:14Z
last_indexed	2023-09-18T22:02:14Z
_version_	1777414475265081344

Synthesis and Characterization of Radiation Grafted Films for Removal of Arsenic and Some Heavy Metals from Contaminated Water

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